Samples collected from a 170 m borehole penetrating till, bentonitic clay, and sand at the Birsay site, Saskatchewan, Canada, has been studied as a first step for understanding the controls on dissolution and transport of trace elements, including REEs, in porewaters of a clay-rich aquitard. The REE budgets of the till, clay, and sand are dominated by apatite and monazite, with sporadic zircon and Y-phosphate. Apatites contain 0.3 to 1.7 wt.% REE, and monazites 12 to 55 wt.%. All three units are characterized by unusual bulk sample REE patterns, with maxima at Eu–Gd, convex down patterns from La–Sm with minima at Ce, and variably fractionated HREE. Apatites feature maxima at Eu–Gd. Consequently the complex patterns arise from variable modal proportions of apatite, monazite, and plagioclase feldspar. Relative to Post-Archean Average Shale (PAAS), the till is SiO 2 and CaO rich with about half the contents of Al 2O 3, TiO 2, and Fe 2O 3. These compositional relationship stem from relatively high proportions of quartz and carbonate, but low modal abundances of ferromagnesian and Ti-oxide minerals. Similarly, the till has Cs, Co, Ni, Sc, V, Cu, Pb and Zn contents at about half PAAS. The bentonite clay has slightly higher SiO 2 and CaO contents than PAAS, with lower abundances of most other trace elements, including REE which plot at 0.7 to 0.9 PAAS. The major and trace element composition is similar to continental arc andesites, and the clay is interpreted to have a mixed provenance of arc andesite and eroded underlying sands. The composition of the till appears to reflect mixed provenance: erosion of the underlying Cretaceous clay and sand, Paleozoic carbonate rocks, and the Precambrian Shield. The silicious Ardkenneth sand has lower concentrations of REE and most trace elements compared to the clay, but the most fractionated REE patterns. The clay and till have inherited more subdued REE patterns in part from the underlying sand unit. Compositional variations between the units are marked by an upturn of Nb, Th, U and REE concentrations at the till–clay interface (80.2 m), and decrease of these elements at the clay–sand boundary (156.2 m). Ce and Eu anomalies vary erratically with depth: the anomalies appear to reflect the degree of sedimentary sorting, which in turn controls the modal abundances of detrital monazite, apatite, zircon, and plagioclase feldspar. Zr/Zr*, Hf/Hf* and Zr/Hf ratios are higher in the till than the clay and sand, indicating an additional Zr (Hf)-bearing phase with a distinctively high Zr/Hf ratio. The observed small compositional variations in the till and clay are not reflected in variations of geotechnical properties. Given that the REE budget of the till and clay are dominated by highly insoluble trace minerals, it is unlikely that the REE patterns of porewaters will be controlled by bulk sample REE concentrations. Weathering of the upper 3 m of the till has oxidized Fe 2+-bearing silicates, oxides, and sulphides, and dissolved carbonates relative to the underlying unoxidized till, weathering has not disturbed major, REE or other trace element compositions.
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