In order to know about the change features of leakage current during the pollution flashover process of composite insulators, the study of the pollution flashover test on composite insulator under the pollutional condition is presented in the artificial fog cabinet. The characteristics of leakage current waveforms in time-domain and frequency-domain are measured and analyzed during the test. The analysis results show that there is a strong correlation among the fundamental harmonic, the third harmonic and fifth harmonic. The characteristics of leakage current spectrum are represented by the maximum value of leakage current (Im), total harmonic distortion (THD), and phase difference of fundamental leakage current (θ). During a near-flash event, the leakage current exhibits high amplitude, low harmonic content, and small phase difference between the fundamental leakage current and voltage. The research findings provide a basis for establishing a pollution flash warning system based on leakage current characteristic quantities.