While significant progress has been achieved in PEMFC modeling, simulating liquid water formation and transportation in a PEMFC remains a challenge. Under wet operating conditions, liquid water may condense in the channel, gas diffusion layer, or electrode, which introduces significant complexities in simulating fuel cell performance. There have been several approaches to model two-phase water transport using both macroscopic and microscopic methods. Two-phase macroscopic models are mostly based on volumetric averaged method and solve the governing equation using CFD techniques, which require intensive computational resources. In recent years, microscopic approaches based on Lattice Boltzmann Method (LBM) and pore-network approach have been applied to detailed morphological geometric domain of gas diffusion layer. While microscopic approach provide useful information, they cannot be coupled with a full fuel cell model. Therefore, constructing an effective analytical two-phase model is crucial in developing materials and design to optimizing fuel cell performance. In this work, we present an empirical-based, steady-state, 1-D, non-isothermal, and two-phase PEMFC model that includes full cell geometry and water balance. Limiting current experiments based on Caulk and Baker [1] is employed to study both dry and wet oxygen transport phenomena with wet-proofed Toray-H-060 carbon fiber paper with microporous layer. Specifically, the ratio of tortuosity and porosity under wet and dry conditions are characterized by the limiting current method and incorporated into the model. The two-phase model uses tendril length to represent the liquid water saturation and penetration in the diffusion layer. Figure 1 shows that the newly constructed two-phase model can capture the total transport resistance as a function of limiting current density in the dry, transition, and wet regions well for operating conditions at 300 kPa, 70°C, 80% and 90% relative humidity. This two-phase model also includes a two-phase electrode model, which correlates electrode relative humidity to available ECSA for fuel cell performance simulation. The details of the model and prediction results will be presented at the conference. Referece: 1. Caulk, D.A. and Baker, D.R., 2010. Heat and water transport in hydrophobic diffusion media of PEM fuel cells. Journal of The Electrochemical Society, 157(8), pp.B1237-B1244. Figure 1
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