Central Au Research Articles

Measurement of Intermittency for Charged Particles in Au + Au Collisions at $\sqrt{s_\mathrm{NN}}$ = 7.7-200 GeV from STAR

Local density fluctuations near the QCD critical point can be probed by intermittency analysis of scaled factorial moments in relativistic heavy-ion collisions. We report the first measurement of intermittency for charged particles in Au + Au collisions at \sqrt{s_\mathrm{NN}}sNN = 7.7-200 GeV from the STAR experiment at RHIC. We observe scaling behaviors in central Au + Au collisions, with the extracted scaling exponent decreasing from mid-central to the most central Au + Au collisions. Furthermore, the scaling exponent exhibits a non-monotonic energy dependence with a minimum around \sqrt{s_\mathrm{NN}}sNN = 20-30 GeV in central Au + Au collisions.

First indication on self-similarity of strangeness production in Au+Au collisions at RHIC: Search for signature of phase transition in nuclear matter

New results of analysis of K^0_S-KS0−meson spectra measured over a wide range of energy \sqrt {s_{NN}}=7.7-200sNN=7.7−200 GeV and centrality in Au+AuAu+Au collisions by the STAR Collaboration at RHIC using the zz-scaling approach are presented. Indication on self-similarity of fractal structure of nuclei and fragmentation processes with K^0_SKS0 probe is demonstrated. The energy loss as a function of the collision energy, centrality and transverse momentum of the inclusive strange meson is estimated.

Analysis of Midrapidity pT Distributions of Identified Charged Particles in Pb + Pb Collisions at snn = 5.02 TeV Using Tsallis Distribution with Embedded Transverse Flow

The midrapidity transverse momentum distributions of the charged pions, kaons, protons, and antiprotons, measured by ALICE Collaboration at ten centrality classes of Pb + Pb collisions at snn = 5.02 TeV in the Large Hadron Collider (LHC, CERN, Switzerland), are successfully analyzed using combined minimum χ2 fits with a thermodynamically non-consistent, as well as thermodynamically consistent, Tsallis function with transverse flow. The extracted non-extensivity parameter q decreases systematically for all considered particle species with increasing Pb + Pb collision centrality, suggesting an increase in the degree of system thermalization with an increase in collision centrality. The results for q suggest quite a large degree of thermalization of quark–gluon plasma (QGP) created in central Pb + Pb collisions at snn = 5.02 TeV with the average number of participant nucleons ⟨Npart⟩ > 160. The obtained significantly different growth rates of transverse flow velocity, ⟨βT⟩, in regions ⟨Npart⟩ < 71 ± 7 and ⟨Npart⟩ > 71 ± 7 with the temperature parameter T0 remaining constant within uncertainties in region ⟨Npart⟩ > 71 ± 7 probably indicates that ⟨Npart⟩ ≈ 71 ± 7 (corresponding to ⟨dNch/dη⟩ ≈ 251 ± 20) is a threshold border value for a crossover transition from a dense hadronic state to the QGP phase (or mixed phase of QGP and hadrons) in Pb + Pb collisions at snn = 5.02 TeV. The threshold border value for transverse flow velocity ⟨βT⟩ ≈ 0.46 ± 0.03 (corresponding to ⟨Npart⟩ ≈ 71 ± 7), estimated by us in Pb + Pb collisions at snn = 5.02 TeV, agrees well with the corresponding border value ⟨βT⟩ ≈ 0.44 ± 0.02, recently obtained in Xe + Xe collisions at snn = 5.44 TeV, and with almost constant ⟨βT⟩ values extracted earlier in the Beam Energy Scan (BES) program of the Relativistic Heavy-Ion Collider (RHIC, Brookhaven, GA, USA) in central Au + Au collisions in the snn = 7.7 − 39 GeV energy range, where the threshold for QGP production is achieved. The correlations between extracted T0 and ⟨βT⟩ parameters are found to be greatly different in regions ⟨βT⟩ < 0.46 and ⟨βT⟩ > 0.46, which further supports our result obtained for the threshold border value in Pb + Pb collisions at snn = 5.02 TeV.

Enhanced Fluorescence with Tunable Color in Doped Diphosphine-Protected Gold Nanoclusters.

Rational control of the luminescent properties of ligand-protected coinage metal clusters has long been pursued but remains challenging. Here we explore the crucial structural and electronic factors governing the fluorescence of a diphosphine-protected [Au13(dppe)5Cl2]3+ cluster by time-dependent density functional theory calculations. By substituting the central Au atom with group 5 to group 11 transition metal atoms, the emission wavelength is adjustable from red to blue, accompanied by enhanced fluorescence intensity compared with the undoped cluster. The evolution of light-emitting behavior upon doping and the corresponding roles of the dopant, Au cage, ligands, and their interplay are interpreted at the electronic structure level. In particular, strong dopant-Au cage interaction associated with large electron-hole overlap on the dopant are is a key factor to endow large emission energy and intensity. These theoretical results provide vital guidance for designing atomically precise nanoclusters with visible fluorescence and high quantum yield for practical uses.

Reactivity of Unsupported Transition Metal-Aluminyl Complexes: A Nucleophilic TM-Al Bond.

Despite the long history of research in transition metal (TM) complexes, the study of TM-aluminyl complexes is still in its early stage of development. It is expected that the presence of an electropositive Al donor atom would open up new possibilities in TM complex reactivity, and indeed TM-aluminyl has shown an early sign of success in small-molecule activation. On the other hand, the existing reports on TM-aluminyl reactivity are often explained to readers with different understanding on individual cases, and a general picture of TM-aluminyl reactivity is still not available. In this work, we have attempted to provide a systematic picture to explain some early explorations in this field, specifically a series of recently reported heteroallene insertion reactions involving unsupported TM-aluminyl complexes. Through density functional theory calculations of a number of TM-aluminyl complexes, covering both Au and Cu centers, we found that their reactivity against heteroallenes (including CO2 and carbodiimides) is mostly based on the strong nucleophilicity of the TM-Al σ-bond.

A digold(I) – Tetraalkynyl macrocycle with host-guest properties

In this contribution we wish to describe the synthesis and characterization of an anthraquinone-based dialkynyl ligand AQ-(OCH2CCH)2 (1, AQ = anthraquinone) and its coordination to Au(I) centers, to form a negatively charged tetraalkynyldigold macrocycle ([AQ-(OCH2CC)2Au]2(NPr4)2 (2)), capable to act as a host for positively charged species. X-Ray diffraction studies revealed that compound 1 crystalizes in the monoclinic crystal system, space group C2/c, with the unit cell dimensions a = 33.4705(19) Å, b = 6.8582(4) Å, c = 12.8850(7) Å, and β = 90.7990(10)°, with Z = 8. The supramolecular structure of 1 consists of ribbons running along the b axis of the unit cell, and it is supported by CC-H ··· O hydrogen bonds and π – π stacking interactions. Complex 2 crystalizes in the monoclinic crystal system, space group P21/c, with the unit cell dimensions a = 21.5515(9) Å, b = 15.3851(6) Å, c = 25.2615(10) Å, and β = 99.6730(10)°, with Z = 4. X-Ray diffraction investigations showed that the structure of 2 consists of two anthraquinone groups connected by two CC–Au–CC spacers, with an overall basket-like shape of the macrocycle. One tetrapropylammonium cation is positioned inside the macrocycle with two n-Pr groups being threaded through the cavity of the macrocycle, and the other two situated between the two anthraquinone moieties of the complex. This species is best described as an inclusion compound, formulated as {N[n-Pr]4+⊂22–}{N[n-Pr]4+}.

2-Aminoalkylgold Complexes: The Putative Intermediate in Au-Catalyzed Hydroamination of Alkenes Does Not Protodemetalate.

Au‐catalyzed hydroamination proceeds well for alkynes but not alkenes. We report gas‐phase binding energies of alkenes and alkynes to a cationic Au center, which indicate that differences in binding are not the origin of the disparate chemical behavior. We further report the synthesis and characterization of 2‐aminoalkylgold complexes, which would be the intermediates in a hypothetical Au‐catalyzed hydroamination of styrene. The reactivity of the well‐characterized and isolable complexes reveals that protonation or alkylation of the 2‐aminoalkylgold complexes results in amine elimination in solution, and in the gas phase, indicating that the failure of Au‐catalyzed alkene hydroamination derives from a non‐competitive protodeauration step. We analyze possible transition states for the protodeauration, and identify an insufficiently strong Au‐proton interaction as the reason that the transition states lie too high in energy to compete.

Polyamine‐Assisted Rapid Gold Nanocluster Synthesis via Electrostatic Attraction‐Facilitated Core Approaching

AbstractThiolate‐stabilized gold nanoclusters (Au NCs) are widely used in bioimaging, chemical sensing, and emitting devices because of their good solubility, great stability and versatile optical/chemical properties. However, most conventional synthetic strategies reported so far suffer long reaction time, which limits the rapid and large‐scale synthesis of Au NCs. In this study, a simple electrostatic attraction‐assisted core approaching strategy was developed, which accelerates the synthesis of Au NCs by introducing polyamine (hyperbranched polyetheneimine, hPEI). As a case study, the tactic was demonstrated for the rapid preparation of Au NCs based on glutathione (GSH)‐HAuCl4 system within 1.5 h. The synthesis includes two steps: first, negatively charged Au(I)‐GSH complex under basic condition (pH 9) was adsorbed onto hPEI surface via electrostatic attraction; second, aurophilic attraction of Au(I) centers benefited the formation of Au NCs. With such a strategy, copper nanoclusters (Cu NCs) can also be quickly prepared within 30 min.

Microwave-Assisted Base-Free Oxidation of Glucose with H2O2 on Gold- and Manganese-Containing SBA-15-Insight into Factors Affecting the Reaction Pathway.

The aim of this work was to gain insights into the role of manganese in MnSBA-15 support for gold in the base-free glucose oxidation with H2O2 using a microwave reactor. MnSBA-15 (manganese—acidity source) and SBA-15 (for comparison) were modified with Au (2.2 wt. %) and Cu (for comparison). The physicochemical properties of the catalysts were investigated by XRD, N2 ads/des, TEM, UV-vis, XPS, pyridine adsorption combined with FTIR, ATR-FTIR, and 2-propanol decomposition. The effects of the Mn presence in the support, Au NPs size that determines the number of active Au centers, and the Fermi energy (EF), together with the effects of the pore size, reaction temperature, and time on the activity and selectivity of the applied catalysts were assessed and discussed. It has been demonstrated that the presence of Mn generated Lewis acid centers which did not participate in glucose and H2O2 adsorption, and thus, were not directly involved in the reaction pathway. Both reagents were adsorbed on gold nanoparticles. H2O2 was decomposed to molecular oxygen which oxidized glucose to gluconic acid (50–90% of glucose conversion depending on the reaction time and ~100% selectivity). The presence of manganese in MnSBA-15 was responsible for increased Au NPs size and only slightly influenced the negative charge on gold particles. To achieve effective activity a compromise between the number of active gold species and the level of EF has to be reached (for 5.7 nm Au NPs).

Plasmonic All-Frame-Faceted Octahedral Nanoframes with Eight Engraved Y-Shaped Hot Zones.

We report the synthesis of all-frame-faceted octahedral nanoframes containing eight Y-shaped hot zones in a single entity where electromagnetic near-field focusing can be maximized. To realize such state-of-the-art complex nanoframes, a series of multiple stepwise bottom-up processes were executed by exploiting Au octahedral nanoparticles as the initial template. By rationally controlling the chemical reactivity of different surface facets (i.e., vertexes, edges, and terraces), the Au octahedral nanoparticles went through controlled shape transformations, leading to Au-engraved nanoparticles wherein 24 edges wrap the octahedral Au nanoparticle core. Those edges were then selectively decorated with Pt, leading to the formation of eight Pt tripods in a single entity. After etching the central Au, 3D Pt tripod frame-faceted octahedral nanoframes were achieved with high integrity. By harnessing the obtained Pt nanoframes as a scaffold, AuAg alloy-based plasmonic all-frame-faceted nanoframes were obtained after the co-reduction of Ag and Au, which generated multiple hot zones within multiple surface intra-nanogaps, creating a single-particle, surface-enhanced Raman spectroscopy enhancer platform.

Selenocysteine of thioredoxin reductase as the primary target for the antitumor metallodrugs: A computational point of view

Selenocysteine (Sec) has been recognized as a soft metal-coordinating residue that dues its relevance to the important role played in the catalytic activity of thioredoxin reductase (TrxR), a well-characterized anticancer target. Thus, several computational studies have been devoted to the metalation of this Se-based residue and several metal scaffolds have been proposed as potential Sec-binders, i.e. TrxR inhibitors. Here, we reported an overview of the chemical features of Sec, as well as of typical Sec-binding metal complexes, and of the computational studies carried on metallodrugs that primary target TrxR, by specifically posing our attention to antitumour metallodrugs based on Au(I), Au(III), Ag(I), Pt(II), Pt(IV), Ru(II), Ru(III), and Rh(III) metal centers. Moreover, we provided a computational insight on the available structural data and highlighted how an optimal articulation of computational methods and modeling of the metallodrug-target system may expand our understanding of the targeting of TrxR active site by metallic scaffolds.

Stable Au(I) catalysts for oxidant-free C-H functionalization with iodoarenes

The development of oxidant-free gold-catalyzed cross coupling reactions involving aryl halides have been hamstrung by the lack of gold catalysts capable of performing oxidative addition at Au(I) centers. Herein, we report the development of novel tricoordinate Au(I) catalysts supported by N,N-bidentate ligands and ligated by phosphine or arsine ligands for C-H functionalization without external oxidants to form biaryls with no homocoupling. The unsymmetrical character of the Au(I) catalyst is critical to facilitating this necessary orthogonal transformation. This study unveils yet another potential of Au(I) catalysis in biaryl synthesis.

Soft Metal Cations Trigger Sandwich‐Cluster Luminescence of a New Au(I)‐Vinylimidazolate Cyclic Trinuclear Complex

AbstractThe formation of heterobimetallic complexes from parent cyclic trinuclear complexes (CTCs) of gold(I) has become straightforward in recent years with this team and others showing that the strategy leads to strengthened Au−M’ bonding and optoelectronic properties. A new gold(I)‐vinylimidazolate CTC, 1, was prepared and the formation of highly emissive sandwich adducts with the soft metal cations Cu+, Ag+, and Tl+, 2–4, respectively, was investigated. Compound 1 does not exhibit peculiar emissive properties at room or cryogenic temperatures as the adducts do. Its unit cell packing displays an unprecedented collection of repeating units for CTCs. While the intermolecular Au…Au distances are versatile (3.470, 3.673, and 4.045 Å), they connect only single Au centres from adjacent CTCs and form extended circular networks. Hirshfeld surface analyses mapped the new CTC contours underlining the possible cooperative effects of not only metallophilic interactions but also C−H…π and hydrogen bonding in the packing of 1 (as opposed to the dominance of the former in most other reported CTCs). DFT calculations validate the formation of sandwich‐like structures for compounds 2–4 with averaged Au−M distances of 2.665 Å, 2.802 Å, and 3.036 Å, respectively, close by to experimental crystal data obtained for similar sandwich compounds.

A Reinterpretation of the Imidazolate Au(I) Cyclic Trinuclear Compounds Reactivity with Iodine and Methyl Iodide with the Perspective of the Inverted Ligand Field Theory.

Coinage metal cyclic trinuclear compounds (CTCs) are an emerging class of metal coordination compounds that are valuable for many fine optoelectronic applications, even though the reactivity dependence by the different bridging ligands remains somewhat unclear. In this work, to furnish some hints to unravel the effect of substituents on the chemistry of Au(I) CTCs made of a specific class of bridging ligand, we have considered two imidazolate Au(I) CTCs and the effect of different substituents on the pyrrolic N atoms relative to classic metal oxidations with I2 or by probing electrophilic additions. Experimental suggestions depict a thin borderline between the addition of MeI to the N-methyl or N-benzyl imidazolyl CTCs, which afford the oxidized CTC in the former and the ring opening of the CTC and the formation of carbene species in the latter. Moreover, the reactions with iodine yield to the oxidation of the metal centers for the former and just of a metal center in the latter, even in molar excess of iodine. The analysis of the bond distances in the X-ray crystal structures of the oxidized highlights that Au(III)-C and Au(III)-N bonds are longer than observed for Au(I)–C and Au(I)–N bonds, as formally not expected for Au(III) centers. Computational studies converge on the attribution of these discrepancies to an additional case of inverted ligand field (ILF), which solves the question with a new interpretation of the Au(I)–ligand bonding in the oxidized CTCs, which furnishes a new interpretation of the Au(I)-ligand bonding in the oxidized CTCs, opening a discussion about addition/oxidation reactions. Finally, the theoretical studies outputs depict energy profiles that are compatible with the experimental results obtained in the reaction of the two CTCs toward the addition of I2, MeI, and HCl.

Measurement of cold nuclear matter effects for inclusive J/ψ in p+Au collisions at [formula omitted] GeV

Measurement by the STAR experiment at RHIC of the cold nuclear matter (CNM) effects experienced by inclusive J/ψ at mid-rapidity in 0-100% p+Au collisions at sNN = 200 GeV is presented. Such effects are quantified utilizing the nuclear modification factor, RpAu, obtained by taking a ratio of J/ψ yield in p+Au collisions to that in p+p collisions scaled by the number of binary nucleon-nucleon collisions. The differential J/ψ yield in both p+p and p+Au collisions is measured through the dimuon decay channel, taking advantage of the trigger capability provided by the Muon Telescope Detector in the RHIC 2015 run. Consequently, the J/ψRpAu is derived within the transverse momentum (pT) range of 0 to 10 GeV/c. A suppression of approximately 30% is observed for pT<2 GeV/c, while J/ψRpAu becomes compatible with unity for pT greater than 3 GeV/c, indicating the J/ψ yield is minimally affected by the CNM effects at high pT. Comparison to a similar measurement from 0-20% central Au+Au collisions reveals that the observed strong J/ψ suppression above 3 GeV/c is mostly due to the hot medium effects, providing strong evidence for the formation of the quark-gluon plasma in these collisions. Several model calculations show qualitative agreement with the measured J/ψRpAu, while their agreement with the J/ψ yields in p+p and p+Au collisions is worse.

The effect of single-particle space-momentum angle distribution on two-pion HBT correlation in relativistic heavy-ion collisions using a multiphase transport model

Using the string melting version of a multiphase transport (AMPT) model, we analyze the transverse momentum dependence of the HBT radius and the single-pion angle distribution on the transverse plane in central Au+Au collisions at =19.6, 27, 39, 62.4, and 200 GeV. Additionally, a numerical connection between these two phenomena is established with a series of functions. We can estimate the single-pion angle distribution on the transverse plane from HBT analysis.

A comparative study of structural, electronic, and optical properties of thiolated gold clusters with icosahedral vs face-centered cubic cores.

The structural, electronic, and optical properties of the protected Au clusters with icosahedral (Ih) and face-centered cubic (FCC)-like Au13 cores were studied to understand the origin of the difference in the optical gaps of these clusters. It has been demonstrated that the choice of density functionals does not qualitatively affect the properties of Au23 and Au25 clusters with Ih and FCC cores. The density of states, molecular orbitals, and natural charges were analyzed in detail using the B3LYP functional. The substantial energy difference in the lowest-energy absorption peaks for the clusters with the Ih and FCC cores is attributed to the difference in the natural charges of the central Au atoms (Auc) in the Ih and FCC cores, the former of which is more negative than the latter. Natural population analysis demonstrates that the excess negative charge of the Auc atom in clusters with Ih cores occupies the 6p atomic orbitals. This difference in Auc is attributed to the smaller size of the Ih core compared to the FCC core, as a less bulky ligand allows a smaller core with increased electron density, which, in turn, increases the highest occupied molecular orbital energy and decreases the optical gap.

Tectono-magmatic controls on decratonic gold deposits

Magmatic-hydrothermal gold–copper deposits in post-subduction settings represent essential targets for mineral exploration, but controls on their formation remain controversial. The early Cretaceous lode Au districts that formed during lithosphere destruction of the North China Craton provide an ideal opportunity to better understand the key tectono-magmatic factors responsible for the genesis of Au-rich deposits in post-subduction settings. Here, we present a LA-ICP-MS study of silicate melt inclusions and sulfide inclusions from ore-related mafic to intermediate rocks in the central Taihangshan Au district in the interior of the North China Craton to constrain the content and evolution of magmatic ore metals ± volatiles. The results, combined with numerical modeling, suggest that the ore-related magmas contained only a few ng/g Au, which is similar to the Au content of non-mineralization-related mafic to intermediate magmas worldwide. The low Au content of the lode Au-related magmas suggest that large volumes of magmas had to accumulate in the middle to lower crust through trans-lithospheric fault systems to produce the lode Au deposits. It is further suggested that the lode Au-related magmas were alkali-rich, hydrous, oxidized and relatively rich in sulfur and chlorine (mafic melt inclusions contain 0.14‒0.24 wt% S and 0.1‒0.2 wt% Cl). These properties are considered critical for the generation of auriferous ore fluids. By comparing the tectono-magmatic setting of the giant Jiaodong Au province (~ 4000 t Au) with the central Taihangshan district (~ 150 t Au), we propose that the much larger total Au tonnage of the Jiaodong district results from the accumulation of a much larger volume of ore-forming magmas at deep crustal levels, induced by a stronger degree of lithosphere modification. In addition, given that the composition of lode Au-related magmas is similar to that of porphyry Cu–Au-related magmas, the lack of giant, early Cretaceous porphyry Cu–Au deposits in the North China Craton suggests that strong extensional settings favor the formation of lode Au deposits instead of porphyry Cu–Au deposits. The present study, therefore, has general implications for the genesis of Au-rich deposits in strongly extensional settings.

Single-atom catalysts with anionic metal centers: Promising electrocatalysts for the oxygen reduction reaction and beyond

Ongoing efforts to develop single-atom catalysts (SACs) for the oxygen reduction reaction (ORR) typically focus on SACs with cationic metal centers, while SACs with anionic metal centers (anionic SACs) have been generally neglected. However, anionic SACs may offer excellent active sites for ORR, since anionic metal centers could facilitate the activation of O2 by back donating electrons to the antibonding orbitals of O2. In this work, we propose a simple guideline for designing anionic SACs: the metal centers should have larger electronegativity than the surrounding atoms in the substrate on which the metal atoms are supported. By means of density functional theory (DFT) simulations, we identified 13 anionic metal centers (Co, Ni, Cu, Ru, Rh, Pd, Ag, Re, Os, Ir, Pt, Au, and Hg) dispersed on pristine or defective antimonene substrates as new anionic SACs, among which anionic Au and Co metal centers exhibit limiting potentials comparable to, or even better than, conventional Pt-based catalysts towards ORR. We also found that anionic Os and Re metal centers on the defective antimonene can electrochemically catalyze the nitrogen reduction reaction (NRR) with a limiting potential close to that of stepped Ru(0001). Overall, our work shows promise towards the rational design of anionic SACs and their utility for applications as electrocatalysts for ORR and other important electrochemical reactions.

Cumulants and correlation functions of net-proton, proton, and antiproton multiplicity distributions in Au+Au collisions at energies available at the BNL Relativistic Heavy Ion Collider

We report a systematic measurement of cumulants, $C_{n}$, for net-proton, proton and antiproton multiplicity distributions, and correlation functions, $\kappa_n$, for proton and antiproton multiplicity distributions up to the fourth order in Au+Au collisions at $\sqrt{s_{\mathrm {NN}}}$ = 7.7, 11.5, 14.5, 19.6, 27, 39, 54.4, 62.4 and 200 GeV. The $C_{n}$ and $\kappa_n$ are presented as a function of collision energy, centrality and kinematic acceptance in rapidity, $y$, and transverse momentum, $p_{T}$. The data were taken during the first phase of the Beam Energy Scan (BES) program (2010 -- 2017) at the BNL Relativistic Heavy Ion Collider (RHIC) facility. The measurements are carried out at midrapidity ($|y| <$ 0.5) and transverse momentum 0.4 $<$ $p_{\rm T}$ $<$ 2.0 GeV/$c$, using the STAR detector at RHIC. We observe a non-monotonic energy dependence ($\sqrt{s_{\mathrm {NN}}}$ = 7.7 -- 62.4 GeV) of the net-proton $C_{4}$/$C_{2}$ with the significance of 3.1$\sigma$ for the 0-5\% central Au+Au collisions. This is consistent with the expectations of critical fluctuations in a QCD-inspired model. Thermal and transport model calculations show a monotonic variation with $\sqrt{s_{\mathrm {NN}}}$. For the multiparticle correlation functions, we observe significant negative values for a two-particle correlation function, $\kappa_2$, of protons and antiprotons, which are mainly due to the effects of baryon number conservation. Furthermore, it is found that the four-particle correlation function, $\kappa_4$, of protons plays a role in determining the energy dependence of proton $C_4/C_1$ below 19.6 GeV, which cannot be understood by the effect of baryon number conservation.