Microstructure Of Carbide Research Articles

Phase Field Simulation and Experimental Study of Carbide Precipitation Process in Submerged Arc Welding on Descaling Roll

The mechanical properties of surfacing layers are significantly affected by the precipitation and evolution of carbides in nickel-based alloys. At present, the study of carbide precipitation in a Ni-Cr-B-Si surfacing layer is described by using the phase field method. In this paper, the true Gibbs free energy of the M23C6 carbide phase in Ni-Cr-C ternary alloy was established by the CALPHAD method and thermodynamic database. The growth and coarsening process of M23C6 carbide was simulated based on phase field method. The microstructure of M23C6 carbide of Ni-Cr-C alloy at 1373 °C isothermal aging time was observed by scanning electron microscope (SEM). The results show that the growth and coarsening of the precipitated M23C6 carbide phase are undergone through multiple processes during isothermal aging. First, a single precipitate core is formed, and then the single precipitate continues to coarsen and grow, forming a lamellar structure. Two precipitates contact to form a single rod-like structure, and multiple precipitates form slender rod-like structures. Finally, the contacting elongated rod-like structures grow, forming a typical layered eutectic carbide. The precipitation behavior, growth, and coarsening process of M23C6-type carbides in Ni-Cr-B-Si series alloys are explored through phase field simulation and experimental research in this paper. A theoretical basis is provided for the rational control and distribution of carbides in surfacing layers. A reference is also offered for optimizing the nickel-based superalloy materials used for surfacing the surface of descaling rolls.

Effect of Ni Addition on the Microstructure and Mechanical Properties of Coarse-Grained Cemented Carbides Using the Dissolution Method with WO3 as the Raw Material

Effect of Ni Addition on the Microstructure and Mechanical Properties of Coarse-Grained Cemented Carbides Using the Dissolution Method with WO3 as the Raw Material

Microstructure, mechanical and corrosion performance of TiC steel-bonded carbides with different heat treatments

Microstructure, mechanical and corrosion performance of TiC steel-bonded carbides with different heat treatments

The Effect of the Heating Process on the Warm Deformation Behavior and Microstructure of Medium Mn Steel

This study investigates the effects of heating processes on the microstructure and deformation behavior of medium Mn steel during warm deformation. The samples treated by austenitization maintain an austenitic microstructure during deformation, which transforms into martensite upon cooling to room temperature. In contrast, the room‐temperature microstructure of samples deformed by direct heating to the deformation temperature is dependent on the deformation temperature: deformation above Ac3 results in a martensitic microstructure; deformation within the intercritical range (Ac1–Ac3) produces a mixture of ferrite, martensite, and austenite; and deformation below Ac1 yields a microstructure of ferrite and carbides at room temperature. When the microstructure only contains austenite during deformation, medium Mn steel exhibits excellent work‐hardening capability, characterized by a gradual increase in work hardening with strain until a dynamic balance between hardening and softening. Conversely, when ferrite is present in the microstructure during deformation, the flow behavior is dominated by ferrite, resulting in poor work‐hardening capability, with peak stress reached at low strain, followed by dynamic softening. Microstructure and stress–strain curve analyses reveal that, below 640 °C, ferrite exhibits higher strength than austenite. At 640 °C, the strengths of ferrite and austenite are approximately equal; above this temperature, austenite surpasses ferrite in strength.

L12 strengthening of WC-CoNiFe cemented carbides by spark plasma sintering

Binder phase has very significant effect on the growth of WC grains, grain morphology, the microstructure and properties of cemented carbide. In this paper, Co, Fe and Ni were used as binder phase, cemented carbides with different sintering temperatures were prepared by spark plasma sintering. The differences in the microstructure and properties of 10Co and 8Co-3NiFe were analyzed. The results showed that the 8Co-3NiFe cemented carbide generated the highly ordered FeNi3 phase with FCC of L12. The addition of Fe and Ni decreases the melting point of 8Co-3NiFe, makes the grain morphology of WC more rounded and more homogeneous distribution of the cemented carbide microstructure. The WC grain sizes of the 10Co and 8Co-3NiFe cemented carbides are very similar, but the 8Co-3NiFe cemented carbide shows a slight increase in grain size. Low-temperature densification of the 8Co-3NiFe cemented carbide can be achieved at sintering temperature of 1050 °C. The fracture toughness of the 8Co-3NiFe cemented carbide improves by about 10 % compared to the 10Co cemented carbide.

Effect of processing parameters and carbon to metal ratio on microstructure and mechanical properties of (MoTaTiVW)Cx high entropy carbide produced by reactive spark plasma sintering

(MoTaTiVW)Cx high entropy ceramics with varying carbon to metal ratio in the range of 0.75–0.97 were synthesized by by reactive spark plasma sintering. The effect of ball milling time on particle size, phase evolution and carbon pick-up due to toluene decomposition were studied. Formation of single-phase high entropy carbide having face-centered cubic (FCC) crystal structure was confirmed by X-ray diffraction (XRD), electron backscattered diffraction (EBSD) and Selected area diffraction pattern (SAED) analysis of the sintered compacts. Transmission Kikuchi Diffraction images revealed presence of equiaxed nature of the grains. Transmission electron microscopy images revealed the presence of an intergranular phase at grain boundaries and triple junctions. 3D-Atom Probe Tomography studies showed uniform distribution of elements within the grains with some segregation of impurity elements Fe and Co to the grain boundaries indicating minor contribution of liquid phase sintering to densification. The grain size of single-phase sintered compacts ranged between 1.69 ± 0.60 μm to 4.6 ± 1.0 μm. A low sintering temperature and higher milling time resulted in finer grain size The microhardness was found to increase with milling time and C/M ratio. The microhardness, Young's modulus and indentation fracture toughness lied between 2221 HV0.1 to 2732 HV0.1, 370 GPa–473 GPa, 3.6 MPa m1/2 to 4.4 MPa m1/2, respectively. The highest microhardness and indentation fracture toughness was found to be 2732 ± 80 HV0.1 and 4.4 MPa m1/2 on par with reported literature for other high entropy carbides.

Microstructure, thermal, and mechanical properties of hierarchical porous silicon carbide made by direct ink writing

AbstractHierarchical porous silicon carbide (SiC) ceramics were fabricated by combining particle‐stabilized emulsions and three‐dimensional (3D) printing. Direct ink writing (DIW) was used as the 3D printing technique. The formulation for successful printing is discussed in relation to the rheology of the emulsions. The SiC emulsions were able to be printed with a lower storage modulus (G′) and apparent yield shear stress (τy) than previously reported SiC ink pastes. The printed and sintered porous SiC ceramics possess a total porosity of 73.7% with an average pore size within the filaments of 2.2 µm in diameter. A hierarchical pore structure that contains pore sizes of about 250 µm, around 1–10 µm and smaller than 0.5 µm can be observed in the microstructure and pore size distribution. The mechanical properties showed a good strength‐to‐density ratio, and the thermal conductivity was reduced to 4.9 W/m·K. This study provides a new reliable approach for fabricating hierarchical porous SiC ceramics with low thermal conductivity.

Effect of oscillation frequency on microstructure and properties of WC-Co cemented carbide prepared by hot oscillating pressing

In this study, a novel hot oscillating pressing (HOP) was used to prepared WC-Co cemented carbides under various oscillation frequencies. The effects of sintering frequencies on the density, microstructure, and mechanical properties of cemented carbides were systematically investigated. The results show that applying a specific oscillation frequency during the sintering process can greatly aid in the densification process, improve the uniformity of microstructure, help the grain refinement, and prevent the formation of abnormally large WC grains. The mechanical properties of the alloys showed a noticeable improvement as the oscillation frequency increased. The hardness and fracture toughness of cemented carbides were not significantly improved when the oscillation frequency was ≥5 Hz, with the optimal values reaching 1913 kg/m2 and 13.11 MPa.m1/2, in turn. The improvement in mechanical properties of cemented carbide can be mainly attributed to higher density, grain refinement, microstructure uniformity and the increase of dislocation/twins caused by plastic deformation.

Effect of theoretical volume fraction (TVF) of reinforcements on Al5083/SiC and Al5083/ZrB2 surface composites produced by friction stir processing

This study focuses on the effects of theoretical volume fraction (TVF) on the microstructure and mechanical properties of silicon carbide (SiC) and zirconium diboride (ZrB2) ceramic reinforced Al5083 surface composites (SC). Al5083–H111 was used as the base material (BM), SiC and ZrB2 were used as reinforcement materials, and TVFs were determined as 5, 10, 15, and 20 % for SCs produced by the friction stirring process (FSP). Macrostructure, microstructure, X-ray diffraction (XRD) analysis and mechanical properties such as microhardness, tensile strength (UTS), and wear behaviour were characterised. When the TVF and AVF values of SiC and ZrB2 particles were compared, it was found that the AVFs were lower than the TVFs. Significant decreases in the changes in the SZ areas of SiC and ZrB2 particle SCs were detected depending on the reinforcement size. In the time-dependent axial load graphs of SiC and ZrB2 reinforced samples, load values ranging from 7800 to 8200 N were obtained and it was determined that these values were sufficient for friction heat, hydrostatic pressure, and plasticisation in FSP. As a result of mechanical characterisation processes, the microhardness values and wear rates of ZrB2 reinforced SCs in the stir zone (SZ) were higher than SiC reinforced SCs. When the reinforcement particles were compared, it was observed that ZrB2 reinforced SCs exhibited higher microhardness and wear resistance than SiC reinforced SCs. As a result of all tests and investigations, it was determined that the ideal TVFs were 15 % for SiC reinforced SCs and 5 % for ZrB2 reinforced SCs. The microhardness value of ZrB2 reinforced SC with 20 % TVF was 119.6 HV, while the UTS and volume loss values of ZrB2 reinforced SC with 5 % TVF were found to be the highest values with 305.86 MPa and 1.83 mm3, respectively. Compared to BM, these values showed significant improvements in mechanical test results, especially in wear behavior. The results obtained showed an improvement of 55 % in microhardness, 3.3 % in UTS values, and 309 % in wear behavior.

Synthesis, microstructure, mechanical and tribological properties of high-entropy carbides (WZrNbTaTi)C-SiCw

In this work, composite high-entropy carbides (WZrNbTaTi)C-x SiCw (x = 0, 5 %, 10 %, 15 %, 20 %) are prepared using the two-step fast hot-pressing sintering (TSFHPS) method. The whiskers in the samples are evenly dispersed and well integrated with the ceramic matrix, forming high density materials. The mechanical properties and tribological properties at room temperature are studied, revealing that the addition of SiCw improves the performance of the materials. When the whisker content is 15 %, the hardness and fracture toughness of composite ceramics are the highest, which are 22.6 GPa and 6.8 MPa m1/2, respectively. The bending strength of the samples increases monotonically with the increase of whisker content, and reaches 639.2 MPa at 20 % content. At the same time, the addition of an appropriate amount of SiCw prevents the propagation of micro-cracks and the expansion of oxidative wear, thereby reducing the friction coefficient and wear rate, and improving the wear resistance of high-entropy carbides.

Study on Evolution Behavior of Carbides in Industrial‐Grade American Iron and Steel Institute M35 High‐Speed Steel Produced by Electroslag Remelting

In order to optimize the heating schedule before forging and improve the breaking and deformation effects of carbides in high‐speed steel, it is of great significance to study the transformation of M2C carbides at high temperatures. The evolution of carbides in the industrial‐grade American Iron and Steel Institute M35 steel produced by electroslag remelting (ESR) is analyzed and observed using thermodynamic calculations and experimental methods. The results indicate that the carbides in the ESR ingot are mainly MC and M2C, and the microstructures of M2C carbides with the highest volume fraction are lamellar and brain like. As the heating temperature increases and holding time prolongs, the lamellar M2C carbides gradually transform into MC and M6C carbides, accompanied by protrusion, dissolution, separation, and spheroidization of the microstructure, until significant coarsening occurs at 1180 °C for 90 min. The newly transformed carbides are embedded and stacked with each other, occupying the original position of M2C carbides. Based on the theories of Gibbs free energy and atomic diffusion, the evolution mechanism of M2C carbides is discussed. Ultimately, the appropriate heating schedule is proposed, and it is validated by combining the characteristics of carbides after forging.

Microstructure and wear properties of carbide reinforced high-entropy alloy coatings on EA4T steel via vibration assisted TIG-cladding using WC core spiral AlCuNiCrTi-CWW

Aiming at the difficulty preparing high-entropy alloy (HEA) coating by adding carbide powder using TIG-cladding, the WC core spiral CWW prefabricated vibration assisted TIG-cladding method is proposed in this work. The HEA coating (S1-coating) was prepared on the EA4T steel using AlCuNiCrTi cable-type welding wire (CWW) via TIG-cladding, then the WC reinforced HEA coating (S2-coating) was produced using spiral AlCuNiCrTi-CWW with WC powder core by TIG-cladding. Finally, another WC reinforced HEA coating (S3-coating) via vibration assistance TIG-cladding using the same material as S2-coating. The S1-coating is composed of BCC and FCC solid solutions. Except for the same phases as S1-coating, TiC appeared in the S2-coating and the S3-coating. Due to the grain refinement effect caused by vibration, the S3-coating has the maximum microhardness (725HV), lowest friction coefficient (0.42) and the smallest volume wear rate (0.1397 × 10−4 mm3/N·m). The addition of vibration assistance effectively improves the microhardness and wear resistance of the coating without changing CWW composition.

Enhanced fracture toughness of high entropy boride by adding SiC

The effect of SiC content (10 vol%, 20 vol% and 30 vol%) and sintering temperature (1800 °C, 1900 °C and 2000 °C) on the microstructure and mechanical properties of high entropy boride-silicon carbide (HEB-SiC) composites were systematically investigated in this work. The densification was gradually increased with the increase of SiC content and sintering temperature. More specially, the densification of HEB-30 vol% SiC composite obtained at 2000 °C was as high as 99.1 %. As for the mechanical properties, the dense HEB-30S-2000 composite possessed the highest fracture toughness (5.24 MPa m1/2) and Vickers hardness (28.5 GPa). The above significantly enhanced fracture toughness was closely pertained to the fracture modes adjusting. In details, after the addition of SiC, the branching and bridging of crack, the rupture of large SiC grain, and the deflection of crack existing near the HBE matrix and SiC particles jointly promote the improvement of fracture toughness. Besides, the Vickers hardness increased linearly with the relative density increasing. A simplified equation was established, which could effectually reflect the linear connection between the Vicker hardness and relative density (SiC content) of HEB-SiC composites. It will certainly play an important guiding role in the further development of HEB-SiC composites.

Microstructure, phase evolution and mechanical properties of nickel-silicon carbide reinforced Ti6Al4V alloy processed by pulsed electric current sintering

In this work, fully densified Ni–SiC reinforced Ti6Al4V matrix composites were consolidated by pulsed electric current sintering (PECS) technique. The microstructural evolution and mechanical properties of the developed composites with varying SiC contents were investigated. The microstructural study revealed in-situ precipitation of TiC, Ti5Si3 and Ti3SiC2 strengthening phases within the composites. The α colony size in the composites was notably reduced compared to the fabricated SiC-deficient samples due to the addition of SiC additive into the Ti6Al4V alloy matrix. The in-situ precipitated phases enhanced the mechanical properties of the composites. Composite reinforced with 10 wt% SiC (TNi10SiC) displayed the highest hardness value of 609.8 ± 50.9 HV0.5 among the sintered samples, translating to an increment of about 88 % compared to the unreinforced sample T. Among the sintered samples, the highest flexural strength of 2094.32 ± 97.67 MPa was obtained for the TNi5SiC composite, after which the flexural strength deteriorates with increasing SiC content as witnessed in TNi10SiC composite with the least flexural strength of 863.67 ± 71.57 MPa due to agglomeration of the reinforcement phases within the composite. Samples reinforced with 0 wt% SiC experienced a ductile fracture, and the composites containing 2.5 wt% - 5 wt% SiC content witnessed intergranular and interlamellar fractures. However, at higher SiC content, reinforcement pull-out and debonding of the agglomerated reinforcement phases predominates, and composites fail by brittle fracture.

Effects of Ti/Nb Dual-Element Addition on the Microstructure and Properties of Tungsten Carbide-Reinforced Laser Cladding Coatings

Metal-ceramic composite coatings are produced on the surface of equipment components by laser cladding, improving the abrasive wear resistance of components and extending their service life. However, defects such as brittleness and cracks limit the wide application of metal-ceramic clad coatings in the field of construction machinery. In the present study, a dual-element (Ti/Nb) alloying method is innovatively adopted to regulate the microstructure and mechanical properties of tungsten carbide (WC)-reinforced clad coatings. Experimental results show that with the introduction of Ti/Nb, novel reinforcements are in-situ synthesized in the cladding coatings with two different kinds of morphologies: one is a core-shell carbide with the core of pure TiC and a shell of (Ti,Nb,W)C multiple carbide; the other is a (Ti,Nb,W)C multiple carbide. With 8 wt.% Ti/Nb addition, the newly formed multiple carbides with the appropriate content are well-dispersed and distributed in the clad coating, which effectively transfers load, inhibits the initiation and expansion of micro-cracks, and resists the wear damage of hard abrasive particles, solving the technical problems of the simultaneous improvement of toughness and abrasive wear resistance of metal-ceramic laser cladding coatings.

Study of the Phase Composition and Microstructure of Complex Carbide (Ti, W)C Obtained by Spark Plasma Sintering of WC and TiC Powders

Study of the Phase Composition and Microstructure of Complex Carbide (Ti, W)C Obtained by Spark Plasma Sintering of WC and TiC Powders

Effects of Cu Addition on the Microstructures and Properties of WC-12Co Cemented Carbides Additively Manufactured by Laser Powder-Bed Fusion

Effects of Cu Addition on the Microstructures and Properties of WC-12Co Cemented Carbides Additively Manufactured by Laser Powder-Bed Fusion

Comparison of Microwave Versus Conventional Furnace Heat Treatments of Carbide Composite Thermal Spray Coatings

Thermal spraying has become an industrial standard in the production of wear-resistant WC-Co and Cr3C2-NiCr composite coatings. However, generating optimum wear-resistant nano-reinforced carbide microstructures within the coatings remains challenging. The alternative two-step approach in this work involves coating formation under high energy conditions to generate maximum carbide dissolution, followed by heat treatment to precipitate nanocarbides. Microwave heating of particulate materials has been reported to offer several benefits over conventional furnace heating, including faster heating rates, internal rather than external heating, and acceleration of reactions/phase transformations at lower temperatures. This novel work explored the use of microwaves for heat treatment (as distinct from melting) of WC-Co and Cr3C2-NiCr thermal spray coatings and contrasted the rate of phase development with that from conventional furnace treatment. Coatings were successfully microwave heat-treated to generate the same phase composition as furnace treatment. Both treatments generated comparable results in the Cr3C2-NiCr system. The WC-Co system achieved a much more crystalline structure in a dramatically shorter time relative to the conventional furnace-treated sample. The results are contrasted as a function of material and microstructure interaction with microwaves and the critical phase transition temperatures to account for the observed responses.

Comparative Study on Microstructure and Mechanical Properties of Coarse-grained WC-based Cemented Carbides Sintered with Ultrafine WC or (W+C) as Additives

Comparative Study on Microstructure and Mechanical Properties of Coarse-grained WC-based Cemented Carbides Sintered with Ultrafine WC or (W+C) as Additives

Effect of Carbides on Thermos-Plastic and Crack Initiation and Expansion of High-Carbon Chromium-Bearing Steel Castings

The bearing steel’s high-temperature brittle zone (1250 °C–1100 °C), second brittle zone (1100 °C–950 °C), and low-temperature brittle zone (800 °C–600 °C) were determined by the reduction in area and true fracture toughness. The crack sensitivity was strongest at temperatures of 1200 °C, 1000 °C, and 600 °C, respectively. Various experimental and computational methods were used to establish the phase type, microstructure, size, and mechanical properties of carbides in bearing steel. The critical conditions for crack initiation in the matrix (FCC-Fe, FCC-Fe, and BCC-Fe)/carbides (striped Fe0.875Cr0.125C, netted Fe2.36Cr0.64C, and spherical Fe5.25Cr1.75C3) were also investigated. The values for the high-temperature brittle zone, the second brittle zone, and the low-temperature brittle zone were 13.85 MPa and 8.21 × 10−3, 4.64 MPa and 6.52 × 10−3, and 17.86 MPa and 1.86 × 10−2, respectively. These were calculated using Eshelby’s theory and ABAQUS 2021 version software. The ability of the three carbides to cause crack propagation was measured quantitatively by energy diffusion: M3C > MC > M7C3. This study analyzed the mechanism of carbide precipitation on the formation of high-temperature cracks in bearing steel casting. It also provided the critical conditions for carbide/matrix interface cracks in bearing steel continuous casting, thus providing effective support for improving the quality of bearing steel casting.