In urban fire, the structure will not only be subjected to high temperature, but also cooled by fire hydrant. This paper presents the experimental results of the residual mechanical performance and the complete compressive stress–strain relationship of recycled pebble aggregate concrete (RAC) after exposure to high temperature of 20 to 600 ℃ and cooled by fire hydrant. In the experiments, five different concrete compositions were designed by substituting natural coarse aggregates with recycled coarse aggregates at the replacement ratios of 0%, 30%, 50%, 70% and 100%. Results exhibit that with the increase of exposure temperature, the surface color of the specimens changes from light to dark, the mass of RAC first increases and then decreases, and the residual mass of RAC at 200 ℃ is higher than that at room temperature. The compressive strength and the strain at the peak point decrease rapidly with the increase of temperature. The compressive strength and the strain at the peak point fluctuate with the increase of aggregate replacement percentage, and the temperature and aggregate replacement percentage have little effect on the ductility of RAC. The residual bearing capacity calculation method and constitutive equation of RAC after high temperature exposure and cooled by fire hydrant are proposed and verified. The accuracy of the constitutive equation is verified by ABAQUS finite element analysis software.