Combustion Of Brown Coal Research Articles

Resolving emission factors and formation pathways of organic gaseous compounds from residential combustion of European brown coal

Residential combustion of brown coal can be an important source of ambient air pollution in areas with abundant brown coal deposits, such as Eastern Europe or China. The exhaust emission contents may vary regionally depending on the fuel composition, calling for detailed characterization of emissions from different coal types. In this work, the organic gaseous emissions of European brown coal combusted in a modern chimney stove -type residential appliance were measured by a proton transfer reaction time-of-flight mass spectrometer. Of three consecutive batches of brown coal briquettes, the first batch produced two-fold emission (144 ± 52 mg/MJ) of organic gaseous compounds (OGCs) compared to the later batches (71 ± 35 mg/MJ). The compositions between the batches were, however, relatively similar. Carbonyls accounted for 36 ± 3.0% of the identified emission factors, while aromatic hydrocarbons and oxygenated aromatic compounds contributed 19 ± 3.4% and 16 ± 1.8%, respectively. The complex and overlapping chemical processes within batch combustion were exposed by non-negative matrix factorization, giving insight into the temporal variation in the formation pathways of the OGCs. The OGCs were separated into five factors revealing the chemical fingerprints of the main processes leading to formation of, for example, substituted or single-ring aromatic hydrocarbons. Oxygenated aromatic compounds were related to a distinct factor, which was proposed to form specifically from decomposition of the lignin residues of the brown coal. OGCs from brown coal combustion were estimated to have notable secondary particle formation potential: in photochemical conditions, they may double the organic particulate emission, while reactions in dark conditions may lead to excessive nitrophenol formation.

Evaluation of brown coal fly ash for stabilising expansive clay subgrade: A sustainable solution for pavement construction

Brown coal fly ash (BCFA) is a lower-quality type of fly ash produced through brown coal combustion, and its disposal in landfills raises environmental concerns. This study, for the first time, evaluates the feasibility of using BCFA for stabilising expansive clay subgrade in pavement construction. Various engineering tests were conducted, including unconfined compressive strength (UCS), repeated load triaxial (RLT), soaked California bearing ratio (CBR), direct shear, and shrink-swell tests. The results indicated that adding BCFA increased UCS, resilient modulus, soaked CBR, and cohesion while reducing shrinkage-swell index and shrinkage/swell strain. The highest resilient modulus (82.52 MPa) and soaked CBR (3.41 %) were achieved with 3 % BCFA content. These findings recommend using 3 % BCFA as the optimum content for stabilising expansive clay subgrade. This research fills a gap by assessing the application of BCFA for stabilising expansive clay soil, providing insights for sustainable utilisation of this abundant waste material in construction.

Ignition behavior of a mixture of brown coal and biomass during the movement of fine particles in a hot air flow

The combustion of brown coal, biomass and their mixtures was studied experimentally and analytically. The experimental research was conducted using a laboratory setup that reproduced the conditions of combustion of pulverized solid fuel in a boiler furnace. Thermogravimetric analysis was employed as part of the analytical study to determine the key characteristics of combustion of solid fuels, such as temperatures at which the ignition and burnout occur, as well as the combustion index. Scanning electron microscopy was utilized to analyze the surfaces of coal and wood particles to detect pores, cracks and channels. To determine the tendency of the solid fuel mixture to slag heat exchangers in boiler furnaces, the ash residue characteristics (iron oxide deposits, active alkali, calcium sulfate compounds) were obtained. Biomass is more reactive than brown coal. Its ignition delay times at 500 °C and 750 °C are 57 % and 25 % lower, respectively, than those for coal. The higher the biomass content in the solid fuel mixture, the lower the ignition delay time. The heating source temperature at which the coal/biomass fuel mixture ignites corresponds to the temperature at which biomass ignites. With a larger proportion of biomass, the temperature during the fuel mixture combustion goes down, while the combustion index increases. On the basis of the findings of the conducted research, optimal proportions of solid fuel components were found (80 % brown coal, 20 % biomass). Also, fuel preparation and feeding systems for pulverized fuel combustion and fluidized bed combustion of optimal fuel mixtures in a coal-fired boiler furnace were proposed.

Study of synergistic effect of fly ash and superabsorbent polymers on properties of cement pastes

The main goal of this study is to observe changes in microstructural properties and the mutual interaction of cement pastes containing superabsorbent polymers (SAPs) and fly ash. SAP is a type of hydrogel additive, able to absorb large amounts of liquid in its structure. In cement-based materials, it is often used in the early stages of matrix hydration to absorb excess mixing water and to release it in the later stages, which is even more desirable when the material is exposed to higher temperatures. Another research goal is a partial substitution of binder (Portland cement) by the energy by-product of high-temperature ash, produced by the combustion of brown coal. A further goal is the observation of the interactions of these binders with the SAPs on the microstructural scale. For this purpose, computed tomography (CT), X-ray diffraction (XRD), differential thermal analysis (DTA), and scanning electron microscopy (SEM) were performed. Basic physical and mechanical properties such as compressive strength, flexural strength, and bulk density were also determined. In the early stages of hydration, viscosity and chemical shrinkage were determined. From the results obtained, it is obvious that the presence of SAPs has a significant impact on the properties of cement pastes. From the two tested SAPs, SAP HM has a positive effect on volume stability and the flexural strength of the composite. The results of the mineralogical composition showed that the effect of SAP incorporation influences the crystallization of portlandite, alite, belite, and calcite. SEM analysis confirmed the results of XRD analysis and proved that hydration products can grow into SAP cavities. It is clear from the evaluation of the pore structure that SAPs increase the porosity of cement composites. The admixture of high-temperature fly ash has a positive effect on reducing the volumetric changes of mixtures. The mechanical parameters of the composite with fly ash were similar to that of the reference test specimens.

DISTRIBUTION OF NATURAL RADIONUCLIDES IN ASHES, COLLECTED BY THERMAL POWER PLANTS ELECTROSTATIC PRECIPITATOR

Link for citation: Nazirov R.A., Vede P.Yu., Tarasov I.V., Zhuikov A.V., Sergunicheva E.M., Tolochko O.R. Distribution of natural radionuclides in ashes, collected by thermal power plants electrostatic precipitator. Bulletin of the Tomsk Polytechnic University. Geo Аssets Engineering, 2023, vol. 334, no. 7, рр. 177-186. In Rus. Relevance. In the context of the global trend towards sustainable development, there is a problem of utilization of ash and slag waste from thermal power plants. The use of these wastes in the construction industry is of particular importance, due to the resource intensity of the production of building materials. Fly ash in the building materials composition can influence to a large extent the natural radioactivity of structures and increase the background radiation in the buildings. This is due to the fact that when coal combusting, fly ash is enriched with natural radionuclides. Purpose: to study the radioactivity of fly ash deposited on various fields of the electrostatic precipitator. Object: fly ash deposited on the fields of electrostatic precipitators from the combustion of Kansk-Achinsk brown coal in power boilers BKZ-420-140 PT-2. Methods. Content of Ra-226, Th-232 and K-40 was determined by gamma-spectrometric method, the value of the normalized indicator of specific effective activity for fly ash was calculated. The granulometric composition of the studied samples was determined by the method of laser diffraction analysis. Cluster analysis was used for statistical processing of test results. Results. The presence of two clusters in the content of natural radionuclides was established. In the first cluster, which has high radioactivity, the first and second fields of UGZ-4 electrostatic precipitators are combined, and in the second – the third and fourth fields. A correlation dependence was established between the numbers of fields of electrostatic precipitators, the size of ash particles, the content of Ra-226 and specific effective activity was established. No such dependence was found for Th-232. Conclusions. Particle distribution in the fields of electrostatic precipitators is multimodal. The nature of the distribution of each mode approaches the lognormal law. The content of radium and the value of the specific effective activity depend on the size of ash particles and are described by an exponential function. The highest content of Ra-226 is observed in the ashes deposited on the third and fourth fields of electrostatic precipitators, which indicates the enrichment of finer ash particles with this radionuclide. The conclusions obtained correspond to the well-known thesis about the increased radioactivity of ash particles that are not deposited by ash collection systems and enter the atmosphere together with flue gases. The proposed method for studying the distribution of natural radionuclides over the fields of electrostatic precipitators can be used to predict the radioactivity of particles that are not captured by the flue gas cleaning system and released into the environment.

Brown Coal and Logwood Combustion in a Modern Heating Appliance: The Impact of Combustion Quality and Fuel on Organic Aerosol Composition.

Residential heating with solid fuels is one of the major drivers for poor air quality in Central and Eastern Europe, and coal is still one of the major fuels in countries, such as Poland, the Czech Republic, and Hungary. In this work, emissions from a single-room heater fueled with brown coal briquettes (BCBs) and spruce logs (SLs) were analyzed for signatures of inorganic as well as semivolatile aromatic and low-volatile organic constituents. High variations in organic carbon (OC) emissions of BCB emissions, ranging from 5 to 22 mg MJ-1, were associated to variations in carbon monoxide (CO) emissions, ranging from 900 to 1900 mg MJ-1. Residential BCB combustion turned out to be an equally important source of levoglucosan, an established biomass burning marker, as spruce logwood combustion, but showed distinct higher ratios to manosan and galactosan. Signatures of polycyclic aromatic hydrocarbons emitted by BCB combustion exhibited defunctionalization and desubstitution with increasing combustion quality. Lastly, the concept of island and archipelago structural motifs adapted from petroleomics is used to describe the fraction low-volatile organic compounds in particulate emissions, where a transition from archipelago to island motifs in relation with decreasing CO emissions was observed in BCB emissions, while emissions from SL combustion exhibited the island motif.

Photochemical Aging Induces Changes in the Effective Densities, Morphologies, and Optical Properties of Combustion Aerosol Particles.

Effective density (ρeff) is an important property describing particle transportation in the atmosphere and in the human respiratory tract. In this study, the particle size dependency of ρeff was determined for fresh and photochemically aged particles from residential combustion of wood logs and brown coal, as well as from an aerosol standard (CAST) burner. ρeff increased considerably due to photochemical aging, especially for soot agglomerates larger than 100 nm in mobility diameter. The increase depends on the presence of condensable vapors and agglomerate size and can be explained by collapsing of chain-like agglomerates and filling of their voids and formation of secondary coating. The measured and modeled particle optical properties suggest that while light absorption, scattering, and the single-scattering albedo of soot particle increase during photochemical processing, their radiative forcing remains positive until the amount of nonabsorbing coating exceeds approximately 90% of the particle mass.

Catalytic co-combustion of biomass and brown coal in a fluidized bed: Economic and environmental benefits

The work is devoted to the study of combustion of brown coal, pine sawdust, and their mixtures in a fluidized bed of catalyst at 600–750°С. It is shown that an increase in the content of sawdust in a mixture with brown coal leads to an increase in the burnout degree of solid fuel from 94.4% to 99.9%, while the emission of greenhouse gases in the form of CO2 CO and NOx is reduced (CO2 from the biomass is not included in the balance). The high content of alkaline earth metal oxides (CaO and MgO) in the mineral part of brown coal, sawdust, and their mixtures eliminates the emission of sulfur oxides and the slagging of heat-exchange surfaces during the combustion in a fluidized bed of catalyst. The optimal temperature, when the highest burnout degree of the above fuels is achieved in the combustion is 750°С. It is also shown that the increase in temperature and the content of sawdust in the composition of the fuel mixtures has a positive effect on the economic and environmental process indicators.

Primjenom otpadne drvne biomase i Miscanthusa do održivog sektora termoenergetike u vremenu energetske tranzicije / Sustainable Energy Sector Using Waste Woody Biomass and Miscanthus in the Energy Transition

The thermal energy sector is very important at this time of global energy transition. From the aspect of stable energy independence, this is especially important in countries whose energy system is based on fossil fuels, especially coal. This is why decarbonisation of the energy sector is necessary, with a partial and gradual substitution of coal with renewable fuels. However, the use of these fuels is not always possible in existing plants. This refers to the establishment of energy, economic and environmentally acceptable proportion of the co-firing of these fuels, i.e. a mixture of coal and renewable fuels. The success of the establishment of this process is a function of several variables, the dominant of which are the aggregate properties of the fuel, basic and their mixtures, including the ash properties of those fuels. With the motive of contributing to a more successful implementation of the energy transition in the thermal energy sector, and with the aim of obtaining new scientific knowledge about the characteristics of the combustion of lignite and brown coal with different renewable fuels, laboratory research was carried out. In particular, different mixtures of lignite and brown coal, waste woody biomass and Miscanthus as a fast-growing energy crop were subjected to co-firing with variable process conditions. In addition to changing the composition of fuel mixtures, the test regimes included a significant change in process temperature (1250-1450 °C) and the primary measure of staged air supply to the furnace. In these combustion conditions, the emission of undesirable and harmful components into the environment, the efficiency of combustion, and the tendency of the ash from the fuel mixture to possible soiling of the heating surfaces in the furnace were evaluated - an analysis of the characteristics of the ash samples from the reaction zone and samples of the slag and ash to the furnace. Here, in both cases of co-firing, lignite and brown coal with different types of biomass, it was shown that in real conditions it is possible to establish a sustainable primary energy conversion process from fuel with a low unburnt carbon content in the slag (unburnt carbon content, UBC<1%) as well as low CO emission, below 350 mg/mn 3. At the same time, the NOx emission is below 320 mg/mn 3 during the co-firing of lignite mixtures at 1250 °C, and in the case of brown coal mixtures below 740 mg/mn 3 at 1450 °C. In both cases, the net CO2 emission decreases in proportion to the proportion of biomass in the mixture, while the SO2 emission is still high, at a level of up to 2500 mg/mn 3 for lignite mixtures and up to 6400 mg/mn 3 for brown coal mixtures. None of the treated types of biomass, up to the level of applicable content in the mixture with lignite and brown coal, does not worsen the progress of the process from the aspect of possible slagging/fouling heating surfaces in the boiler.

Modeling gas energy process of underground coal combustion

Protective coal pillars in underground mining are technological losses in the technology of extracting coal at the Angren deposit. During the mine operation, a significant part of the coal remains in the mine space. Extracting them is not possible with traditional energy-mechanical technologies. The paper considers a new extraction technology -energy-heat technological unmanned extraction of brown coal energy from the underground space of spent mine fields. The research results on the experimental sites of the technology of underground combustion of brown coal are presented. A simulation topological scheme of coal pillar combustion with a special chamber has been implemented. The burning rates of coal and heat fluxes in time are determined. The possibility of extracting the energy of coal in the form of a physical heat flow from the underground space of the mine to the daylight surface has been established.

Characteristics of the Joint Combustion of Brown Coal and Sewage Sludge under Nonisothermal Heating Conditions

Characteristics of the Joint Combustion of Brown Coal and Sewage Sludge under Nonisothermal Heating Conditions

Co-combustion of Sewage Sludge in the Coal-Fired Heating Plant

Due to greening of production of electricity and heat some owners of heating plant are changing their fuel mix from fossil fuels to biomass one. The stabilized sewage sludge is in this biomass category as well. New Czech national legislation limits are stricter in parameters of biological activity, so the owners of water treatment plant are looking for new utilization of their stabilized sludge. There are some possibilities in combustion or co-combustion of this sludge in currently heating plant. The article describes the trial test of stabilized sludge combustion on heating plant technology. The heating plant is originally designed for combustion of brown coal. The stabilized sludge was produced at the municipal wastewater treatment plant, from where it was transported to low-temperature (78 °C) drying technology, from where it was transported in granular form to the heating plant in Mladá Boleslav. The fuel mixture of trial test was in energetic ratio of 23% dried sludge and 77% brown coal. The sludge was transported into the boilers by pneumatic conveying, which is used in normal operation for conveying pelletized phytomass. The result shows an increase in SO2 emissions from the original 189.91 mg∙m-3 to 407.98 mg∙m-3 and an increase in NOx emissions from 148.45 mg∙m-3 to 181.46 mg∙m-3. There were also detected increasing NH3 emissions due to reac-tion of control system in SNCR technology od decreasing of NOx emissions. The trial test was done during full op-eration of the heating plant. During the test there was also a lower steam production, from originally 38.17 kg∙s-1 to 34.44 kg∙s-1, which is related to the lower LHV compared to the reference fuel. There were no major operation problems, except higher dustiness during unloading of sludge. Finally, the Czech legislative problems associated with the combustion of stabilized sewage sludge are mentioned. In the current system, the sludge is established as waste, which forbids the combustion of it in conventional heating plants, even though all emission legislative limits are complied with. Nowadays the Ministry of the Environment of the Czech Republic is working on new regulation, which will determine new category of solid alternative fuels and it will be solution of this situation.

COMBUSTION OF COMPOSITE PEAT-COAL MIXTURES IN A VORTEX FIREPLACE

The results of the numerical study of peat and brown coal combustion processes in avortex furnace with a power of 2.5 MW are presented. The processes in a vortex furnace with counterswirling flows with an upper supply of fuel and primary air and a supply of secondary air at thebottom of the furnace are studied. The removal of slag occurs in the bottom of the furnace. Theparticle size of fuel is from 25 microns to 250 microns. The calorific value of peat is 12.3 MJ/kg, thevolatile content is Vdaf=38 %, humidity is Wp=40 %, the stoichiometric coefficient is 7 kg air/kg fuel.The calorific value of brown coal is 13.9 MJ/kg, volatile content Vdaf=25-35 %, humidity Wp=30 %,stoichiometric coefficient is 4.3 kg air/kg fuel. The ash content of the fuel varies from Ap=20 % toAp=35 %. Ash content and humidity are Аp+Wp=65 %. It has been found that at ash content ofАp=30-35 % and humidity Wp=30-35 % the combustion process is unstable due to the problem ofremoving moisture and ash from the furnace volume. The temperature of the flue gases at the outletof the furnace when burning peat is found to be 1711 ºC, and the temperature of the ash is 1380 ºC,which ensures solid ash removal. The temperature of flue gases during the combustion of brown coalis 1888 ºC. A higher air excess coefficient is noted: a=2.36 in the process of burning peat and a=2.0when burning brown coal. The calculation results indicate that this ensures a high degree of cokecombustion in the particles that are captured: 99.8 % (peat particles) and 93.9 % (lignite). Theunderburning of fuel particles that are carried away is 0 % (peat) and 3.04 % (lignite). Theunderburning of fuel particles that are captured is 0.06 % (peat) and 0 % (lignite). The ratio ofoncoming flows is 0.2, which ensures the minimum hydraulic resistance of the furnace. Peat andbrown coal are similar to each other in chemical composition after the stages of coalification.Therefore, similar characteristics of combustion processes can be obtained by burning a composite mixture of peat/lignite (50 %/50 %), both in pulverized combustion and in the combustion of briquettegranules and water-fuel suspension – water-peat-lignite.

Effectiveness analysis of Maikuben brown coal combustion in the heating boiler “Kamkor-300”

This research presents the results of studying the efficiency of Maikuben brown coal combustion in low-power heating boilers using the case of the Kamkor-300 boiler. Improving the combustion efficiency of low-grade fuels is directly related to fuel economy and the decrease of toxic emissions into the atmosphere. The research results show the possibility of adjusting the boiler according to the “fuel-air” ratio in the furnace volume, without violation of its general heat exchange structure and changing the heat-transfer operation in the device. In the research the adjustment of the operation of a long-burning boiler with an upper air supply in order to increase the time of combustion gases dwell in the boiler furnace volume drum is proposed. It is also possible to reduce the excess air coefficient to 0.55 and to operate the boiler under conditions of oxygen deficiency. Under such conditions, in the presented boiler, additional synthesis gases are released during the combustion of low-grade coals, in particular of coal rank “B”, to obtain an additional thermal effect. The resulting thermal effect leads to an increase of the boiler efficiency and its operational and economic indicators.

Potentially Economic Concentrations of Rare Earth Elements and Gold in Power Plant Coal Combustion Products (Far East, Russia)

The distribution of rare earth elements (REE) and gold (Au) in fly ash released during combustion of brown coal from the Pereyaslavskoye (Siberia) and Erkovetskoye (Far East) deposits has been investigated. Coal combustion was carried out in two locations: the boiler unit of the Blagoveshchenskaya coal-fired power plants (CFPP), equipped with an electrostatic precipitator (ESP); and at the Amur Experimental and Technological Complex (ETC) with the aim of separating the combustion products (slag, fly ash, sludge). It was found that in both processes the highest contents of REE (400 and more ppm) and Au (up to 0.29 ppm) are concentrated in fly ash. These characteristics of coals were used as the basis for the author's calculation of the predicted resources of REE and Au under the conditions of the annual operation of firstly one boiler unit, and then five, equipped with an ESP. Further research by the authors will be aimed at improving the degree of recovery of concentrates through the development of technologies at pilot plants such as ETC “Amur”.

Genotoxic and inflammatory effects of spruce and brown coal briquettes combustion aerosols on lung cells at the air-liquid interface

Solid fuel usage in residential heating and cooking is one of the largest sources of ambient and indoor air particulate matter, which causes adverse effects on the health of millions of peoples worldwide. Emissions from solid fuel combustion, such as biomass or coal, are detrimental to health, but toxicological responses are largely unknown. In the present study, we compared the toxicological responses regarding cytotoxicity, inflammation and genotoxicity of spruce (SPR) and brown coal briquette (BCB) combustion aerosols on human alveolar epithelial cells (A549) as well as a coculture of A549 and differentiated human monocytic cells (THP-1) into macrophages exposed at the air-liquid interface (ALI). We included both the high emissions from the first hour and moderate emissions from the third hour of the batch combustion experiment in one ALI system, whereas, in the second ALI system, we exposed the cells during the whole 4-hour combustion experiment, including all combustion phases. Physico-chemical properties of the combustion aerosol were analysed both online and offline. Both SPR and BCB combustion aerosols caused mild cytotoxic but notable genotoxic effects in co-cultured A549 cells after one-hour exposure. Inflammatory response analysis revealed BCB combustion aerosols to cause a mild increase in CXCL1 and CXCL8 levels, but in the case of SPR combustion aerosol, a decrease compared to control was observed.

Use of Ashes from Lignite Combustion as Fillers in Rubber Mixtures to Reduce VOC Emissions.

This paper presents the use of ashes from brown coal combustion (BCA) as fillers in rubber mixtures, to reduce the emission of volatile organic compounds. Two types of ash, BCA1 and BCA2, were selected as fillers for styrene–butadiene rubber (SBR). The ashes were produced during the treatment of brown coal at the Bełchatów Power Plant in the years 2017 and 2018. The morphology and chemical composition of the ash were tested. Morphology studies using scanning microscopy showed differences in the grain sizes of the ashes, and EDS analysis showed a difference in their chemical compositions. Vulcanizates with different weight proportions of the individual ashes were produced. Mixtures were made with the addition of 10–30 pts. wt. ashes per 100 g of SBR. The addition of BCA1 ash at 10 and 30 pts. wt. reduced the emission of volatile organic compounds (VOC) while maintaining the good strength properties of the mixtures.

Neutralization of Sulfur Compounds during the Filter Combustion of Brown Coals with Mineral Additives

Neutralization of Sulfur Compounds during the Filter Combustion of Brown Coals with Mineral Additives

Extending the Life Cycle of Cement Binders by Partially Replacing Portland Cement with Different Types Fluidized Bed Combustion Fly Ash

A significant reduction in the CO2 emission associated with cement production is obtained by partially replacing Portland cement with supplementary cementing materials (SCM’s): e.g., siliceous fly ash or granulated blast furnace slag. In the near future, the limited availability of these materials will do more attractive to use ashes from combustion in fluidized bed boilers, which currently are mainly deposited in various landfills. Paper identifies the effect of Fluidized Bed Combustion (FBC) fly ash from both hard and brown coal combustion on the durability of mortars exposed to sodium and magnesium sulfate solution at different curing temperature: 20 and 5 °C. The evaluation was based on the results of long-term linear changes of mortar samples made with Portland cement and different amounts of FBC fly ash addition stored in a corrosive environment, as well as the evaluation of the type of formed corrosion products using XRD and microstructural studies (SEM/EDS). It has been shown that amount of FBC fly ashes used in binders significantly determines sulfate resistance of prepared cements as well as its chemical composition. By using fluidized ashes, the sulfate resistance of cement binders can be achieved with their content even of 15%.

Self-Immobilizing Metals Binder for Construction Made of Activated Metallurgical Slag, Slag from Lignite Coal Combustion and Ash from Biomass Combustion.

Research on the effective use of secondary products is gaining more and more importance in Poland due to the intensively implementing idea of the circular economy. The solution used in this work are one of many tests useful in construction. The subject of this work was therefore the formation and testing of a new ecological construction binder, in particular for mortars or prefabricated elements working in the environment with high humidity. The binder was made of alkaline activated ground granular blast furnace slag (AAS), fly ash from biomass combustion (BFA) and furnace slag from brown coal combustion (LFS). The mixture was modified by introducing the zeolite to check the degree of metals immobilization contained in the ingredients of the mixture. A series of three mixtures were prepared: without and with zeolite soaked in distilled water or calcium nitrate. The strength of binders in time in dry and wet curing were tested and compared with the microstructure. The maximum compressive strength values at the eighth week were about 30 MPa. The strength values after 4 weeks of dry and wet curing were also compared. It was shown that 28-day wet curing increased the bending strength of the beams more than twice, but slightly decreased the compressive strength. The microstructure of the mixture with the highest values of compressive strength was the densest and the one with the lowest values of compressive strength, the most loosened with the most differentiated topographically fracture. The impregnation of zeolite with calcium nitrate decreased the compressive strength of the binder significantly. The bending strength of samples curing in dry conditions decreased during hardening. The results of the metals leaching test showed that the mixtures were safe for the environment, and due to the impregnation of zeolite with calcium nitrate, the binding effect of copper and zinc in the first weeks was greater than in the other mixtures.