Brackish Water Reverse Osmosis Research Articles

Multi-dimensional parametric study for enhancing Brackish Water Reverse Osmosis membrane performance suited for desalination of low salinity feeds.

Reverse osmosis (RO) effectively provides clean drinking water. Different RO membrane types are tailored to treat saline water feeds with varying characteristics. In the context of low brackish water feeds, the objective is to remove only a minimal excess of salinity through the membrane. Our study introduces a method of membrane post-treatments capable of achieving controlled salt rejection while concurrently enhancing permeate flux, which is vital for achieving effective and energy-efficient desalination of low brackish water. The post-treatments were conducted on our in-house-developed membranes using aqueous solutions of N,N-Dimethylformamide and glycerol for different drying times at the coupon level. The process was scaled up at the module level, allowing us to assess its potential for commercial application. At the coupon level, the permeate flux increased significantly from 3.7 ± 0.9 to 10.6 ± 0.2L/m2·h·bar, while the salt rejection decreased from 95.6 ± 1% to 70.5 ± 1% when measured with a feed of 2,000 ppm NaCl concentration. At the module level, we observed a higher flux of 12.8L/m2·h·bar, alongside a salt rejection of 55.5% with a similar feed. Varying post-treatment parameters at the coupon level allowed us to attain the desired salt rejection and permeate flux values. Physical changes in both pristine and post-treated membranes, including polymer swelling, were observed without chemical alterations, enhancing our understanding of the post-treatment effect and its potential for broader commercial use. PRACTITIONER POINTS: Post-treatment of RO membranes enhances flux. Physical structuring through polymer swelling was observed with the chemical structure unaltered. Post-treatment of RO opens doors for broader energy-efficient desalination application.

Optimizing energy efficiency in brackish water reverse osmosis (BWRO): A comprehensive study on prioritizing critical operating parameters for specific energy consumption minimization

Reverse osmosis (RO) systems offer a viable solution for treating brackish water (BW), a common but underutilized water resource. However, the energy-intensive nature of brackish water reverse osmosis (BWRO) systems poses affordability challenges to water supply, necessitating a focus on minimizing their energy consumption to support SDG6's goal of providing safe and affordable drinking water for all. This study addresses the critical need to minimize the specific energy consumption (SEC) of a typical BWRO system, defined as the energy consumed per unit of water recovered, mathematically and experimentally. Empirical models were developed proving there is a global minimum SEC while adjusting the operating conditions. Furthermore, we identified the key operating factors influencing SEC and their priority levels, along with their interactive effects. Notably, no prior study has discussed the significance and interaction of these operating factors (e.g., feed water salinity, temperature, pressure, flowrate and membrane permeability) on SEC of a BWRO system. Employing a full factorial experimental design with mixed levels of operating parameters, the study developed regression models that elucidate the mechanistic interaction between these parameters and system performance. Moreover, the models were validated experimentally, with a new dataset demonstrating their accuracy and reliability. ANOVA statistical analysis identified feed salinity, pressure, flow rate, feed flow rate×pressure, salinity×pressure, and temperature as influential operating parameters in reducing SEC, in descending order of importance. Operating within the determined optimum range resulted in a 36 % decrease in SEC and a more than fourfold increase in water recovery. The study's systematic approach and findings can be extrapolated to optimize the performance of other desalination technologies and diverse feed water types, contributing significantly to global water sustainability efforts.

Energetic Comparison of Flow-Electrode Capacitive Deionization and Membrane Technology: Assessment on Applicability in Desalination Fields.

Flow-electrode capacitive deionization (FCDI) is a promising technology for sustainable water treatment. However, studies on the process have thus far been limited to lab-scale conditions and select fields of application. Such limitation is induced by several shortcomings, one of which is the absence of a comprehensive process model that accurately predicts the operational performance and the energy consumption of FCDI. In this study, a simulation model is newly proposed with initial validation based on experimental data and is then utilized to elucidate the performance and the specific energy consumption (SEC) of FCDI under multiple source water conditions ranging from near-groundwater to high salinity brine. Further, simulated pilot-scale FCDI system was compared with actual brackish water reverse osmosis (BWRO) and seawater reverse osmosis (SWRO) plant data with regard to SEC to determine the feasibility of FCDI as an alternative to the conventional membrane processes. Analysis showed that FCDI is competent for operation against brackish water solutions under all possible operational conditions with respect to the BWRO. Moreover, its distinction can be extended to the SWRO for seawater conditions through optimization of its total effective membrane area via scale-up. Accordingly, future directions for the advancement of FCDI was suggested to ultimately prompt the commercialization of the FCDI process.

Brackish groundwater desalination by constant current membrane capacitive deionization (MCDI): Results of a long-term field trial in Central Australia

A long-term field trial of membrane capacitive deionization (MCDI) was conducted in a remote community in the Northern Territory of Australia, with the aim of producing safe palatable drinking water from groundwater that contains high concentrations of salt and hardness ions and other contaminants. This trial lasted for 1.5 years, which, to our knowledge, is one of the longest reported studies of pilot-scale MCDI field trials. The 8-module MCDI pilot unit reduced salt concentration to below the Australian Drinking Water Guideline value of 600 mg/L total dissolved solids (TDS) concentration with a relatively high water recovery of 71.6 ± 8.7 %. During continuous constant current operation and electrode discharging at near zero volts, a rapid performance deterioration occurred that was primarily attributed to insufficient desorption of multivalent ions from the porous carbon electrodes. Performance could be temporarily recovered using chemical cleaning and modified operating procedures however these approaches could not fundamentally resolve the issue of insufficient electrode performance regeneration. Constant current discharging of the electrodes to a negative cell cut-off voltage was hence employed to enhance the stability and overall performance of the MCDI unit during the continuous operation. An increase in selectivity of monovalent ions over divalent ions was also attained by implementing negative voltage discharging. The energy consumption of an MCDI system with a capacity of 1000 m3/day was projected to be 0.40∼0.53 kWh/m3, which is comparable to the energy consumption of electrodialysis reversal (EDR) and brackish water reverse osmosis (BWRO) systems of the same capacity. The relatively low maintenance requirements of the MCDI system rendered it the most cost-efficient water treatment technology for deployment in remote locations. The LCOW of an MCDI system with a capacity of 1000 m3/day was projected to be AU$1.059/m3 and AU$1.146/m3 under two operational modes, respectively. Further investigation of particular water-energy trade-offs amongst MCDI performance metrics is required to facilitate broader application of this promising water treatment technology.

Life cycle assessment of hybrid electrodialysis and reverse osmosis seawater desalination systems

This study investigates the environmental impact (EI) and water footprint (WF) of four seawater (SW) desalination configurations that combine both standalone and hybrid systems of SW reverse osmosis (SWRO) and SW electrodialysis (SWED). The analysis is conducted using life cycle assessment (LCA) and water recovery calculations. The results indicate that the hybrid SWRO-ED configuration has increased water recovery by 18–48 % over standalone SWRO and SWED. However, the SWRO-ED hybrid configuration has decreased membrane performance, which leads to increasing membrane replacement by 1.2–3.7 times compared to standalones SWED and SWRO, respectively. The carbon footprint for the SWRO-ED hybridization is 7.62 kg CO2 eq. per cubic meter of desalinated water compared to 5.35 and 6.48 kg CO2 eq/m3 emitted from SWRO and SWED standalones, respectively. On the other hand, the amending of SWED with brackish water RO (BWRO) consecutively increases water recovery by 8.4–42.1 % while reducing CO2 emissions by 41–51 %. The average WF per cubic meter of desalinated water is 2.46, 3.52, 2.65 and 3.92 m3 for the SWRO standalone, SWED standalone, SWED-BWRO, and SWRO-ED hybrid systems, respectively. Most of the WF is consumed indirectly for electricity or chemical production required for water desalination.

Synthesis of high-performance biocompatible polymeric membranes incorporated with zirconium-based MOF for an enhanced brackish water RO desalination

A nanosized zirconium 1,4- dicarboxybenzene metal-organic framework (UiO-66-MOF) was synthesized and impregnated into cellulose acetate (CA) polymeric matrix to enhance the membrane characteristics for brackish water desalination. Phase inversion was used for the fabrication of CA/UiO-66 hybrid membranes (CAU-X), where X is the concentration of immobilized UiO-66 nanoparticles (UiO-66-NPs) into CA polymeric matrix. Morphological structure and functional groups were investigated through different characterization techniques to prove the successful synthesis of the prepared UiO-66-NPs, the blank CA membrane, and hybrid CAU-X membranes. For more CAU-X characteristics, porosity, contact angle, and tensile strength were measured. The obtained data demonstrated that the impregnation of zirconium-based-NPs had a positive influence on the blank CA membrane properties. Additionally, the performance of the fabricated membranes was investigated in reverse osmosis (RO) bench-scale unit. The performance results for the pristine CAU-0 membrane showed a high salt rejection (SR) of 99.8% and a permeate water flux (PWF) of 1.14 L/m2.h. In comparison to pristine CA membrane, CAU-X hybrid membranes have a slightly lower SR and a higher PWF. It was found that the hybrid CAU-0.02 membrane had almost a doubled PWF of 2.8 L/m2.h with only 2% sacrificed SR of 97.6% compared with CAU-0 membrane. Moreover, a much better PWF of 3.4 L/m2h and a sufficient SR of approximetly 92% were obtained by CAU-0.05 membrane. Thus, CAU-0.05 was selected to further test its performance under different operating parameters. Results revealed that the optimum parameters were recorded for a sodium chloride feed stock of 5000 ppm operating at 25 °C temperature and pressure up to 15 bar.Graphical

(Invited) Electrochemical Deionization for Water Desalination and Direct Lithium Extraction

Electrochemical deionization based on carbonaceous and intercalation electrodes has been proposed as a promising candidate for desalinating saline water and for selectively separating toxic or valuable ionic constituents from water. In this talk, I will first introduce our work on the performance evaluation and techno-economic assessment for electrochemical desalination of brackish water. Parametric models were established to estimate the unit cost of water desalination and energy efficiency in electrochemical desalination with different configurations, and results were compared against brackish water reverse osmosis. In the second part of the talk, I will present our work on the development of selective electrochemical separation systems, focusing on the recovery of lithium from water streams. We investigated the selectivity of lithium separation in electrolyte solutions with different cation concentration ratios as well as in simulated brines. Results show that lithium chloride with a purity of >95% can be extracted from high-salinity brines in the presence of competing monovalent and divalent cations.

Evaluation of nanofiltration and reverse osmosis membranes for efficient rejection of organic micropollutants

Nanofiltration (NF) and reverse osmosis (RO) membranes have revolutionized water treatment processes. However, emerging separations, such as the removal of organic micropollutants (OMPs), pose a challenge for traditional RO and NF membranes due to either low water permeance (RO) or inadequate OMP rejection (NF). In this work, we investigated the rejection of thirteen frequently detected OMPs at environmentally relevant low feed concentration of 12 μg/L by using a wide range of commercial RO and NF polyamide thin-film composite (TFC) membranes and an in-house prepared NF membrane. The membranes were characterized using scanning electron microscopy (SEM), atomic force microscopy (AFM), Fourier transform infrared spectroscopy (FTIR), contact angle, and surface charge measurements. We investigated removal capabilities of OMPs at standard brackish water RO operating conditions (i.e., 15.5 bar transmembrane pressure, pH 8) and also examined the effect of feed solution transmembrane pressure on membrane performance. The rejection of ionic OMPs was strongly influenced by electrostatic repulsion effects, whereas rejection of non-ionic solutes was primarily driven by size exclusion and hydrophobic/hydrophilic interactions. The best performing TFC membranes — a lab-made semi-aromatic piperazine-based NF polyamide membrane and a fully aromatic commercial polyamide NF membrane (NF1) — displayed excellent rejection of OMPs comparable to a commercial RO seawater membrane (RO4), but exhibited ∼2-fold and ∼6-fold higher water permeance, respectively.

Transformation of brackish water Reverse Osmosis membranes to nanofiltration & ultrafiltration membranes by NaOCl treatment: Kinetic and characterization studies

Thin Film Composite (TFC) Reverse Osmosis (RO) membranes used in desalination, reach their End-of-Life (EoL) due to fouling and chemical degradation and pose disposal problem. Their lifetime can be increased by converting them into Ultrafiltration (UF) or Nanofiltration (NF) membranes. The present work demonstrates a systematic methodology in terms of ‘ppm-h/ppm∙h exposure’ to chemically convert brackish water RO membranes into NF and subsequently into UF membranes using sodium hypochlorite (NaOCl). Post-performance studies of pure water flux, monovalent and bivalent salt rejection are carried at each treatment level. RO membrane has transformed into NF at 3000–3 ppm-h, 2000–6 ppm-h, 3000–6 ppm-h and in to UF membrane beyond 10000–3 ppm-h. Gradual changes in physicochemical properties of membrane during conversion are ascertained from Scanning Electron Microscope (SEM), Atomic Force Microscopy (AFM), Attenuated Total Reflection – Fourier Transform Infrared Spectroscopy (ATR-FTIR), X-Ray Photoelectron Spectroscopy (XPS), contact angle, zeta potential etc. The rate of chlorination of polyamide is derived using XPS elemental data from initial stages of NaOCl exposure, and rate of hydrolysis from the membrane resistance, and pH. The overall rate equation is combination of both. The membrane thickness calculated from the kinetics match with experimental data. This study gives account of depolymerization of polyamide upon NaOCl exposure (ppm-h) which can be useful in chemical recycling/treatment of EoL membranes on a plant scale.

Comparative analysis of integrating standalone renewable energy sources with brackish water reverse osmosis plants: Technical and economic perspectives

This paper tries to simulate and discuss the possible solutions that improve the economic and technical performances of a battery-less renewable energy-powered BWRO system according to the real climate conditions. The systems are considered in two capacities (50 and 100 m3/day) and are powered using photovoltaic panels, wind turbines, or both. Four scenarios are considered to couple the RO unit with renewable energy (RE) sources: simple; elevated brackish water tank; variable frequency drive; and a combination of the latter two. First, the simple approach is optimized for the lowest levelized cost of water, and then the other three scenarios are analyzed based on the optimized results of the first scenario. Results indicate that the hybrid system can provide more water (13,500 and 24,900 m3/year). However, due to its homogenous nature and fewer fluctuations, the PV-based system shows better results from several viewpoints, such as specific energy consumption (1.08 kWh/m3 for both capacities) and unused energy ratio (0.32 and 0.28 for 50 and 100 m3/day devices). Also, the suggested scenarios improve the economic performance of the systems. With the modifications of scenario 4, the PV-based system enhances more and shows the lowest value of levelized cost of water (1.09 $/m3).

Innovative system for BWRO desalination powered by PV and pumped hydro storage – Economic and GHG emissions analysis

Brackish water reverse osmosis (BWRO) desalination driven by photovoltaic (PV) system as a primary energy source and pumped hydro storage (PHS) as an intermediate storage offers an energy-efficient and competitive solution to overcome freshwater scarcity. This innovative system for drinking water production from brackish groundwater was developed and technically analyzed in a prior work. In this paper, the entire system with two power supply scenarios: scenario 1 (PV, PHS and battery storage) and scenario 2 (PV, PHS and grid) is economically assessed and its greenhouse gas (GHG) emissions are analyzed. Thereafter, this system is compared with the state-of-the-art and BWRO systems powered by a conventional energy source (grid or diesel generator) to discuss and evaluate the future role of this innovative system in the BWRO desalination market. For off-grid operation, the innovative system with scenario 1 is the most economical system for drinking water production from brackish groundwater compared to the other examined systems as long as the diesel fuel price is equal to or more expensive than 0.58 US$/L. Moreover, the minimum specific GHG emissions produced per unit of drinking water production in scenario 1 is 46.8 % less than in the current system (PV and battery storage).

Pilot study of biofouling occurrence in a brackish water reverse osmosis system using intermittent operation

Water scarcity is a severe issue for humans owing to global climate change. Water reuse via reverse osmosis (RO) has been widely used to stabilize water supplies; however, RO membrane fouling increases operational costs and necessitates intermittent operation. The biofouling study on the RO pilot was operated either intermittently or continuously using collected brackish water. The environmental microbiome was incubated under oxic and anoxic conditions to simulate surface and groundwater conditions as the feed water. The least fouling was observed on the RO membrane surface when the RO system was operated intermittently using feed water incubated under anoxic conditions. The microbial results showed that specific biofilm communities were formed on RO membrane surface after brackish water RO (BWRO) operation. The major biofilm-forming bacteria distinctively differed with influent water conditions (i.e., oxic vs. anoxic), whereas they were less different with operational strategies (i.e., continuous vs. intermittent). Intermittent operation could compensate for physical cleaning. However, chemical cleaning showed the most effective results for microbe removal on the membrane surface. Therefore, intermittent operation using anoxic feed water can mitigate fouling formation on RO membranes.

Thermodynamic performance assessment of a community-scale brackish water reverse osmosis plant using exergy analysis

Abstract This study investigated the thermodynamic performance of a community-scale membrane-based brackish water reverse osmosis (BWRO) plant at various operating pressures from 13.79 to 27.58 bar and feed salinity levels from 2,000 to 20,000 mg/L. We aimed to identify the components responsible for the exergy losses and to suggest improvements. The results showed that the exergetic efficiency of some individual components had a significant impact on the performance of the desalination plant, where the high-pressure (HP) pump assembly and pressure control valve were identified as the major contributors to exergy losses (57.83–70.59 and 15.75–27.62%, respectively). The inefficiency of the feed pump assembly contributed to 11–12% of the total destruction of exergy under different operating conditions. The analysis further revealed that the exergetic efficiency of the plant was maximum (0.51%) at the feed salinity of 10,000 mg/L and operating pressure of 27.58 bar. It was minimum (0.01%) for the highest salinity (20,000 mg/L) and the lowest operating pressure (13.79 bar), due to the low requirement of work of separation and higher fixed losses. The exergetic efficiency was also correlated to the energetic performance of the BWRO plant at different operating conditions.

Performance Analysis of Reverse Osmosis Desalination Plant, Study Case of BBRI Plant

Desalination using seawater resources has been a cornerstone in meeting both human and industrial water demands for several decades. Some well-known methods are thermal desalination and membrane desalination. Among these, membrane desalination stands out, employing reverse osmosis (RO) technology, wherein seawater is pressurized and forced through a semi-permeable membrane to produce purified water. Black Bear Resources Indonesia (BBRI), which operates in the chemical industry relies on RO technology to cater its desalination requirements within the manufacturing facility. Notably, BBRI's desalination plant is equipped with both Seawater Reverse Osmosis (SWRO) and Brackish Water Reverse Osmosis (BWRO) modules. In the SWRO unit, the Hydranautic SWC-6 Max membrane is employed, while the BWRO unit features the Hydranautic ESPA-2 LD membrane. Both modules adopt the spiral wound configuration utilizing polyamide composite material. To determine the reliability of factory operations and dependability, a comprehensive performance analysis of the SWRO and BWRO units is imperative. This analysis encompasses critical parameters such as Recovery Rate, Membrane Flux, Percent Rejection, Concentration Rejection, and Specific Energy Consumption (SEC). Notably, performance degradation in both SWRO and BWRO systems primarily stems from membrane fouling, scaling phenomena, and the natural aging of the membranes.

Hybrid BWRO/FO system for high recovery in-land brackish water desalination: techno-economic assessment

Several hybrid Forward osmosis (FO) systems for seawater and brackish water desalination have been developed in recent years. This study investigates two approaches of integrated systems comprising brackish water reverse osmosis desalination (BWRO) and forward osmosis (FO) systems. These approaches aim to minimize the environmental effect of inland reject brine disposal while enhancing total water recovery. Experiments were performed using different draw solution (DS) concentrations of KCl and MgCl2.6H2O (0.5, 1, 1.5 and 2 Molar) to reach maximum recovery. In scheme (A), feed water is directed to BWRO with recovery 45% and 97% rejection, while the brine water is directed to the FO system as FS stream. In scheme (B), the feed water is divided into two streams, one of which is directed to the BWRO with recovery 75% and 98% rejection and the other stream is sent to the FO unit as FS stream. KCl DS displayed higher flux rate of an average 28.5 L/(m2.h) using 2 M concentration, while MgCl2.6H2O 2M solution shows an average flux of 23.5 L/(m2.h) during the first 100 min of operation. Scheme A shows 81% total system recovery, while scheme B shows 78% total system recovery. The cost indicators for desalination system with small capacity of 10 m3/d showed that scheme (A) has lower capital cost 55,732$ for scheme (A), while total capital cost was 59,400 $ for scheme (B).

Desalination, Water Re-use, and Halophyte Cultivation in Salinized Regions: A Highly Productive Groundwater Treatment System.

Groundwater salinization is a problem affecting access to water in many world regions. Though desalination by conventional reverse osmosis (RO) can upgrade groundwater quality for drinking, its disadvantages include unmanaged brine discharge and accelerated groundwater depletion. Here, we propose a new approach combining RO, forward osmosis (FO), and halophyte cultivation, in which FO optimally adjusts the concentration of the RO reject brine for irrigation of Salicornia or Sarcocornia. The FO also re-uses wastewater, thus, reducing groundwater extraction and the wastewater effluent volume. To suit different groundwater salinities in the range 1-8 g/L, three practical designs are proposed and analyzed. Results include specific groundwater consumption (SGC), specific energy consumption (SEC), wastewater volume reduction, peak RO pressure, permeate water quality, efficiency of water resource utilization, and halophyte yield. Compared to conventional brackish water RO, the results show superior performance in almost all aspects. For example, SGC is reduced from 1.25 to 0.9 m3 per m3 of drinking water output and SEC is reduced from 0.79 to 0.70 kW h/m3 by a FO-RO-FO system treating groundwater of salinity 8 g/L. This system can produce 1.1 m3 of high-quality drinking water and up to 4.9 kg of edible halophyte per m3 of groundwater withdrawn.

Silica mitigated calcium mineral scaling in brackish water reverse osmosis

Although the autopsies of reverse osmosis (RO) membranes from full-scale, brackish water desalination plants identify the co-presence of silica and Ca-based minerals in scaling layers, minimal research exists on their formation process and mechanisms. Therefore, combined scaling by silica and either gypsum (non-alkaline) or amorphous calcium phosphate (ACP, alkaline) was investigated in this study for their distinctive impacts on membrane performance. The obtained results demonstrate that the coexistence of silica and Ca-based mineral salts in feedwaters significantly reduced water flux decline as compared to single type of Ca-based mineral salts. This antagonistic effect was primarily attributed to the silica-mediated alleviation of Ca-based mineral scaling. In the presence of silica, silica skins were immediately established around Ca-based mineral precipitates once they emerged. Sheathing by the siliceous skins hindered the aggregation and thus the morphological evolution of Ca-based mineral species. Unlike sulfate precipitates, ACP precipitates can induce the formation of dense and thick silica skins via an additional condensation reaction. Such a phenomenon rationalized the notion concerning a stronger mitigating effect of silica on ACP scaling than gypsum scaling. Meanwhile, coating by silica skins altered the surface chemistries of Ca-based mineral precipitates, which should be fully considered in regulating membrane surface properties for combined scaling control. Our findings advance the mechanistic understanding on combined mineral scaling of RO membranes, and may guide the appropriate design of membrane surface properties for scaling-resistant membrane tailored to brackish water desalination.

Pilot study of emerging low-energy seawater reverse osmosis desalination technologies for high-salinity, high-temperature, and high-turbidity seawater

The increasing impact of climate change has worsened drought conditions, leading to a surge in the demand for seawater desalination. However, current seawater reverse osmosis (SWRO) desalination technologies are not energy-efficient for handling the high-salinity, high-temperature, and high-turbidity seawater found in the Arabian Gulf. Therefore, a pilot-scale SWRO desalination plant was established to evaluate the new desalination technologies. The pilot plant tested high-performance SWRO membranes, meshed tube filtration (MTF) as a low-energy pretreatment for the high turbidity induced by algal blooms, and membrane capacitive deionization (MCDI) to improve permeate quality. The high-performance SWRO membrane demonstrated exceptional salt rejection and produced permeate quality in the range of 250–455 mg/L from the feed with salinities of 47,500–53,500 mg/L. MTF was effective in controlling turbidity, and the energy consumption was reduced by 77 % compared to the existing pretreatment process. Furthermore, MCDI exhibited similar levels of energy efficiency as brackish water reverse osmosis and may have the potential for future deployment by enhancing process development. Based on the pilot plant results, it is expected that a 100,000–200,000 m3/d SWRO desalination plant will have a specific energy consumption of 3.11–3.13 kWh/m3 for final product water quality at or below 200 mg/L.

Raman spectroscopy for real-time concurrent detection of multiple scalants on RO membranes

In-situ monitoring techniques of reverse osmosis (RO) desalination systems, particularly those with chemical sensing capabilities, can provide the means for better understanding important scaling mechanisms as well as early scaling detection. In this work, both calcium sulfate and calcium carbonate scaling on RO membranes were detected concurrently in real time using Raman spectroscopy to provide a unique chemical fingerprint. Two different sampling methodologies (manual and automated) were employed, and their performance was evaluated by comparing the Raman detection times to concurrent values of flux decline. The manual sampling strategy resulted in the detection of calcium sulfate and calcium carbonate at mean permeate flux declines of 13 ± 10 % and 22 ± 3 %, respectively. The automated sampling strategy provided better performance, with detection of calcium sulfate and calcium carbonate at mean flux declines of 8 ± 5 % and 4 ± 3 %, respectively. The increased sensitivity and decreased variability of the automated sampling strategy provided valuable preliminary insights for the selection of optimized sampling strategies. The ability to identify the chemical composition of different scaling crystals including their polymorphs is an important step toward better understanding of the crystallization pathways of multi-component feed streams used in seawater and brackish water RO desalination.

A theoretical analysis on upgrading desalination plants with low-salt-rejection reverse osmosis

Brackish water/seawater reverse osmosis (RO) desalination is a key solution to global freshwater scarcity. However, the water recovery (Rw) in conventional RO desalination plants is limited by the operating pressure (∆P). As a novel staged RO technology, low-salt-rejection RO (LSRRO) can potentially enhance the Rw in the desalination plants. In this study, we perform process modeling and techno-economic analysis to evaluate the viability of upgrading current RO desalination plants with LSRRO. Based on the results from process modeling, in typical brackish water RO (BWRO) and seawater RO (SWRO) desalination plants, adding an LSRRO stage can effectively enhance the Rw by 21 and 53 %, respectively, and the energy efficiencies are not compromised with the enhanced Rw. From techno-economic analysis, upgrading RO desalination plant with LSRRO is highly viable. Specifically, after adding an LSRRO stage in a BWRO plant, the Rw can be enhanced from 71 to 81 % without notably increasing the levelized cost of water (LCOW), and adding an LSRRO stage in the SWRO plant with zero brine discharge can reduce the LCOW by 30 %. The findings in our study highlight the vast potential of adopting LSRRO in brackish water/seawater desalination plants, and shed lights on the design of future desalination plants.