Biodiesel Industry Research Articles

Cost, Emission, and Thermo-Physical Determination of Heterogeneous Biodiesel from Palm Kernel Shell Oil: Optimization of Tropical Egg Shell Catalyst

The advantages of reusability, lower cost, and environmentally friendly operation have made the heterogeneous catalyzed methylic process a preferable alternative to the homogeneously catalyzed protocol. The optimal production yield of palm kernel shell oil (PKSO) methyl ester (PKSOME) was modeled using Response Surface Methodology (RSM). The cost of PKSOME was determined, and the synthesized PKSOME was blended with diesel fuel with various volume ratios. Several analyses were done, including thermophysical properties using ASTM test methods, density and viscosity, fire point and flash point, aniline point, and acid value. Emission characteristics such as exhaust smoke, carbon monoxide, and carbon dioxide were measured using an IC engine. The use of waste eggshells for heterogeneously catalyzed biodiesel from underutilized PKSO for green diesel can reduce production costs even further. The green biodiesel model and TP correlations have applications in the biodiesel and aviation industries.

One-pot synthesis of MoO3-ZrO2 solid acid catalyst for solvent-free solketal production from glycerol

Glycerol acetalization to solketal is a promising method of increasing the additional value of glycerol, which is a by-product in biodiesel industry. In this work, a series of mesoporous x-MoO3-ZrO2 (x = Mo/Zr) solid acid catalysts with controllable Mo contents were designed and synthesized for the acetalization of glycerol. As important influence factors of solid acid catalysts, the mesoporous structure and existential state of Mo species were systematically investigated. Results show that Mo species were introduced as planned and existed in a homogeneously dispersed state in MoO3-ZrO2 materials. The acidic properties of MoO3-ZrO2 were explored through NH3-TPD and pyridine-chemisorbed FT-IR spectroscopy, and the formation of Brønsted and Lewis acid sites was confirmed by density functional theory calculations. Given their excellent acidity, MoO3-ZrO2 catalysts were employed for the acetal reaction of glycerol. Among the tested catalysts, the 20 %-MoO3-ZrO2 catalyst exhibited the optimal catalytic performance and reusability, achieving a conversion of 89 % for glycerol and a selectivity of 97 % for solketal. Consequently, MoO3-ZrO2 is a green solid acid catalyst with promising applications in solvent-free solketal production from glycerol.

Experimental and Simulation Studies for Purification and Etherification of Glycerol from the Biodiesel Industry

In this study, a purification route was applied to crude glycerol and its valorization via etherification was evaluated. Crude glycerol samples were obtained through transesterification reactions of soybean oil with methanol using potassium hydroxide as catalyst. A set of separation steps (acidification, neutralization, salt precipitation, evaporation and removal of contaminants using ion-exchange resins) was performed for purification of crude glycerol. The glycerol contents of crude samples were 46% wt., and for purified samples they were above 98% wt. The etherification reactions were carried out with purified samples and different alcohols (ethanol, isopropanol and 3-methyl-1-butanol) placed into a batch reactor, using a small amount of Amberlyst 15 as a catalyst, with autogenous pressure and solvent-free conditions. The glycerol conversion, selectivity and yield to ethers were evaluated. A glycerol conversion of up to 97% wt. was obtained when using ethanol. For isopropanol, the glycerol conversion rate was 85% (97.1% of monoether and 2.8% of diether). However, the selectivity to ethers for 3-methyl-1-butanol was negligible (<3% wt.). A process simulation for the purification and etherification steps integrated with a biodiesel production process was assessed in terms of productivity and energy consumption, considering different scenarios of glycerol/alcohol molar ratios. Finally, main impacts on the overall energy consumption were evaluated for the purification processes (glycerol and ethers).

Pengaruh Harga Internasional, Ekspor, Harga TBS, Dan Volume Produksi Biodiesel Terhadap Harga CPO Domestik

The palm oil industry downstream program supports the development of new energy made from palm oil, namely biodiesel. Biodiesel is used as a blend for fuels such as diesel. One of the goals of developing the biodiesel industry is to produce new renewable energy sources so that it can reduce dependence on fossil energy. With the development of the biodiesel industry, Indonesia's consumption of crude palm oil (CPO) will increase. It is feared that this could lead to an increase in domestic CPO prices. This research was conducted to analyze the impact of developing the biodiesel industry on domestic CPO prices. The data used is secondary data in the form of annual data from 1997-2021. The research analysis used multiple linear regression which is processed with Ordinary Least Square (OLS). The variables in this research are international CPO prices, CPO export volumes, biodiesel production, prices of fresh fruit bunches (FFB), and productivity of oil palm plantations. The real domestic CPO price was significantly affected by international CPO prices, CPO export volume, FFB prices, and the productivity of oil palm plantations. Biodiesel production was not proven to have a significant effect on domestic CPO prices.

Transformations of Glycerol into High-Value-Added Chemical Products: Ketalization and Esterification Reactions

Biomass allows us to obtain energy and high-value-added compounds through the use of different physical and chemical processes. The glycerol obtained as a by-product in the synthesis of biodiesel is considered a biomass compound that has the potential to be used as a raw material to obtain different chemical products for industry. The development and growth of the biodiesel industry allows for the projection of glycerol biorefineries around these plants that efficiently and sustainably integrate the biodiesel production process together with the glycerol transformation processes. This work presents a review of the ketalization and esterification of glycerol to obtain solketal and acetylglycerols, which are considered products of high added value for the chemical and fuel industry. First, the general aspects and mechanisms of both reactions are presented, as well as the related chemical equilibrium concepts. Subsequently, the catalysts employed are described, classifying them according to their catalytic nature (zeolites, carbons, exchange resins, etc.). The reaction conditions used are also described, and the best results for each catalytic system are presented. In addition, stability studies and the main deactivation mechanisms are discussed. Finally, the work presents the kinetic models that have been formulated to date for some of these systems. It is expected that this review work will serve as a tool for the advancement of studies on the ketalization and esterification reactions that allow for the projection of biorefineries based on glycerol as a raw material.

Recent Advances in Organic Synthesis Using Glycerol as a Green Media

Abstract: Various catalytic and non-catalytic organic transformations are carried out in glycerol media with superior efficiency over commonly employed organic solvents. The success of glycerol as a green media is due to its exceptional H-bonding properties, which result in enhanced reactivity in many organic transformations. In addition, its highly polar nature and non-toxic properties, recyclability, large availability as an organic waste from the biodiesel industry, high boiling point, low vapor pressure and low price further extend the scope of this solvent as green media. In this review, we present the potential use of glycerol as a green solvent in many organic transformations in two sections: cyclization reactions and miscellaneous reactions.

Comparative analysis of groundnut oil quality in the north-central zone of Nigeria: Determination and evaluation of heavy metals, fatty acids, Phospholipids, and iodine values in groundnut oil

The research presents a comparative analysis of the quality of locally produced groundnut oil (Arachis hypogaea) sold in the north-central zone of Nigeria markets (Benue, Nasarawa, Kogi, Kwara, Niger, Plateau States). The aim was to assess and compare the qualities of the oils and to know the safety of human consumption. The groundnut oil produced biodiesel, shampoo lubricants, and soap-making industries. The concentrations of the heavy metals were analyzed with atomic absorption spectrometry (AAS). It showed that the lead, zinc, and copper (Pb, Zn, Cu) were within the FAO/WHO recommended limit, while Cd (0.201-0.331 mg kg-1) was above the limit (0.07 mg kg-1). Also, the gas chromatography (GC-FID) results indicated that twelve fatty acids (linoleic > oleic > palmitic > stearic >lignoceric > arachidic acid > behenic > erucic> arachidonic > margaric > linolenic > palmitoleic) were obtained in the groundnut oils in all markets and fatty acids include caprylic acid, capric acid, lauric acid, and myristic acid were absent in oils. In addition, the magnitude of six Phospholipids (phosphatidylcholine > phosphatidylethanolamine> phosphatidylinositol > phosphatidylserine > phosphatidic acid > lysophosphatidylcholine) were also achieved, respectively. The iodine were below the FAO/WHO and the acid value was higher than the normal range.

Heteropolyacid supported on ionic liquid decorated hierarchical faujasite zeolite as an efficient catalyst for glycerol acetalization to solketal

To handle huge amount of glycerol produced in biodiesel industry, glycerol is transformed to value-added products. In this regard, glycerol acetalization to solketal is industrially attractive. As in this process various by-products can be formed, designing highly selective catalysts is of great importance. In this line, we wish to report a novel catalyst that benefits from strong acidity, high specific surface area and thermal stability, which can selectively form solketal in glycerol acetalization. To prepare the catalyst, hierarchical zeolite was prepared via a novel method, in which partially dealuminated NaY was treated with PluronicF-127 and then reacted with NH4NO3 to furnish the H-form zeolite. Hierarchical faujasite was then achieved through calcination and template removal. Subsequently, it was functionalized with ionic liquid and used for the immobilization of heteropolyacid. The results indicated the importance of the mesoprosity of zeolite and the presense of ionic liquid functionality for achiveing high solketal yield. Moreover, among three investigated heteropolyacids, phosphomolybdic acid exhibited the highest catalytic activity. In fact, using 10 wt% catalyst at 55 °C and glycerol to acetone molar ratio of 1:20, solketal with yield of 98% was furnished under solvent-less condition. Besides, the catalyst was recyclable with low leaching of heteropolyacid.

Physicochemical and microbiological parameters of rumen fluid of lactating goats fed diets containing crude glycerin from waste frying oil used in biodiesel production.

Crude glycerin from the biodiesel industry is a alternative energy source used to replace part of the energy components of the diet, since the nutritional value of glycerol makes it suitable for use in ruminant diets. The objective was to analyze the effects including crude glycerin (CG) derived from the production of biodiesel from residual frying oil, in diets of lactating goats on the physicochemical and microbiological parameters of rumen fluid. Eight 2-year-old goats weighting approximately 42.06 ± 3.5kg of body weight (BW) were kept in individual stalls, receiving diets containing 0, 7, 14 and 21% of CG (% DM). The experiment was carried out according to a double 4 × 4 Latin square and lasted for 80days. Orthogonal contrasts were tested to determine linear and quadratic effects, as well as the effects of 0% CG in the diet in comparison to the other treatments. There was a linear decreasing effect on DM intake (P = 0.001) and neutral detergent fiber (P = 0.0001), as well as a quadratic effect (P = 0.0002) on ether extract (EE) intake with increasing level of CG in the diet. Including CG affected motility and density of the protozoa (P = 0.0001). Treatments had no effect on pH, N-NH3 concentration and percentage of protozoa in the rumen liquid. There was increasing linear effect on sedimentation and flotation time (P = 0.001). Therefore, including 14 and 21% CG in the diet as a source of glycerol decreased nutrient intake and altered the ruminal microbiota, but pH and N-NH3 were not affected. Thus, to avoid impairment to the physicochemical and microbiological parameters of the rumen liquid of goats, the inclusion of CG should not exceed 7% DM.

Biodiesel Production from Waste Cooking Oil Using Extracted Catalyst from Plantain Banana Stem via RSM and ANN Optimization for Sustainable Development

Biodiesel is a promising sector worldwide and is experiencing significant and rapid growth. Several studies have been undertaken to utilize homogeneous base catalysts in the form of KOH to develop biodiesel in order to establish a commercially viable and sustainable biodiesel industry. This research centers around extracting potassium hydroxide (KOH) from banana trunks and employing it in the transesterification reaction to generate biodiesel from waste cooking oil (WCO). Various operational factors were analyzed for their relative impact on biodiesel output, and after optimizing the reaction parameters, a conversion rate of 95.33% was achieved while maintaining a reaction period of 2.5 h, a methanol-to-oil molar ratio of 15:1, and a catalyst quantity of 5 wt%. Response surface methodology (RSM) and artificial neural network (ANN) models were implemented to improve and optimize these reaction parameters for the purpose of obtaining the maximum biodiesel output. Consequently, remarkably higher yields of 95.33% and 95.53% were achieved by RSM and ANN, respectively, with a quite little margin of error of 0.0003%. This study showcases immense promise for the large-scale commercial production of biodiesel.

Techno-commercial viability of glycerol valorization to 1,2- and 1,3-propanediol using pinch technology

Glycerol is a low-value by-product in biodiesel industries and an important platform chemical in biorefinery with vast derivative potentials. 1,2- and 1,3-Propanediol (PDO) are vital polymer precursors. Valorizing glycerol to PDOs is thus a promising approach for producing renewable chemicals and improving the economics of biodiesel industries. Therefore, this work demonstrated the techno-economic feasibility of PDOs for 100–2000 metric tons per day glycerol feed rate. 1,2-PDO was produced by selective hydrogenolysis of glycerol, while microbial batch and fed-batch fermentation of glycerol was considered for manufacturing 1,3-PDO with the co-production of 2,3-butanediol and ethanol. Pinch analysis was applied for process integration that reduced utility demands by around 19% for 1,2-PDO and 12–16% for 1,3-PDO. However, utilities were still major operating costs in these processes. Besides, utility consumptions and capital expenditures were considerably higher for 1,3-PDO by batch fermentation than 1,2-PDO due to low glycerol concentration (50 g/L). 1,3-PDO production cost (USD 3.42/kg) by batch fermentation was thus much more than 1,2-PDO (USD 0.98/kg). The minimum unitary selling price was USD 1.15 for 1,2-PDO and USD 4.90 for 1,3-PDO (batch) for 8.5% rate of return and five years payback period. However, the microbial 1,3-PDO produced by fed-batch fermentation was economically viable, with USD 0.78 and USD 1.02 as unitary production costs and minimum selling price.

Optimizing viscosity measurement: an automated solution with YOLOv3

Measuring viscosity can be done using either Tracker software or a digital viscometer. However, the Tracker software proved to be ineffective due to the need to manually set the object’s center point for obtaining its final velocity. On the other hand, the digital viscometer was costly. Hence, a novel approach is needed to measure viscosity with high precision, efficiency, and affordability. To tackle these concerns, the study combined measuring instruments and computer programming with YOLOv3. The YOLOv3 model was applied to measure the B30 Biodiesel viscosity in a falling ball viscometer. The stages were: using a 10.07 mm ball size, the YOLOv3 model tracked the iron ball in the experimental videos to obtain the velocity. Next, based on the velocity, B30 biodiesel viscosity can be obtained. The formula of velocity and viscosity of the falling ball viscometer is integrated into the algorithm. The results are then compared to the reference data. The result showed that the final velocity and viscosity error relative were 1.30% and 2.04%. With an error relative below 5%, The data indicates that the algorithm effectively measures the velocity and viscosity of B30 biodiesel. This study was provided as a foundation for automatization in the quality control process for the biodiesel industry.

Recent trends on sewage sludge transesterification: review

The need for non-existent or low-cost sources to be a feedstock for the biodiesel industry as a source of lipids has led to the trend of sewage sludge (containing high fat content) and thinking about it and finding ways to benefit from it. On the other hand, he use of sludge is an environmental treatment, as it rids the environment of tons of sludge produced daily and a solution to a problem for treatment plants that were looking for ways and solutions to get rid of it and save the cost of getting rid of it and converting it into clean and promising energy. It was found that the sewage sludge in all its primary and secondary types is a feedstock rich in free fatty acids (FFA), which is the raw material for the production of biodiesel, while treating it with one of the types of catalyst alcohols. According to a review of previous studies, it was found that acidic catalysts are most suitable for biodiesel production from sewage sludge, because sewage sludge has a free fatty acid content of 65-70%, which is a high percentage. It is a severely high percentage of free fatty acids found in pure vegetable oils that do not exceed 5%. The heterogeneous acid catalysts were preferred over the homogeneous ones because of the satisfactory results they provided and the high productivity of biodiesel compared to the homogeneous ones, and they are more economical as they can be reused more than once, but also many times. Reacting sewage sludge lipids with a type of catalyst alcohol and forming biodiesel called transesterification or esterification, and it may be traditional or in-site, and in-site is more important and economical than conventional. It was found from previous references that heterogeneous catalysts in general and zeolite types in particular are the most suitable for oil extracted from sewage sludge. Where The yield reached 100% using a type of zeolite.

Insight into the influence of plant oils on the composition of diacylglycerol fabricated by glycerolysis and esterification

Thirty plant oils are utilized for preparation of value-added DAG by esterification and glycerolysis with glycerol to simultaneously clarify the source-structure-composition relationship in order to increase DAG production and reduce separation process in this investigation. It is found that the dominant DAG components of linoleic acid-rich oils are dilinolein (DL, ECN=28) and linoleoyl-oleoyl glyceride (DOL, ECN=30), and oleic acid-rich oils mainly comprise DOL and diolein (DO ECN=32), whereas DAG from the oils with the close ratio of linoleic/oleic acid dominantly contains the DL, DOL and DO species. The constituents of DAG from the oils rich in unsaturated fatty acid (oleic + linoleic + linolenic acid ≥ 80%) are occupied by the dilinolenin (DLn, ECN=24), dilinoleoyl-linolenoyl glyceride (DLnL, ECN=26) and DL. Visualization and three-dimension structure optimization shows that the DLn, DL, DOL and DO molecules have the lower steric energy. The molecular docking simulation reveals that DAG molecule is mainly interacted with the active pocket (Thr40-Ser105-Asp134-Gln157-His224) of Novozym 435 by O···H bond. This investigation not only provides a deep insight into the source-structure-composition relationship of value-added DAG-rich oils from glycerol as byproduct in biodiesel industries and plant oils derived from agro-industrial residues in food industry, but also discloses the interaction mechanism DAG molecule and Novozym 435.

Producing polyglycerol polyester polyol for thermoplastic polyurethane application: A novel valorization of glycerol, a by-product of biodiesel production

The production of biodiesel generates glycerol as a by-product that needs valorization. Glycerol, when converted to polyglycerol, is a potential polyol for bio-based thermoplastic polyurethane (TPU) production. In this study, a novel polyglycerol polyester polyol (PPP) was developed from refined glycerol and coconut oil-based polyester polyol. Glycerol was first converted to glycerol acetate and then polymerized with coconut oil-based polyester polyol (CPP) as secondary polyol and phthalic anhydride. The resulting PPP polymerized at 220 °C and OH:COOH molar ratio of 2.5 exhibited an OH number of <100 mg KOH·g sample−1, an acid number of <10 mg KOH·g sample−1, and a molecular weight (MW) of 3697 g mol−1 meeting the polyol requirement properties for TPU (Handlin et al., 2001; Parcheta et al., 2020) [1-2]. Fourier-transform infrared (FTIR) spectroscopic characterization determined that higher reaction temperatures increase the polymerization rate and decrease the OH and acid numbers. Further, higher OH:COOH molar ratios decrease the polymerization rate and acid number, and increase the OH number. Gel permeation chromatography determined the molecular weight of PPP and suggested two distinct molecular structures which differ only in the number of moles of CPP in the structure. A differential scanning calorimetric (DSC) experiment on a sample of PPP-based polyurethane revealed that it was able to melt and remelt after 3 heating cycles which demonstrates its thermoplastic ability. The novel PPP derived from the glycerol by-product of biodiesel industries can potentially replace petroleum-derived polyols for TPU production.

Pretreatment and Bioconversion for Valorization of Residues of Non-Edible Oilseeds

Biodiesel production currently follows a first-generation model using edible oils as raw materials. Such a production model is unsustainable, considering that it is limited by the high cost of edible oils, competes with the food sector, and is linked to deforestation and other environmental threats. Changing the raw material base to non-edible oils provides an opportunity to increase the sustainability of the biodiesel industry and to avoid conflicts with food production. Processing non-edible oilseeds for extracting the oil to be used for producing biodiesel generates large amounts of residues, such as de-oiled cakes, seed husks, and fruit shells and pods as well as plant stems and leaves resulting from pruning and other agronomy practices. Most of those residues are currently disposed of by burning or used in a suboptimal way. Bioconversion following the sugar platform route, anaerobic digestion, or enzyme production provides means for upgrading them to advanced biofuels and high-added value products. Bioconversion of plant biomass, including oilseed residues, requires pretreatment to enhance their susceptibility to enzymes and microorganisms. This review provides an outlook on bioconversion approaches applicable to different residues of oilseed-bearing plant species. Recent reports on the pretreatment of non-edible oilseed residues for enhancing their bioconversion through either the sugar platform route or anaerobic digestion are critically discussed. This review is based on an exhaustive Web of Science search performed in January–May 2023.

Asymmetric price transmission and impulse responses from U.S. crude oil to jet fuel and diesel markets

Despite numerous studies on price interdependencies in petroleum markets, the exploration of price transmission from crude oil to jet fuel and diesel remains surprisingly limited. This knowledge gap is particularly remarkable given the increasing economic significance of these fuels and the emerging biojet and biodiesel industries. Filling this research gap, this study employs a nonlinear time series approach that considers unique features of these markets— ‘stickiness’ of firms' responses, asymmetric price adjustments, and the time-dependent responses to oil price shocks. This approach provides a much-needed understanding of long-term price relationships, short-term dynamic adjustments, and price response mechanisms to crude oil shocks in the context of jet fuel and diesel markets. Key results include: (1) both jet fuel and diesel have long-run equilibrium relationships with oil prices; (2) price adjustments of jet fuel and diesel are asymmetric, in opposite directions, due to distinct differences in industrial characteristics; (3) the responses of the two types of fuel prices to oil shocks show nonlinear dynamic paths, with different amplitudes and decay periods. The findings contribute to a better understanding of the current fuel industries, and provide insights into emerging biofuel markets, with implications for businesses and policymakers.

Optimization of microwave-assisted biodiesel production from watermelon seeds oil using thermally modified kwale anthill mud as base catalyst

A heterogeneous catalyst was developed from raw Kwale red Anthill mud by thermal treatment in a muffle furnace at 900 °C for 4 h. The resulting heterogeneous catalyst was highly porous with a surface area of 42.16m2/g, possessing excellent stability as well as high catalytic activity. Central Composite Design and Machine Learning approach (Python code) were applied to model and optimize biodiesel yield from extracted watermelon oilseed. Highest biodiesel yield of 93.41 wt% was obtained under the experimental conditions of 4min duration, 350 W microwave power, 4 wt% of catalyst, and MeOH/oil ratio of 8:1 based on Central Composite Design rotatable. The optimum value of the biodiesel yield from Machine Learning was 91.7 wt%, showing a marginal performance over the Central Composite Design rotatable value (91.6 wt%) at the optimized conditions of 3 min, 280 W, 3 wt% catalyst loading and MeOH/oil molar ratio of 6:1. The correlation of the coefficient (R2) of the model was 0.9827 for Central Composite Design rotatable while the R2 of the Machine Learning model was 1.0. Thus, python coding in terms of prediction and accuracy of biodiesel yield was superior to Central Composite Design rotatable, even though both models provide a reliable response within the region of data analyzed. The Gas Chromatography-Mass Spectroscopy of the biodiesel produced revealed the presence of both saturated and unsaturated fatty acid methyl esters. Biodiesel properties from watermelon seed oil transesterification fall within the recommended standard for biodiesel fuel. This study concluded that an effective green biowaste catalyst generated from earthen waste could enhance biodiesel production from watermelon seed oil, hence, ensuring sustainability and economic feasibility for biodiesel industries.

Biosynthesis of Au/CuO catalyst with Syringa oblata Lindl. leaf extract for efficient selective oxidation of glycerol to 1,3-dihydroxyacetone

Efficient conversion of glycerol to 1,3-dihydroxyacetone (DHA) is the affirmation and guarantee of the feasible development of biodiesel industry, but the biocompatibility of catalyst must be considered due to the wide application of DHA in food and medicine industries. In this work, an environmentally benign biosynthesis approach with Syringa oblata Lindl. (SoL) leaf extract was employed to fabricate Au/CuO catalysts for the oxidation of glycerol to DHA. The biosynthesized SoL-Au/CuO catalysts were characterized and the effects of plant extracts concentration, gold loading, calcination temperature and reaction conditions on the catalytic performance were systematically analyzed. High catalytic performance with glycerol conversion rate of 95.7% and DHA selectivity of 77.9% can be attained under optimum conditions. This work provides the first example of preparing biocompatible catalyst for the thermal catalytic oxidation of glycerol to DHA, which can not only reach efficient conversion of glycerol and selectivity to DHA, but also is simple, green, environmentally friendly, and promising.

Glycerin combustion through chemical looping

Greenhouse gas emissions and their consequences are one of the main environmental problems faced today. To mitigate the impacts caused by this phenomenon, Brazil seeks to reduce 43% of its CO2 emissions by 2030 in order to meet the Paris Agreement. To achieve this goal, it is possible to use technologies based on the Carbon Capture, Utilization and Storage (CCUS) concept, such as Chemical Looping Combustion (CLC). The CLC can use natural wastes and industrial residues as carbon sources such as biomass, biogas and heavy oils. Glycerin, a by-product that accounts for almost 10% of all products from the biodiesel industry, can be used in this process since its availability is increasing over the years. Glycerin has a heat of combustion higher than ethanol and methane. This study aims to evaluate the feasibility of using glycerin in Chemical Looping Combustion. The crude glycerin was synthesized considering water, methanol and ethanol as the main contaminants. The fuel reactor temperature (TFR), oxygen-to-fuel molar ratio (ϕ) and H2O/Glycerin molar ratio, as well as the influence of methanol and ethanol on the performance of CLC were assessed. It was shown that the optimal performance of CLC was ϕ = 7, H2O/Glycerin = 0.75 and TFR = 1023 K, with a combustion efficiency (ηC) of 90% and complete carbon capture (carbon capture efficiency, ηCC = 100%). At these conditions, was noted that ethanol addition increased the combustion efficiency, while adding methanol caused a loss in efficiency.