Bare Fiber Research Articles

Electrochemical sensing of vitamin B6 using platinum nanoparticles decorated poly(2-aminothiazole)

Vitamin B6 (Vit B6), also known as pyridoxine, is pivotal in fundamental physiological and metabolic processes within the body. Insufficient levels of this essential nutrient may contribute to various health complications. We introduce an electrochemical sensor designed to determine Vit B6 levels precisely. This sensor is constructed through a two-step process: first, by modifying a bare carbon fiber paper electrode (CFP) with poly(2-aminothiazole) (PAT), and second, by electrodepositing platinum nanoparticles onto the modified electrode surface, giving the final working electrode- Pt/PAT/CFP. Electrochemical impedance spectroscopy (EIS) and Cyclic voltammetry (CV) were utilized to examine the electrochemical characteristics of the developed sensor. The characterization of the sensor was done through a range of analytical techniques, including X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), and optical profilometric studies. Furthermore, we optimized the sensor’s performance by assessing the impact of pH, scan rates, and analyte concentrations. The sensor showed a wide linear dynamic range of 5.0 nM–80 µM and a low detection limit of 0.054 µM. We have successfully quantified Vit B6 levels in tablet formulations and dried palm date fruits. The outcomes of this study hold the promise of substantial progress in Vit B6 quantification, with far-reaching implications across pharmaceuticals, healthcare, and nutritional science.

Immobilized proline-based electro-organocatalyst for the synthesis of bis-β-diketone via Knoevenagel condensation reaction

In the quest for more sustainable chemical processes, we devised a technique using electro-organocatalysis to synthesize bis-β-diketone compounds via Knoevenagel condensation of benzaldehyde and dimedone. Our approach involves a modified electrode fabricated via anchoring L-proline onto a carbon fiber paper electrode supported by poly-3,4-diaminobenzoic acid (PDABA), which enhances efficiency in addition to the simple catalyst separation from the reaction mixture in heterogeneous catalysis. The electrochemical and surface topographical studies for the fabricated electrode were carried out, revealing high efficiency in comparison to the bare carbon fiber paper electrode. This electrochemical reaction operates under mild conditions utilizing lithium perchlorate and acetonitrile, yielding high amounts of the desired product. This study showcases a promising pathway for producing valuable organic compounds in an environmentally friendly manner, marking a significant stride forward in sustainable synthesis practices.

A novel single mode fiber optic temperature sensor combined with the FLRDS technique

A single mode optical fiber loop was employed as a temperature sensor to observe changes in optical loss regarding to ringdown time (RDT) by high sensitive the fiber loop ringdown spectroscopy (FLRDS) technique which has real-time and fast response measurement capability due to allowing trapped light pulse multiple interactions with the measurands. Two different fiber loops of 45 ± 5 m and 120 ± 5 m lengths were embedded one by one into a copper, circular and closed housing. Continuous monitoring of RDTs was carried out by changing the temperature in the range of 25–200 °C with the steps of 25 °C for the first time by using bare fiber without any modification as a temperature sensor. The FLRDS system for temperature sensing has simple design without extra components such as an optical time domain reflectometer (OTDR), long-period fiber grating (LPFG) or fiber Bragg grating (FBG) as sensorhead. The FLRDS system was diligently optimized to achieve the lowest baseline as %0.49. Since the RDT of the FLRDS system was changed due to the thermal expansion of the fiber, continuous monitoring of the temperature was the first time recorded by utilizing this kind of FLRDS temperature sensor. These kind of FLRDS temperature sensors have high potential to be employed in mining, nuclear facilities, railways, underwater structures, biomedical, medicine, structural health monitoring, transportation and communication applications with simple system setup, lower cost, higher sensitivity, portability, real-time and continuous monitoring for early detection.

Balancing the Mechanical and Electrochemical Properties of Multifunctional Composite Electrolyte for Structural Batteries

The pursuit of energy-efficient for electric vehicles and aircraft has driven the exploration of structural batteries. In the material-level design of structural batteries, electrode and electrolyte materials act as both load-bearing structures and energy storage elements. During these developments, carbon fibers with excellent mechanical and electrical conductive properties were used as electroactive materials and current collectors. However, most of these systems are combined with electrolytes without mechanical integrity (such as liquid or gel-type electrolytes), thus limiting the load-carrying performance of the battery. Currently the development of electrolytes for structural batteries remains challenging because the parameters enhancing electrochemical properties are often in contradiction with that for mechanical properties. In response to this challenge, the present study proposes a multifunctional composite electrolyte with balanced mechanical and electrochemical properties, which uses polyvinylidene fluoride (PVDF) as the matrix and metal-organic frameworks (MOF) modified glass fabric (MOF@GF) as the reinforcement. This study systematically investigates the following factors on mechanical and electrochemical properties of the composite electrolytes. Firstly, MOF with high specific surface areas and metal open sites onto the surface of glass fibers establishes a robust ion transporting network. With 20% MOF modified glass fiber and resin content 89%, the electrolyte exhibits high ion conductivity (1.74 × 10-3 S cm−1). In addition, by carefully controlling the resin content, a key parameter for fiber-reinforced composites, a delicate balance between mechanical strength and ionic conductivity can be achieved. Furthermore, interfaces were investigated, including glass fiber-MOF and MOF-PVDF interfaces, revealing the importance of effectively transfers stress and maintains structural integrity. Finally, these findings were combined to create a structural lithium metal battery that utilizes carbon fiber (CF) as the positive electrode and lithium metal as the anode. The resulting battery exhibits ultra-high tensile strength while maintaining a moderate capacity, ensuring normal operation under high voltage stress. This breakthrough discovery not only enhances the understanding of multifunctional composite electrolytes, but is also expected to promote further research and applications in the field of structural batteries. The promise of enhanced system electrolytes opens new avenues for lightweight design, space efficiency and expanded energy storage capabilities in electric vehicles and aircraft. Figure 1 . SEM images of (a) bare glass fiber. (b) MOF grown in-situ on glass fiber. (c) Single fiberglass within polymer matrix. (d) Cross section of the composite polymer electrolyte membrane. Figure 1

Offset VSP acquired with a single-use fiber-optic probe: Gorgon CCS case study

There are many challenges associated with monitoring industrial subsurface CO2 storage. Utilizing a reliable strategy for monitoring and assurance is paramount. Numerous aspects and trade-offs need to be considered when designing a cost-effective monitoring solution that must satisfy regulatory and social licensing requirements and minimize operational complexity. Among various geophysical techniques that are included in the suite of carbon capture and storage (CCS) monitoring programs, seismic surveys provide reliable observations of the deep subsurface. However, active surface seismic techniques are expensive, resulting in significant time separation between surveys (several months or years). Downhole seismic approaches combined with fiber-optic sensing provide flexible options in designing on-demand monitoring strategies. Distributed acoustic sensing offers the opportunity to utilize injection wells for downhole time-lapse seismic imaging and microseismic detection, minimizing the impact on production operations. This paper presents the results of a multioffset vertical seismic profiling survey acquired in CO2 injection wells using bare fibers. The fibers were deployed inside the production tubing through FiberLine Intervention technology developed by Well-SENSE. The test utilized two injection wells for active seismic acquisition. The study took place on Barrow Island (Western Australia) as part of the Gorgon CCS project. The study demonstrates the technological advantages of fast deployment of the sensing fiber and the high quality of acquired seismic data. The paper highlights characteristic noise patterns in the recorded data and suggests approaches to attenuate their effects on seismic image quality. Finally, the impact of survey geometry and directional sensitivity of fiber on the recorded wavefield and the quality of seismic imaging is discussed.

Impacts of Hydrostatic Pressure on Distributed Temperature-Sensing Optical Fibers for Extreme Ocean and Ice Environments

Optical fiber is increasingly used for both communication and distributed sensing of temperature and strain in environmental studies. In this work, we demonstrate the viability of unreinforced fiber tethers (bare fiber) for Raman-based distributed temperature sensing in deep ocean and deep ice environments. High-pressure testing of single-mode and multimode optical fiber showed little to no changes in light attenuation over pressures from atmospheric to 600 bars. Most importantly, the differential attenuation between Stokes and anti-Stokes frequencies, critical for the evaluation of distributed temperature sensing, was shown to be insignificantly affected by fluid pressures over the range of pressures tested for single-mode fiber, and only very slightly affected in multimode fiber. For multimode fiber deployments to ocean depths as great as 6000 m, the effect of pressure-dependent differential attenuation was shown to impact the estimated temperatures by only 0.15 °K. These new results indicate that bare fiber tethers, in addition to use for communication, can be used for distributed temperature or strain in fibers subjected to large depth (pressure) in varying environments such as deep oceans, glaciers and potentially the icy moons of Saturn and Jupiter.

The antioxidative protection mechanism of the ultra-high temperature radome composite material BNf/SiBN

In the study, a BNf/SiBN composite was fabricated through precursor infiltration and pyrolysis (PIP) method. The oxidation resistance of the composite was investigated at different oxidation temperatures, focusing on the micro-structure evolution, the phase composition and oxidation kinetics of bare fibers versus fibers protected by the matrix under various oxidation states. The result indicates that the BNf/SiBN composite remains stable at 1100 °C in air atmosphere, while the fibers protected by matrix maintain their complete structure even at 1500 °C. Furthermore, we elucidated the oxidation mechanism of SiBN matrix: SiBN matrix undergoes a prior oxidation stage and transforms into amorphous SiO2 and B2O3 at high temperatures to impede the oxygen attachment to fibers while preserving the integrity of internal structure. The emergence of ultra-high temperature resistant BNf/SiBN composite and along with the exploration of oxidation behavior has opened up new approach for advancing radome material development.

Ω-Shaped fiber optic LSPR coated with hybridized nanolayers for tumor cell sensing and photothermal treatment

Circulating tumor cell (CTC) in the blood is the main cause of cancer metastasis for death in cancer patients. It is extremely important for cancer diagnosis at an early stage and treatment to simultaneously detect and kill the CTCs. In this work, a new hybridized nanolayer, namely gold nanoparticle/gold nanorods@ Polydopamine (AuNPs/AuNRs@PDA), was coated on the Ω-shaped fiber optics (Ω-FO) for localized surface plasmonic resonance (LSPR) to perform tumor cell sensing and photothermal treatment (PTT). The PDA nanolayer was formed on a bare fiber optic through the self-polymerization of dopamine under mild conditions. The AuNRs and AuNPs were absorbed on the surface of the PDA nanolayer to form a hybridized nanolayer. The hybridized nanolayer-modified Ω-FO LSPR exhibited a high refractive index sensitivity (RIS) of 37.59 (a.u/RIU) and photothermal conversion efficiency. After being modified with the recognition element of aptamer, the Ω-FO LSPR was used to develop a sensitive and specifical tumor cell sensing. Under the irradiation of near-infrared light (NIR) laser, the Ω-FO LSPR can kill the captured tumor cells with the apoptotic/necrotic rate of 62.6 % and low side-effect for the nontarget cells. The FO LSPR sensor realized the dual functions of CTC sensing and PTT, which provided a new idea for the early diagnosis and treatment of cancer.

Quantitative monitoring of localized pitting corrosion in steel bars through a combined use of distributed optical fiber sensors and finite element analyses

Pitting corrosion of steel bars can greatly impair mechanical properties of steel bars, so detecting pitting corrosion timely and accurately is crucial for assessing the health of structures. However, most current corrosion detection methods have some difficulties measuring pitting corrosion level of steel bars effectively. Considering that corrosion pits can cause strain redistribution of steel bar in the tensile state, this study proposes a method to quantitatively determine the pitting corrosion level through monitoring the steel strain distribution. Distributed optical fiber sensors (DOFS) based on Rayleigh scattering and capable of achieving the spatial resolution in millimeter scale were adopted to monitor the strain distributions of notched HRB400E steel bars subjected to tensile stress, and finite element (FE) method was employed to analyze the strain distributions of steel bars with different pit geometries. Experimental results showed that the bare fiber sensors (PI-FS) measured steel strain more accurately than jacketed fiber sensors. From strain distributions monitored by PI-FS, the pit location and pit length can be directly determined. Further, FE results revealed that the strain distribution along the fiber sensor position was significantly affected by the fiber sensor position relative to the pit mouth. Finally, the procedures to determine the pitting corrosion level from DOFS data and FE results were presented by mathematically comparing the similarity of strain curves given by the fiber sensor on a pitting-corroded bar and FE analyses of steel bars with different corrosion levels. In the end, the issues related to the practical applicability of the proposed method were discussed and limitations of this study were addressed. Although with limitations, this study provided a novel and promising way to quantitatively monitor the pitting corrosion level based on the strain distribution of steel bars.

N,N-dimethylformamide detection and refractive index sensing using an electrospun polymer/Ti3C2 MXene-TiO2 modified optical fiber sensor

Monitoring volatile organic compounds (VOCs), the majority of which are toxic and carcinogenic and pose serious threats to human health and the environment, provides diverse environmental data from industrial and biological processes. In this study, a sensor for the detection of refractive index (RI) and N,N-dimethylformamide (DMF) vapors was developed by electrospinning polyacrylonitrile (PAN) and Ti3C2 MXene/TiO2 hybrid materials onto a U-shaped evanescent optical fiber (UOFEs). UOFEs coated with PAN/Ti3C2 MXene/TiO2 films exhibited a 7-fold increase in RI sensitivity, with a maximum RI response value of 540 %/RI unit when compared to bare fibers. The UOFEs exhibited a limit of detection for DMF in the gas of 5.33 ppm at 25 °C. The proposed sensor works on the principle that DMF, which has a high RI, binds to PAN, which is rich in binding sites, via high compatibility and strong dipole–dipole interactions, increasing the RI of the films.

In-situ synthesis of bimetallic Co/Zn-ZIF on the graphite-felt for electrocatalytic degradation of pharmaceutical pollutants

In the electro-Fenton process, one of the important challenges is to adjust the pH of the environment in the acidic region so that the system's performance is not affected by side reactions. In this case, it will be necessary to neutralize the solution after the process. One of the solutions is to use a heterogeneous catalyst to widen the pH range. However, recovering the used catalyst itself can be another challenge. Modifying the electrode using electroactive materials can answer both of these challenges. This work modified the bare graphite-felt (GF) electrode using zeolitic imidazolate frameworks (ZIF)-derived carbon material doped with Co and Zn through a rapid, room-temperature, and water-based synthesis method. Various analyses, including XRD, SEM, XPS, and LSV, confirmed the proper modification of bare GF carbon fibers. The modified Co/Zn-N-C@GF electrode showed good performance in removing rifampicin (RFP) during the electro-Fenton process, so about 90 % of the pollutant was removed within 30 min without adding a homo-/heterogeneous catalyst. Optimum conditions for this process were 1.0 V for applied voltage, 40 mg/L for initial concentration of RFP, and 5.6 for pH. Also, LC-MS analysis was performed to confirm the degradation of RFP and investigate its degradation pathway.

Research on the removal mechanism and surface damage of laser assisted cutting of CFRP materials

The material removal mechanism of carbon fiber reinforced polymer (CFRP) in the process of laser assisted cutting (LAC) is still unclear. This study adopts a simulation and experimental methods to reveal the material removal mechanism of CFRP under the thermal-mechanical coupling effect. The cutting force, cutting temperature, and surface morphology are also analyzed through orthogonal cutting experiments. The experimental results show that the cutting force at various angles is significantly reduced due to enhancements in fiber fracture mode and a decrease in material removal volume with the laser assistance. The most substantial reduction, at 75.3 %, is observed in the feed cutting force at a 135° cutting angle. Additionally, the cutting temperature remains steady at approximately 55 °C, with no damage to the substrate in the laser assisted cutting. A three-dimensional finite element model of laser assisted orthogonal cutting was established innovatively by considering the bare fiber leakage to simulate the laser assistance. Based on this model, the fracture evolutionary mechanism of fibers and resins under laser irradiation is characterized. Laser assisted cutting experiments were conducted, and the simulation results were consistent with the experimental cutting force error within 20 %. The substrate damage and surface morphology were consistent with the experimental results. It is found that the bonding effect of the resin is significantly weakened due to being ablated in laser assisted cutting, making the fibers more prone to shear fracture. The proportion of fiber extrusion fracture under 90° cutting angle in laser assisted orthogonal cutting decreases, the crack damage is small and the fracture point of fiber bending is higher than that of conventional cutting. In addition, the effect of the laser on fiber fracture is more significant when the cutting angle is 135°, and it is more helpful for improving the fiber fracture mode with an increasing cutting speed when the cutting angle is 90°.

High‐Performance Thermoelectric Fibers from Metal‐Backboned Polymers for Body‐Temperature Wearable Power Devices

AbstractMetal‐backboned polymers (MBPs), with a unique backbone consisting of bonded metal atoms, are promising for optic, electric, magnetic, and thermoelectric fields. However, the application of MBP remains relatively understudied. Here, we develop a shear‐induced orientation method to construct a flexible nickel‐backboned polymer/carbon nanotube (NBP/CNT) thermoelectric composite fiber. It demonstrated a power factor of 719.48 μW ⋅m−1 K−2, which is ca. 3.5 times as high as the bare CNT fiber. Remarkably, with the regulation of carrier mobility and carrier concentration of NBP, the composite fiber further showed simultaneous increases in electrical conductivity and Seebeck coefficient in comparison to the bare CNT fiber. The NBP/CNT fiber can be integrated into fabrics to harvest thermal energy of human body to generate an output voltage of 3.09 mV at a temperature difference of 8 K. This research opens a new avenue for the development of MBPs in power supply.

High-Performance Thermoelectric Fibers from Metal-Backboned Polymers for Body-Temperature Wearable Power Devices.

Metal-backboned polymers (MBPs), with a unique backbone consisting of bonded metal atoms, are promising for optic, electric, magnetic, and thermoelectric fields. However, the application of MBP remains relatively understudied. Here, we develop a shear-induced orientation method to construct a flexible nickel-backboned polymer/carbon nanotube (NBP/CNT) thermoelectric composite fiber. It demonstrated a power factor of 719.48 μW ⋅m-1 K-2, which is ca. 3.5 times as high as the bare CNT fiber. Remarkably, with the regulation of carrier mobility and carrier concentration of NBP, the composite fiber further showed simultaneous increases in electrical conductivity and Seebeck coefficient in comparison to the bare CNT fiber. The NBP/CNT fiber can be integrated into fabrics to harvest thermal energy of human body to generate an output voltage of 3.09 mV at a temperature difference of 8 K. This research opens a new avenue for the development of MBPs in power supply.

Recovery stress, bond resistance, and stiffness to slip of crimped SMA fibers with considering geometric variation

Bond resistance is critical for reinforcing fibers in cementitious materials. Recently, crimped shape memory alloy fibers (SMA) have been raised as candidates for providing abundant benefits such as improved strength, enhanced durability, and crack closing. This study aimed to examine the influence of wave-depth and wave-length of crimped SMA fibers on their bond behavior. The crimped fibers in this study were categorized in four groups based on the wave-length. Each group had four types of fibers that considered the ratio of wave-depth to wave-length (DLR). Thus, a total of sixteen types of fibers were prepared with variations in wave-length and wave-depth. The tensile test used bare crimped SMA fibers, while the pullout tests used half dog-bone specimens. After the tests, the finite element model was used to evaluate the interaction parameters that were difficult to measure in the experience test. The results showed that the fibers with the smallest wave-length showed the largest maximum bond resistance in the same dept-to-length ratio (DLR) group, and that values decreased with an increasing wave-length. In addition, the smallest wave-length fibers demonstrated the most effective stiffness. Furthermore, the finite element analysis discovered that the geometric friction coefficients of the crimped SMA fibers were affected significantly by the geometric variation. The longer wave-length fiber revealed the larger estimated frictional coefficient.

Electrospun superhydrophobic polyvinyl chloride /polydimethylsiloxane-nanodiamond nanocomposite with enhanced antifouling and mechanical properties for fresh produce packaging

Food package films serve the important functions of preserving food quality, extending shelf life, and protecting against external contaminants while also providing a barrier to moisture and oxygen. In consideration of the increasing frequency of foodborne outbreaks, there is a growing demand for food packaging films with additional functionality to prevent cross-contamination and the attachment of pathogens, thereby enhancing bacterial safety. Herein, we report a one-step fabrication approach relying on electrospinning of a blend of polyvinyl chloride (PVC) and polydimethylsiloxane (PDMS) together with nanodiamond (ND) on a rotating drum collector for the formation of bacterially antifouling food package films. In this approach, by adjusting the concentrations of PVC, PDMS, and ND and the drum angular velocity, the nanofiber diameter could be tuned in the range of 0.4 μm to 2.0 μm. Furthermore, these process parameters could also be used to modulate the water contact angle on the resultant films, with a minimum contact angle of 136.2 ± 5.6° and a maximum of 159.5 ± 3.8°. The lowest water contact angles were observed for films with bare PVC fibers while the highest contact angles were seen for films with nanocomposite fibers containing ND and PVC/PDMS. Compared with the films with bare PVC, nanocomposite films with ND-PVC/PDMS achieved up to 99.8 % and 99.6 % reduction in bacterial adhesion against S. typhimurium LT2 and Listeria innocua, respectively. The tensile strength of nanofibrous PVC film can be increased from 1.2 ± 0.4 MPa to 4.4 ± 0.3 MPa by the inclusion of PDMS (1:1 wt.%) and further increased to 8.9 ± 0.3 MPa with the additional inclusion of ND (PVC/PDMS/ND 1:1:0.1 wt.%). Considering the notable antifouling properties against bacteria and the improved mechanical characteristics, these nanocomposite films represent a noteworthy step in the development of sustainable and active food packaging solutions for a safer and healthier food supply chain.

Laser Hemorrhoidoplasty Using Reusable Bare Fiber Combined Mucopexy on Grade IV Internal Hemorrhoid: A Case Report

Background: Hemorrhoids are the most common anorectal disease, affecting millions worldwide. Hemorrhoids are categorized as "internal" or "external" based on their proximity to the pectinate line, which separates the upper 2/3 and lower 1/3 of the anus. The hemorrhoidal disease can be treated in various ways, from non-invasive methods like rubber band ligation, cryotherapy, sclerotherapy, laser photocoagulation, and phototherapy to invasive methods like surgical excision for patients with severe symptoms, grade III or IV hemorrhoids, or persistent bleeding. This study described the results of Laser Hemorrhoidoplasty (LHP) using reusable bare fiber combined mucopexy, a diode laser with wavelengths of 980 nm and 1470 nm, specifically gallium aluminum arsenide (GaAIAs). Methods: a case of a 28-year-old male with complaints of rectal prolapse mass one day ago and could not be reinserted with a finger, bleeding while passing stool, and rectal pain with a Visual analog scale was 7. The patient had experienced similar symptoms and had a sclerobanding procedure four years ago. However, it has reappeared in the past year. The patient was diagnosed with grade 4 internal hemorrhoids and underwent Conclusion: Laser hemorrhoidoplasty using reusable bare fiber with combined mucopexy. After the laser hemorrhoidoplasty procedure on day 4, the patient felt no pain, rectal bleeding, rectal lumps, or soiling.

Multimode fiber endoscopes for computational brain imaging.

Advances in imaging tools have always been a pivotal driver for new discoveries in neuroscience. An ability to visualize neurons and subcellular structures deep within the brain of a freely behaving animal is integral to our understanding of the relationship between neural activity and higher cognitive functions. However, fast high-resolution imaging is limited to sub-surface brain regions and generally requires head fixation of the animal under the microscope. Developing new approaches to address these challenges is critical. The last decades have seen rapid progress in minimally invasive endo-microscopy techniques based on bare optical fibers. A single multimode fiber can be used to penetrate deep into the brain without causing significant damage to the overlying structures and provide high-resolution imaging. Here, we discuss how the full potential of high-speed super-resolution fiber endoscopy can be realized by a holistic approach that combines fiber optics, light shaping, and advanced computational algorithms. The recent progress opens up new avenues for minimally invasive deep brain studies in freely behaving mice.

Electrospun PCL Filtration Membranes Enhanced with an Electrosprayed Lignin Coating to Control Wettability and Anti-Bacterial Properties.

This study reports on the two-step manufacturing process of a filtration media obtained by first electrospinning a layer of polycaprolactone (PCL) non-woven fibers onto a paper filter backing and subsequently coating it by electrospraying with a second layer made of pure acidolysis lignin. The manufacturing of pure lignin coatings by solution electrospraying represents a novel development that requires fine control of the underlying electrodynamic processing. The effect of increasing deposition time on the lignin coating was investigated for electrospray time from 2.5 min to 120 min. Microstructural and physical characterization included SEM, surface roughness analysis, porosity tests, permeability tests by a Gurley densometer, ATR-FTIR analysis, and contact angle measurements vs. both water and oil. The results indicate that, from a functional viewpoint, such a natural coating endowed the membrane with an amphiphilic behavior that enabled modulating the nature of the bare PCL non-woven substrate. Accordingly, the intrinsic hydrophobic behavior of bare PCL electrospun fibers could be reduced, with a marked decrease already for a thin coating of less than 50 nm. Instead, the wettability of PCL vs. apolar liquids was altered in a less predictable manner, i.e., producing an initial increase of the oil contact angles (OCA) for thin lignin coating, followed by a steady decrease in OCA for higher densities of deposited lignin. To highlight the effect of the lignin type on the results, two grades of oak (AL-OA) of the Quercus cerris L. species and eucalyptus (AL-EU) of the Eucalyptus camaldulensis Dehnh species were compared throughout the investigation. All grades of lignin yielded coatings with measurable antibacterial properties, which were investigated against Staphylococcus aureus and Escherichia coli, yielding superior results for AL-EU. Remarkably, the lignin coatings did not change overall porosity but smoothed the surface roughness and allowed modulating air permeability, which is relevant for filtration applications. The findings are relevant for applications of this abundant biopolymer not only for filtration but also in biotechnology, health, packaging, and circular economy applications in general, where the reuse of such natural byproducts also brings a fundamental demanufacturing advantage.

Temperature and strain monitoring during thermoforming of thermoplastic composite laminates using optical frequency domain reflectometry

In this study, optical frequency domain reflectometry (OFDR) was used to monitor the thermoforming processes of carbon fiber reinforced thermoplastics (CFRTPs) to address the limitations of conventional sensors including large size and low spatial resolution. A bare single-mode fiber with a polyimide coating and a fiber encapsulated by a long metal capillary were cascaded and embedded into composite laminates to withstand the high pressure and temperature during thermoforming, and then connected to the OFDR for monitoring. A fiber encapsulated by a 2 cm short metal capillary was also embedded to demonstrate that a 1 mm resolution of the OFDR is beneficial for reflecting the local change in the composite. After processing by wavelet denoising, signal extraction, and decoupling, the frequency shift along the optical fiber sensor was successfully converted to strain and temperature. In two repeated thermoforming experiments that involved cooling from 340 °C, the average temperature difference measured by the OFDR and reference thermocouple was only 4.64 °C. The strain measured by the OFDR and reference fiber Bragg grating (FBG) decreases in the cooling stage, and has a clear knee point of 250 °C when correlated with the temperature and strain. This knee point is consistent with the liquid–liquid transition temperature of the polyetherimide and indicates the beginning of consolidation when the composite changes its properties significantly. The average strain difference measured by OFDR and the reference FBG was 69 μϵ when the total strain is approximately 1820 μϵ if only considering the consolidation process from 250 °C. The results of 1 mm spatial resolution and high accuracy demonstrate that OFDR is a promising high-resolution sensing solution for the in-situ temperature and strain monitoring of the thermoforming of CFRTPs.