Balsa wood, despite being a cost-effective insulation material, has limited applications due to its inherent hydrophilicity. This study introduces an innovative technique for the in-situ growth of low surface energy long alkyl chain segments on balsa wood using the atom transfer radical polymerization (ARGET-ATRP) method, which not only provides durable and stable hydrophobicity but also preserves its natural texture, mechanical strength, and thermal insulation. The resulting hydrophobic wood demonstrated exceptional hydrophobicity in diverse environments, with a water contact angle up to 141.3° and a contact angle decrease of no more than 10.47 % after 150 min, confirming its hydrophobic stability. Furthermore, axial thermal conductivity of the wood was as low as 0.1012 W/m·K, the axial compressive strength decreased by only 12.8 %, further evidencing the retention of its mechanical properties. This simple yet effective strategy of in-situ alkyl chain growth on balsa wood not only preserves its structure but also opens new avenues for the multifunctional development of biomaterials.
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