Atomic Vapor Cell Research Articles

Remote chip-scale quantum sensing of magnetic fields

Quantum sensing is an ever-evolving research field describing the use of a quantum phenomenon to perform measurement of a physical quantity. Amongst different types of quantum sensors, atomic vapor-based quantum effects are extensively used to measure quantities such as time, velocity, acceleration, electric, and magnetic fields. Here, we propose and demonstrate remote quantum sensing using a chip-scale atomic vapor cell. Specifically, we remotely interrogate millimeter-scale micromachined vapor cells, and measure the ambient Earth’s magnetic field at a standoff distance of ∼10 m and a sensitivity of ∼1 pT/√Hz. We further spatially map different magnetic fields in the presence of a noisy ambient environment. Simultaneously we are able measure the distance between a micro-cell and the interrogating system by means of time-of-flight measurements, thus correlating between position and magnetic field. Utilizing micromachined vapor cells for remote magnetometry offers substantial advantages in scalability, planar photonic integration, cost, and size. Consequently, we provide a novel toolset to deploy, measure, and map arbitrary, remote, and hard-to-access magnetic fields in unshielded environments with high sensitivity and spatial resolution, paving the way to a variety of novel applications in diverse fields such as medicine, communication, defense, space-exploration, and quantum technologies.

Improving 795 nm Single-Frequency Laser’s Frequency Stability by Means of the Bright-State Spectroscopy with Rubidium Vapor Cell

The utilization of atomic or molecular spectroscopy for frequency locking of single-frequency laser to improve laser frequency stability plays an important role in the experimental investigation of optically pumped atomic magnetometers, atomic clocks, laser cooling and trapping of atoms, etc. We have experimentally demonstrated a technique for frequency stabilization of a single-frequency laser employing the bright state spectroscopy (BSS) with a rubidium atomic vapor cell. By utilizing the counter-propagating dual-frequency 795 nm laser beams with mutually orthogonal linear polarization and a frequency difference of 6.834 GHz, which is equal to the hyperfine splitting of rubidium-87 ground state 5S1/2, an absorption-enhanced signal with narrow linewidth at the center of Doppler-broadened transmission spectroscopy is observed when continuous scanning the laser frequency over rubidium-87 D1 transition. This is the so-called BSS. Amplitude of the absorption-enhanced signal in the BSS is much larger compared with the conventional saturation absorption spectroscopy (SAS). The relationship between linewidth and amplitude of the BSS signal and laser beam intensity has been investigated. This high-contrast absorption-enhanced BSS signal has been employed for the laser frequency stabilization. The experimental results show that the frequency stability is 4.4×10−11 with an integration time of 40 s, near one order of magnitude better than that for using the SAS.

Comparison and analysis of methods for measuring the spin transverse relaxation time of rubidium atomic vapor

The spin transverse relaxation time (T2) of atoms is an important indicator for magnetic field precision measurement. Especially in optically-pumped atomic magnetometer, the linewidth of the magnetic resonance signal is one of the most important parameters of sensitivity, which is inversely correlated with T2 of atoms. In this paper, we propose four methods, namely spin noise spectroscopy signal fitting, radio-frequency free induction decay (RF-FID) signal fitting, ω m (modulation frequency)-broadening fitting, and magnetic resonance broadening fitting, for in-situ measurement T2 of atomic vapor cells based on light-atom interactions. Meanwhile, T2 of three Rubidium (Rb) atomic vapor cells with different parameters are measured and discussed by using these four methods. A comparative analysis visualizes the characteristics of the different methods and the effects of buffer gas on T2 of Rb atoms. Through theoretical and experimental analysis, we assess the applicability of each method and concluded that the RF-FID signal fitting method provides the most accurate measurements due to the timing sequence control system, which results in a cleaner measurement environment. Furthermore, we demonstrate and qualitatively analyze the relationship between temperature and T2 of Rb atoms. This work may offer valuable insights into the selection of atomic vapor cells and it is also applicable for the spin-exchange relaxation-free region.

Influence of the size of the cubic atomic vapor cell on a Rydberg atomic microwave sensor.

This study investigates the enhancement of the microwave (MW) electric (E) field due to the Fabry-Perot (FP) effect in cubic cells of varying sizes, and it is confirmed that the lower limit of MW power can be measured. Theoretical simulations and empirical validations are conducted for three vapor cells of different sizes. At a MW frequency of 23.904GHz, the FP effect in the 10mm cell is found to significantly enhance the MW E-field relative to larger cells (20 and 25mm). The results show that, due to the existence of the FP effect, the lower limit of MW power can be measured in the cubic atomic vapor cells with different sizes. These findings contribute to the advancement of the vapor cell design for quantum accuracy measurements and the development of future atomic MW communication technologies.

Broad Instantaneous Bandwidth Microwave Spectrum Analyzer with a Microfabricated Atomic Vapor Cell

We report on broad instantaneous bandwidth microwave spectrum analysis with hot Rb87 atoms in a microfabricated vapor cell in a large magnetic field gradient. The sensor is a MEMS atomic vapor cell filled with isotopically pure Rb87 and N2 buffer gas to localize the motion of the atoms. The microwave signals of interest are coupled through a coplanar waveguide to the cell, inducing spin-flip transitions between optically pumped ground states of the atoms. A static magnetic field with large gradient maps the frequency spectrum of the input microwave signals to a position-dependent spin-flip pattern on absorption images of the cell recorded with a laser beam onto a camera. In our proof-of-principle experiment, we demonstrate a microwave spectrum analyzer that has ≈1 GHz instantaneous bandwidth centered around 13 GHz, 3 MHz frequency resolution, 2 kHz refresh rate, and a −23 dBm single-tone microwave power detection limit in 1 s measurement time. A theoretical model is constructed to simulate the image signals by considering the processes of optical pumping, microwave interaction, diffusion of Rb87 atoms, and laser absorption. We expect to reach more than 25 GHz instantaneous bandwidth in an optimized setup, limited by the applied magnetic field gradient. Our demonstration offers a practical alternative to conventional microwave spectrum analyzers based on electronic heterodyne detection. Published by the American Physical Society 2024

Continuous broadband Rydberg receiver using AC Stark shifts and Floquet states

We demonstrate the continuous broadband microwave receivers based on AC Stark shifts and Floquet states of Rydberg levels in a cesium atomic vapor cell. The resonant transition frequency of two adjacent Rydberg states 78 S1/2 and 78 P1/2 is tuned based on AC Stark effect of 70 MHz radio frequency (RF) field that is applied outside the vapor cell. The use of the j=1/2 Rydberg states ensures that only a single mj sublevel is involved. The generated Rydberg Floquet states act to enhance the sensitivity of the AC-Stark-tuned states when the frequency is matched and further extend the bandwidths. We achieve microwave field measurements with over 1.172 GHz continuous frequency tuning and a sensitivity ranging from 280.2 nVcm−1Hz−1/2 to 14.6 μ Vcm−1Hz−1/2. The achieving of continuous frequency and high sensitivity microwave detection will promote the application of Rydberg receivers in the radar technique and wireless communication.

Additive manufacturing of functionalised atomic vapour cells for next-generation quantum technologies

Abstract Atomic vapour cells are an indispensable tool for quantum technologies (QT), but potential improvements are limited by the capacities of conventional manufacturing techniques. Using an additive manufacturing (AM) technique – vat polymerisation by digital light processing - we demonstrate, for the first time, a 3D-printed glass vapour cell. The exploitation of AM capacities allows intricate internal architectures, overprinting of 2D optoelectronical materials to create integrated sensors and surface functionalisation, while also showing the ability to tailor the optical properties of the AM glass by in-situ growth of gold nanoparticles. The produced cells achieve ultra-high vacuum of 2 x 10-9 mbar and enable Doppler-free spectroscopy; we demonstrate laser frequency stabilisation as a QT application. These results highlight the transformative role that AM can play for QT in enabling compact, optimised and integrated multi-material components and devices.

Simultaneously measuring microwave electric fields at different frequencies by Rydberg-atom-based electrometry with Zeeman-resolved Autler–Townes splitting

We provide the simultaneous traceable measurements of microwave electric fields at two different frequencies by the electromagnetically induced transparency (EIT) and Autler–Townes (AT) splitting. A static magnetic field working together with a linearly polarized probe and coupling light prepares Rydberg atoms in Zeeman sublevels with maximal |mJ| in an atomic vapor cell. Using the EIT-AT splitting of these two maximal |mJ| states, the microwave electric fields at two different frequencies are simultaneously measured, in which their frequency difference can be adjustable within the linear range of magnetic field-induced level shifts. The proposed method provides a promising prospect for calibrating multiple microwave frequencies simultaneously in the future.

Chip-scale sub-Doppler atomic spectroscopy enabled by a metasurface integrated photonic emitter

We demonstrate chip-scale sub-Doppler spectroscopy in an integrated and fiber-coupled photonic-metasurface device. The device is a stack of three planar components: a photonic mode expanding grating emitter circuit with a monolithically integrated tilt-compensating dielectric metasurface, a microfabricated atomic vapor cell, and a mirror. The metasurface photonic circuit efficiently emits a 130 μm wide (1/e2 diameter) collimated surface-normal beam with only −6.3 dB loss and couples the reflected beam back into the waveguide and connecting fiber, requiring no alignment between the stacked components. We develop a simple model based on light propagation through the photonic device to interpret the atomic spectroscopy signals and explain spectral features covering the full Rb hyperfine state manifold. The demonstration of waveguide-to-waveguide coupling through the vapor cell paves the way for atomic ensembles to be used as components in complex photonic integrated circuits, allowing the unique properties of atomic systems to be available for future highly miniaturized optical devices and systems.

Direct generation of time-energy-entangled W triphotons in atomic vapor.

Entangled multiphoton sources are essential for both fundamental tests of quantum foundations and building blocks of contemporary optical quantum technologies. While efforts over the past three decades have focused on creating multiphoton entanglement through multiplexing existing biphoton sources with linear optics and postselections, our work presents a groundbreaking approach. We observe genuine continuous-mode time-energy-entangled W-class triphotons with an unprecedented production rate directly generated through spontaneous six-wave mixing (SSWM) in a four-level triple-Λ atomic vapor cell. Using electromagnetically induced transparency and coherence control, our SSWM scheme allows versatile narrowband triphoton generation with advantageous properties, including long temporal coherence and controllable waveforms. This advancement is ideal for applications like long-distance quantum communications and information processing, bridging single photons and neutral atoms. Most importantly, our work establishes a reliable and efficient genuine triphoton source, facilitating accessible research on multiphoton entanglement.

Ultrasensitive SERF atomic magnetometer with a miniaturized hybrid vapor cell

The chip-scale hybrid optical pumping spin-exchange relaxation-free (SERF) atomic magnetometer with a single-beam arrangement has prominent applications in biomagnetic measurements because of its outstanding features, including ultrahigh sensitivity, an enhanced signal-to-noise ratio, homogeneous spin polarization and a much simpler optical configuration than other devices. In this work, a miniaturized single-beam hybrid optical pumping SERF atomic magnetometer based on a microfabricated atomic vapor cell is demonstrated. Although the optically thin Cs atoms are spin-polarized, the dense Rb atoms determine the experimental results. The enhanced signal strength and narrowed resonance linewidth are experimentally proven, which shows the superiority of the proposed magnetometer scheme. By using a differential detection scheme, we effectively suppress optical noise with an approximate five-fold improvement. Moreover, the cell temperature markedly affects the performance of the magnetometer. We systematically investigate the effects of temperature on the magnetometer parameters. The theoretical basis for these effects is explained in detail. The developed miniaturized magnetometer has an optimal magnetic sensitivity of 20 fT/Hz1/2. The presented work provides a foundation for the chip-scale integration of ultrahighly sensitive quantum magnetometers that can be used for forward-looking magnetocardiography (MCG) and magnetoencephalography (MEG) applications.

Key Technologies in Developing Chip-Scale Hot Atomic Devices for Precision Quantum Metrology.

Chip-scale devices harnessing the interaction between hot atomic ensembles and light are pushing the boundaries of precision measurement techniques into unprecedented territory. These advancements enable the realization of super-sensitive, miniaturized sensing instruments for measuring various physical parameters. The evolution of this field is propelled by a suite of sophisticated components, including miniaturized single-mode lasers, microfabricated alkali atom vapor cells, compact coil systems, scaled-down heating systems, and the application of cutting-edge micro-electro-mechanical system (MEMS) technologies. This review delves into the essential technologies needed to develop chip-scale hot atomic devices for quantum metrology, providing a comparative analysis of each technology's features. Concluding with a forward-looking perspective, this review discusses the future potential of chip-scale hot atomic devices and the critical technologies that will drive their advancement.

Radio-Frequency Magnetometry Based on Parametric Resonances.

We propose and demonstrate a radio-frequency (rf) atomic magnetometer based on parametric resonances. Previously, most rf atomic magnetometers are based on magnetic resonances and their sensitivities are often limited by spin-exchange relaxation. Here, we introduce a novel scheme for an rf magnetometer where the rf magnetic field is measured by exciting the parametric resonances instead of magnetic resonances using parametric modulation fields. In this way, the spin-exchange relaxation is almost eliminated. Benefiting from the low spin relaxation rate, the parametric resonance scheme exhibits a narrower linewidth and stronger signal, which results in a higher sensitivity. With a 6×6×3 mm^{3} Rb atomic vapor cell, we developed an rf atomic magnetometer with a noise floor of 2 fT/Hz^{1/2}, which is about one order of magnitude higher than the sensitivity achieved in the magnetic-resonance-based scheme. The presented rf detection scheme holds promise in advancing rf atomic magnetometers and brings new insight into their various applications.

On the reduction of gas permeation through the glass windows of micromachined vapor cells using Al2O3 coatings

Stability and precision of atomic devices are closely tied to the quality and stability of the internal atmosphere of the atomic vapor cells on which they rely. Such an atmosphere can be stabilized by building the cell with low permeation materials such as sapphire or aluminosilicate glass in microfabricated devices. Recently, we have shown that permeation barriers made of Al2O3 thin-film coatings deposited on standard borosilicate glass could be an alternative for buffer gas pressure stabilization. In this study, we, hence, investigate how helium permeation is influenced by the thickness, ranging from 5 to 40 nm, of such Al2O3 thin films coated by atomic layer deposition. Permeation rates are derived from long-term measurements of the pressure-shifted transition frequency of a coherent population trapping (CPT) atomic clock. From thicknesses of 20 nm onward, a significant enhancement of the cell hermeticity is experienced, corresponding to two orders of magnitude lower helium permeation rate. In addition, we test cesium vapor cells filled with neon as a buffer gas and whose windows are coated with 20 nm of Al2O3. As for helium, the permeation rate of neon is significantly reduced, thanks to alumina coatings, leading to a fractional frequency stability of 4×10−12 at 1 day when the cell is used in a CPT clock. These features outperform the typical performances of uncoated Cs–Ne borosilicate cells and highlight the significance of Al2O3 coatings for buffer gas pressure stabilization.

Doppler sensitivity and resonant tuning of Rydberg atom-based antennas

Radio frequency antennas based on Rydberg atom vapor cells can in principle reach sensitivities beyond those of any conventional wire antenna, especially at lower frequencies where very long wires are needed to accommodate the increasing wavelength. They also have other desirable features such as consisting of nonmetallic, hence lower profile, elements. This paper presents a detailed theoretical investigation of Rydberg antenna sensitivity, elucidating parameter regimes that could cumulatively lead to a sensitivity increase 2–3 orders of magnitude beyond that of currently tested configurations. The key insight is to optimally combine the advantages of two well-studied approaches: (i) three laser ‘2D star configuration’ setups that, when enhanced with increased laser power, to some degree compensate for atom motion-induced Doppler broadening, and (ii) resonant coupling between a pair of near-degenerate Rydberg levels, tuned via a local oscillator to the incident signal of interest. The advantage of the star setup is subtle because it only restores the overall sensitivity to the expected Doppler-limited value, compensating for additional significant off-resonance reductions where differently moving atom sub-populations destructively interfere with each other in the net signal. An additional unique advantage of local oscillator tuning is that it leads to vastly narrower line widths, as low as ∼10 kHz set by the intrinsic Rydberg state lifetimes, rather than the typical ∼10 MHz scale set by the core state lifetimes. Intuitively, with this setup the two Rydberg states may be tuned to act as an independent high-q cavity, a point of view supported by a study of the frequency-dependence of the antenna resonant response. There are a number of practical experimental advances, especially larger ∼1 cm laser beam widths, required to suppress various extrinsic line broadening effects and to fully exploit this ‘Rydberg superheterodyne’ response.

Utilizing quantum coherence in Cs Rydberg atoms for high-sensitivity room-temperature terahertz detection: a theoretical exploration

In recent years, terahertz (THz) technology has made significant progress in numerous applications; however, the highly sensitive, room-temperature THz detectors are still rare, which is one of the bottlenecks in THz research. In this paper, we proposed a room-temperature electrometry method for THz detection by laser spectroscopy of cesium (Cs133) Rydberg atoms, and conducted a comprehensive investigation of the five-level system involving electromagnetically induced transparency (EIT), electromagnetically induced absorption (EIA), and Autler–Townes (AT) splitting in Cs133 cascades. By solving the Lindblad master equation, we found that the influence of the THz electric field, probe laser, dressing laser, and Rydberg laser on the ground state atomic population as well as the coherence between the ground state and the Rydberg state, plays a crucial role in the transformation and amplitude of the EIT and EIA signals. Temperature and the atomic vapor cell’s dimensions affect the number of Cs133 atoms involved in the detection, and ultimately determine the sensitivity. We predicted the proposed quantum coherence THz detection method has a remarkable sensitivity of as low as 10−9 V m−1 Hz−1/2. This research offers a valuable theoretical basis for implementing and optimizing quantum coherence effects based on Rydberg atoms for THz wave detection with high sensitivity and room-temperature operation.

Coherent control on the generation and annihilation of a pseudospin-induced optical vortex in a honeycomb photonic lattice.

We experimentally investigate the coherently controllable generation and annihilation of a pseudospin-induced optical vortex in an optically induced honeycomb photonic lattice in a Λ-type 85Rb atomic vapor cell. Three Gaussian coupling beams are coupled into the atomic gases to form a hexagonal interference pattern, which can induce a honeycomb photonic lattice under electromagnetically induced transparency. Then, two probe beams interfere with each other to form periodical fringes and cover one set of sublattice in the honeycomb lattice, corresponding to excite the K or K' valleys in momentum space. By properly adjusting the experimental parameters, the generation and annihilation of the induced optical vortex can be effectively controlled. The theoretical simulations based on the Dirac and Schrödinger equations are performed to explore the underlying mechanisms, which will support the observations. The demonstrated properties of such controllable optical vortex may lay the foundation for the design of vortex-based optical devices with multidimensional tunability.

Low-frequency weak electric field measurement based on Rydberg atoms using cavity-enhanced three photon system

Introduction: Rydberg atoms are ideal for measuring electric fields due to their unique physical properties. However, low-frequency electric fields below MHz can be challenging due to the accumulation of ionized free electrons on the atomic vapor cell’s surface, acting as a shield.Method: This paper proposes a Cavity-enhanced three-photon system (CETPS) measurement scheme, which uses a long-wavelength laser to excite the Rydberg state, reducing atomic ionization and enhancing detection spectrum resolution. A theoretical model is proposed to explain the quantum coherence effect of the light field, measured electric field, and the atomic system.Result: The results show that the proposed scheme significantly increases the electromagnetically induced transparency (EIT) spectral peak and narrows the spectral width, resulting in the maximum slope increasing by more than an order of magnitude.Discussion: The paper also discusses the impact of the Rabi frequency of the two laser fields and the coupling coefficient of the optical cavity on the transmission spectrum amplitude and linewidth, along with the optimal configuration of these parameters in the CEPTS scheme.

Mode analysis of spin field of thermal atomic ensembles

The spin dynamics in a thermal atomic vapor cell have been investigated thoroughly over the past decades and have proven to be successful in quantum metrology and memory owing to their long coherent time and manipulation convenience. The existing mean field analysis of spin dynamics among the whole cell is sometimes inaccurate due to the non-uniformity of the ensemble and spatial coupling of multi-physical fields interacting with the ensembles. Here we perform mode analysis onto the quasi-continuous spin field including atomic thermal motion to derive Bloch mode equations and obtain corresponding analytical solutions in diffusion regime. We demonstrate that the widely used mean field dynamics of thermal gas is a particular case in our solution, corresponding to the uniform spatial mode. This mode analysis approach offers a precise method for analyzing the dynamics of the spin ensemble in greater detail from a field perspective, enabling the effective determination of spatially non-uniform multi-physical fields coupling with the spin ensembles, which cannot be accurately analyzed by the mean field method. Furthermore, this work paves the way to address quantum noises and relaxation mechanisms associated with non-uniform fields and inter-atomic interactions, which limit further improvement of ultra-sensitive spin-based sensors.

Generation of subnatural-linewidth orbital angular momentum entangled biphotons using a single driving laser in hot atoms.

Orbital angular momentum (OAM) entangled photon pairs with narrow bandwidths play a crucial role in the interaction of light and quantum states of matter. In this article, we demonstrate an approach for generating OAM entangled photon pairs with a narrow bandwidth by using a single driving beam in a 85Rb atomic vapor cell. This single driving beam is able to simultaneously couple two atomic transitions and directly generate OAM entangled biphotons by leveraging the OAM conservation law through the spontaneous four-wave mixing (SFWM) process. The photon pairs exhibit a maximum cross-correlation function value of 27.7 and a linewidth of 4 MHz. The OAM entanglement is confirmed through quantum state tomography, revealing a fidelity of 95.7% and a concurrence of 0.926 when compared to the maximally entangled state. Our scheme is notably simpler than previously proposed schemes and represents the first demonstration of generating subnatural-linewidth entangled photon pairs in hot atomic systems.