The problem of finite-time decentralized neural adaptive constrained control is studied for large-scale nonlinear time-delay systems in the non-affine form. The main features of the considered system are that 1) unknown unmatched time-delay interactions are considered, 2) the couplings among the nested subsystems are involved in uncertain nonlinear systems, 3) based on finite-time stability approach, asymmetric saturation actuators and output constraints are studied in large-scale systems. First, the smooth asymmetric saturation nonlinearity and barrier Lyapunov functions are used to achieve the input and output constraints. Second, the appropriately designed Lyapunov-Krasovskii functional and the property of hyperbolic tangent functions are used to deal with the unknown unmatched time-delay interactions, and the neural networks are employed to approximate the unknown nonlinearities. Note that, due to unknown time-delay interactions and the couplings among subsystems, the controller design is more meaningful and challenging. At last, based on finite-time stability theory and Lyapunov stability theory, a decentralized adaptive controller is proposed, which decreases the number of learning parameters. It is shown that the designed controller can ensure that all closed-loop signals are bounded and the tracking error converges to a small neighborhood of the origin. The simulation studies are presented to show the effectiveness of the proposed method.