Aspheric microlens arrays (MLAs) are introduced on glass substrate to improve the light out-coupling efficiency (LOCE) of organic light-emitting diode (OLED). Geometric ray tracing was employed to simulate the improved effects and optimize the structure parameters of the MLAs pattern. The simulation results show that when the parameters of MLAs as follows, the curved profile is parabola, the base shape is hexagon, the fill factor is 1, the aspect ratio is 0.6, and the material refractive index should be match to that of the substrate of the OLED, which can improve LOCE maximum.Poly-dimethyl-siloxane (PDMS) parabola curve MLAs films ware fabricated by maskless lithography technique and template replication. The experimental results show that the MLAs can improve the LOCE and the trends of the experimental results agree with the simulation results. A maximum increase of 49 % in the coupling efficiency was achieved.