Anisotropic Magnetic Properties Research Articles

(Invited) An Overview of Electrochemistry Application to Additive Manufacturing

Additive manufacturing (AM) is the process of creating three-dimensional (3D) objects from digital models through the sequential deposition of material in layers. This talk will highlight how researchers have used electrochemical research in additive manufacturing and will provide insights into how technology can be exploited to formulate novel microstructures and optimize the manufacturing process. Electrochemical 3D printing is a relatively new form of AM that creates metallic structures through the electrochemical reduction of metal ions from solutions onto conductive substrates. It involves localized electrochemical deposition of metals combined with additive manufacturing principles to achieve Electrochemical Additive Manufacturing (ECAM). The talk will also focus on the formulation of metal precursor inks to produce novel metallic microstructures and nanoalloys containing multiple metals. These inks are used with AM techniques to fabricate 2D and 3D printed conductive structures directly onto a substrate. Examples include aligned nickel nanowires over large areas, which provide opportunities to produce structures with enhanced anisotropic electrical and magnetic properties. Nanoalloy films printed using metal precursor inks have a variety of important applications involving local control of alloy composition in AM part. Examples include the facile formation of layered nanostructures and electrical conductivity with oxidative stability. The talk will conclude with current research on electropolishing of AM parts. AM while capable of producing complex-shaped metal parts with intricate internal geometries and lattice structures struggles to make parts with the smooth surface finish required for many applications. Polishing interior surfaces inaccessible to traditional surface polishing methods is a challenge. Electropolishing is increasingly being used as a post-treatment option for metal AM parts due to its non-contact nature and ability to finish complex internal features.

Tunable Magnetic Domain Patterns in Thickness-Gradient Nickel Films on Flexible PDMS Substrates.

Flexible magnetoelectronic devices (based on magnetic films) have great application prospects in the fields of information storages, bionic robotics, and electronic skins. The intrinsic stress and external loading are very important to modulate the structures and properties of flexible magnetic films due to the magnetoelastic coupling effect. Here, we report on tunable magnetic domain patterns in thickness-gradient nickel (Ni) films deposited on flexible polydimethylsiloxane substrates. It is found that stripe magnetic domains spontaneously form in the Ni films and their sizes increase with the film thickness. The internal stress evolves from tensile to compressive states with decreasing film thickness, leading to the formation of cracks in thicker regions and wrinkles in thinner regions. Meanwhile, the orientations of stripe magnetic domains change from the gradient direction to the orthogonal direction. The structural features, evolution behaviors, and physical mechanisms of the cracks, wrinkles, and magnetic domains are analyzed based on the stress theory and magnetoelastic coupling. Periodic gradient Ni films with large-scale regulations of stripe magnetic domains are also realized by masking of copper grids. This study helps to better understand the magnetoelastic coupling effect in gradient flexible magnetic films and provides a technique to modulate anisotropic magnetic properties by designing specific film systems.

Magnetically-assisted digital light processing 4D printing of flexible anisotropic soft-Magnetic composites

ABSTRACT Flexible anisotropic soft-magnetic composite (FASMC) presents superior magnetic properties in one or more specified directions, showing great potential in the application of microwave absorption, soft robots, and other smart sensors/actuators. However, the fabrication of FASMC using additive manufacturing is challenging due to a trade-off between magnetic properties of the composites enhanced by iron particles and printability during printing. Here, we developed a 4D printing scheme using flexible soft-magnetic photosensitive resin consisting of flexible long-chin acrylic resin monomer and soft magnetic iron particles. Multiple complex structures with good spatial resolution of ∼170 μm were fabricated using magnetic field-assisted digital light processing (MF-DLP). Directional magnetic field was applied during printing, enabling the fabrication of FASMC with strong anisotropic magnetic properties. FASMC with high CIP (carbonyl iron powder, CIP) concentration of up to 45 wt.% was fabricated with excellent tensile strength and elongation up to 460%. Strong anisotropic magnetic properties were demonstrated through a series of stimuli-response testing such as large deformation, anti-deflection, controlled motion, variable stiffness metamaterial, and array assembly, under external magnetic field. This study demonstrates the feasibility and potential of MF-DLP technique for fabrication of FASMC, shedding light on the design and fabrication of next-generation sensors and actuators.

Facile preparation of bonded NdFeB/SmFeN hybrid magnets with flexibility, anisotropy and high energy density

The application of rubber isotropic bonded magnets is limited due to low energy density, although it remainsunbeatableintermsofprice and production rate. In this paper, high-filled, flexible, and anisotropic NdFeB/SmFeN bonded magnets were prepared using mixtures of fine SmFeN powders and coarse NdFeB powders by calendering molding. The optical microscope images show that adding fine SmFeN powder benefits processability, leading to higher loading while retaining flexibility. The magnetic property and microstructure of the magnets display the anisotropic magnetic property of NdFeB/SmFeN bonded magnets derived from the arrangement of the platelet-shaped NdFeB particles induced by mechanical stress during the calendaring process. To further optimize the magnetic properties of NdFeB/SmFeN bonded magnets, the NdFeB was sieved and then mixed with SmFeN to mold into sheets. Finally, the effect of NdFeB particle size on the magnetic and mechanical properties of NdFeB/SmFeN bonded magnets was investigated. The results showed that when the particle size of the NdFeB particle was 75–100 µm, the magnetic properties of magnets reached the maximum value (Br = 7.77 KG, Hcj = 14.70 KOe, (BH)max = 12.70 MGOe) with density of 5.59 g/cm3. In addition, the tensile strength of the NdFeB/SmFeN bonded magnets increases and the sample standard deviation narrows with decreasing NdFeB particle size. This method provides a facile preparation for anisotropic bonded magnets with a new energy density record of rubber bonded rolled magnets prepared without an external field.

Magnetic Behavior of Trigonal (Bi-)pyramidal 3d8 Mononuclear Nanomagnets: The Case of [Ni(MDABCO)2Cl3]ClO4.

This paper attempts to shed light on the origin of the magnetic behavior specific to trigonal bi- and pyramidal 3d8 mono- and polynuclear nanomagnets. The focus lies on entirely unraveling the system's intrinsic microscopic mechanisms and fundamental quantum mechanical relations governing the underlying electron dynamics. To this end, we develop a self-consistent approach to characterize, in great detail, all electron correlations and the ensuing fine structure of the energy spectra of a broad class of 3d8 systems. The mathematical framework is based on the multiconfigurational self-consistent field method and is devised to account for prospective quantum mechanical constraints that may confine the electron orbital dynamics while preserving the properties of all measurable quantities. We successfully characterize the experimentally observed magnetic anisotropy properties of a slightly distorted trigonal bipyramidal Ni2+ coordination complex, demonstrating that such compounds do not exhibit intrinsic huge zero-field splitting and inherent giant magnetic anisotropy. We reproduce qualitatively and quantitatively the behavior of the low-field magnetic susceptibility, magnetization, low-, and high-field electron paramagnetic resonance spectroscopy measurements and provide an in-depth analysis of the obtained results.

Influence of energy density on the microstructure, growth orientation, and anisotropy of magnetic properties in additively manufactured Fe-3.8wt%Si transformer steels

Fe-3.8wt%Si transformer steels were processed using two different additive manufacturing (AM) techniques, laser powder bed fusion (LPBF) and directed energy deposition (DED). While the LPBF processed samples exhibited a strong <001> orientation of the BCC grains along the build axis, the DED processed samples exhibited a randomized texture along the build axis. DED processed samples showed substantially coarser columnar grains as compared to their LPBF counterparts. The columnar grains exhibited a substantial number of low-angle sub-grain boundaries. All samples exhibited very good soft magnetic properties, with saturation magnetization (Ms) values ranging from 205 - 232 emu/gm, and coercivity (Hc) values ranging from 1.2 – 4.2 Oe. The Coercivity (Hc) values were significantly lower when the magnetic field was applied parallel to the build axis, as compared to being perpendicular, which can be rationalized based on the columnar nature of the grains, resulting in a higher number density of grain boundaries in case of the field applied perpendicular to the build axis.

Nanocrystalline Nd–Fe–B Anisotropic Magnets by Flash Spark Plasma Sintering

Flash spark plasma sintering (flash SPS) is an attractive method to obtain Nd–Fe–B magnets with anisotropic magnetic properties when starting from melt‐spun powders. Compared to the benchmark processing route via hot pressing with subsequent die upsetting, flash SPS promises electroplasticity as an additional deformation mechanism and reduced tool wear, while maximizing magnetic properties by tailoring the microstructure—fully dense and high texture. A detailed parameter study is conducted to understand the influence of Flash SPS parameters on the densification and magnetic properties of commercial MQU‐F powder. It is revealed that the presintering conditions and preheating temperature before applying the power pulse play a major role for tailoring grain size and texture in the case of hot deformation via Flash SPS. Detailed microstructure and magnetic domain evaluation disclose the texture enhancement with increasing flash SPS temperature at the expense of coercivity. The best compromise between remanence and coercivity (1.37 T and 1195 kA m−1, respectively) is achieved through a combination of presintering at 500 °C for 120 s and preheating temperature of 600 °C, resulting in a magnet with energy product (BH)max of 350 kJm−3. These findings show the potential of flash SPS to obtain fully dense anisotropic nanocrystalline magnets with high magnetic performance.

Anisotropic magnetic and magnetotransport properties in morphologically distinct Nd0.6Sr0.4MnO3 thin films

We investigate the magnetic and magnetotransport properties of nanostructured Nd0.6Sr0.4MnO3 (NSMO) thin films grown on (100) oriented SrTiO3 (STO) substrates. The thin films of 100 nm thickness fabricated using the pulsed laser deposition technique possess two distinct surface morphologies—granular and nano-rod type. The morphological change present in the system significantly affects the magnetic and magnetotransport properties of the thin films. Magnetization measurements revealed that the films with rod-type morphology exhibit improved in-plane magnetic anisotropy. The colossal magnetoresistance (∆R/R(H = 0)) of the granular sample is ∼91 %, and the rod morphology sample is ∼97 % at 3 T magnetic field. Additionally, magnetotransport studies revealed that the granular thin films display a characteristic butterfly-shaped low-field magneto-resistive (LFMR) behavior with the value of LFMR of up to ∼10 %. Furthermore, it is observed that the thin film’s morphology has a significant effect on the anisotropic magnetoresistance ratio (AMR). Thin films with rod-type morphology show an enhanced AMR of ∼30 % around its metal-insulator transition temperature. Such morphology-dependent tunability in magnetoresistance properties over a wide temperature range is potentially interesting for developing oxide-based sensors and devices.

Magnetic properties of the putative higher-order topological insulator EuIn$_2$As$_2$

In higher-order topological insulator (HOTI), a gap is preserved both for the bulk and the surface states, and only hinges or corners become gapless. Recently, it has been predicted that the antiferromagnetic compound EuIn_22As_22 can host both the HOTI and axion insulator features. Preliminary experimental confirmation of this finding was obtained using angle-resolved photoemission spectroscopy. The main objective of this work was to characterize the anisotropic magnetic properties of single-crystalline EuIn_22As_22. In addition, complementary studies on the transport properties, heat capacity, and magnetocaloric effect in this compound were performed.

Structural and Magnetic Properties of the {Cr(pybd)3[Cu(cyclen)]2}(BF4)4 Heteronuclear Complex

Heterotopic ligands containing chemically different binding centers are appealing candidates for obtaining heteronuclear metal complexes. By exploiting this strategy, it is possible to introduce different paramagnetic centers characterized by specific anisotropic magnetic properties that make them distinguishable when weakly magnetically coupled. This molecular approach has great potential to yield multi-spin adducts capable of mimicking logical architectures necessary for quantum information processing (QIP), i.e., quantum logic gates. A possible route for including a single-ion magnetic center within a finite-sized heterometallic compound uses the asymmetric (1-pyridyl)-butane-1,3-dione (pybd) ligand reported in the literature for obtaining Cr3+−Cu2+ metallo-cages. To avoid the formation of cages, we adopted the cyclen (1,4,7,10-tetraazacyclododecane) ligand as a “capping” agent for the Cu2+ ions. We report here the structural and magnetic characterization of the unprecedented adduct {Cr(pybd)3[Cu(cyclen)]2}(BF4)4, whose structure is characterized by a central Cr3+ ion in a distorted octahedral coordination environment and two peripheral Cu2+ ions with square-pyramidal coordination geometries. As highlighted by Continuous Wave Electron Paramagnetic Resonance (EPR) spectroscopy and Direct Current (DC) magnetometry measurements, this adduct shows negligible intramolecular magnetic couplings, and it maintains the characteristic EPR signals of Cr3+ and Cu2+ moieties when diluted in frozen solutions.

Tunable Magnetic and Optical Anisotropy in ZrO2‐Co Vertically Aligned Nanocomposites

AbstractMetamaterials have gained great research interest in recent years owing to their potential for property tunability, multifunctionality, and property coupling. As a new group of self‐assembled thin films, vertically aligned nanocomposite (VAN)‐based hybrid metamaterials have been demonstrated with significant anisotropic physical properties and a broad range of property tailorability, such as optical anisotropy, magnetic anisotropy, hyperbolic dispersion, and enhanced second harmonic generation properties. Herein, self‐assembled ZrO2‐Co nanocomposite films, with high epitaxial quality and ultra‐fine vertically aligned Co nanopillars (with an average diameter of ≈2 nm) embedded in a ZrO2 matrix, are fabricated using a pulsed laser deposition (PLD) method. The Co pillar density can be effectively tuned by varying the Co concentration in the target, which results in tunable optical properties and magnetic properties. Specifically, a high saturation magnetization of 100 emu cm−3, strong out‐of‐plane magnetic anisotropy and tailorable magnetization properties are achieved via tuning the Co nanopillar density. Coupled with hyperbolic dispersion of dielectric constant from 950 to 1500 nm in wavelength, plasmonic Co metal nanopillars, and the unique dielectric ZrO2 matrix, this new nanoscale hybrid metamaterial shows great potential for future integrated optical and magnetic device designs.

Synthesis and anisotropic magnetic properties of LiCrTe single crystals with a triangular-lattice antiferromagnetic structure

We report on the synthesis of LiCrTe single crystals and on their anisotropic magnetic properties. We have obtained these single crystals by employing a Te/Li-flux synthesis method. We find LiCrTe to crystallize in a TlCdS -type structure with cell parameters of a = 3.9512(5) Å and c = 6.6196(7) Å at T = 175 K. The content of lithium in these crystals was determined to be neary stoichiometric by means of neutron diffraction. We find a pronounced magnetic transition at = 144 K and = 148 K, respectively. These transition temperatures are substantially higher than earlier reports on polycrystalline samples. We have performed neutron powder diffraction measurements that reveal that the long-range low-temperature magnetic structure of single crystalline LiCrTe is an A-type antiferromagnetic structure. Our DFT calculations are in good agreement with these experimental observations. We find the system to be easy axis with moments oriented along the c-direction experimentally as well as in our calculations. Thereby, the magnetic Hamiltonian can be written as with K (where ). We find LiCrTe to be highly anisotropic, with a pronounced metamagnetic transition for with a critical field of (5 K) ≈ 2.5 T. Using detailed orientation-dependent magnetization measurements, we have determined the magnetic phase diagram of this material. Our findings suggest that LiCrTe is a promising material for exploring the interplay between crystal structure and magnetism, and could have potential applications in spin-based 2D devices.

Differences in the Optical Response of MSU and CPP Crystals During Magnetic Orientation: Possibility of Diagnosing Gout and Pseudogout.

Pseudogout is crystalline arthritis. It has a similar clinical picture to that of gout, and it is difficult to distinguish the two diseases using conventional analysis methods. However, it is important to identify the different crystals responsible for these two cases because the treatment strategies are different. In a previous study, we reported magnetic orientation of monosodium urate (MSU) crystals, which are the causative agent of gout, at the permanent magnet level. In this study, we investigated the effect of an applied magnetic field on calcium pyrophosphate (CPP) crystals, which are the causative agent of pseudogout, and the difference in the magnetic responses of CPP and MSU crystals. We found that the CPP crystals were oriented in a magnetic field on milli-Tesla order because of the anisotropy of the diamagnetic susceptibility. In addition, the CPP crystals exhibited different anisotropic magnetic properties from those of MSU crystals, which led to a characteristic difference between the orientations of the two crystals. That is, we found that the causative agents of gout and pseudogout responded differently to a magnetic field. This report suggests that the discrimination between CPP and MSU by optical measurements is possible by application of magnetic fields appropriately. © 2023 Bioelectromagnetics Society.

Thickness-tunable magnetic and electronic transport properties of the quasi-two-dimensional van der Waals ferromagnet Co0.27TaS2 with disordered intercalation

The intercalation of magnetic elements in nonmagnetic van der Waals (vdW) materials is an effective way to design different (quasi) 2D magnets and produce exotic properties. More specifically, how exactly the intercalator is distributed within the synthetic crystal can also affect the physical properties substantially. In contrast to conventional $3d$ transition-metal intercalates of niobium and tantalum dichalcogenides, which commonly have $2\ifmmode\times\else\texttimes\fi{}2$ or $\sqrt{3}\ifmmode\times\else\texttimes\fi{}\sqrt{3}$ type ordered intercalation, we report a disordered intercalation of Co atoms between the vdW gaps of $2H$-tantalum disulfide ($2H\text{-Ta}{\mathrm{S}}_{2}$). The obtained quasi-vdW ferromagnet ${\mathrm{Co}}_{0.27}\mathrm{Ta}{\mathrm{S}}_{2}$ shows both perpendicular magnetic anisotropy and thickness-tunable magnetic properties. More interestingly, the temperature dependence of electrical resistivity shows a semiconductorlike behavior, in contrast to the metallic feature of other analogs in this material family. This unexpected phenomenon can be understood through a variable-range hopping mechanism, which is due to highly disordered intercalation. Moreover, ${\mathrm{Co}}_{0.27}\mathrm{Ta}{\mathrm{S}}_{2}$ shows a side-jump scattering dominated anomalous Hall effect, which can also be related to the disordered distribution of Co intercalators.

Magnetic field-assisted DLP of CIPs/resin composites: Mechanical properties, anisotropic magnetic performance and wear behavior

Fabrication of composites with anisotropic properties by additive manufacturing has drawn great attention in recent years. Magnetic-assisted digital light processing (DLP) of micron-scale carbonyl iron powders (CIPs)/resin composites (MACRCs) with tunable microstructure and magnetic properties can be used as smart sensors/actuators in soft robots, aerospace/automobile applications and drug delivery devices due to their complex geometries and fast activation response. However, anisotropic, wear and mechanical properties remain unclear for MACRCs. This work aims to investigate their microstructure-function-wear resistance relationship. Photosensitive resin and CIPs with a concentration up to 5 wt% were prepared to print samples with different anisotropic magnetic properties, using magnetic field-assisted techniques. The results show that addition of CIPs in resin can still maintain good printability, while the mechanical properties deteriorate slightly as the micro-size CIPs reduced the interface bonding strength. Anisotropic magnetic properties were studied using the magnetization tests. In addition, wear tests showed that the coefficient of friction of samples decreases from 0.4938 (pure resin) to 0.4066 (MACRCs with 5 wt% CIPs), indicating improved wear resistance by the addition of CIPs. This work demonstrated that tunable magnetic and mechanical properties can be achieved by manipulation anisotropy of the magnetic nanoparticles using external magnetic field.

Structural, magnetic and Magnetic-Microstructural properties of sputtered FeCoNi thin films

This paper reports the effect of growth rate and substrate temperature on the composition, structure, microstructure, magnetic and magnetic microstructural properties of Fe-Co-Ni alloy thin films. 200 nm thick Fe-Co-Ni thin films were grown by high power impulse magnetron sputtering on Si 〈100〉 at different growth rates (viz., 1 – 2.4 Å/s). Films were also thermally processed by modifying the substrate temperatures. Room temperature deposited films showed the presence of FCC structure for all the films. However, films grown at higher substrate temperatures displayed presence of BCC phase co-existing with FCC phase. High saturation magnetization combined with low coercivity has been obtained for the Fe-Co-Ni films grown at higher growth rate and enhanced substrate temperature. Magnetization and magnetic microstructural studies using Kerr microscopy showed anisotropic magnetic properties along the plane of the film with the magnetization reversal dominated by domain wall motion and domain wall rotation.

Magnetic and structural properties of sputtered thick Co2FeSi alloy films

We investigate magnetic and structural properties of the sputtered thick Co2FeSi (CFS) alloy films. X-ray diffraction measurements show CFS alloy film changes from amorphous to disordered A2 structures after annealing, which leads to pronounced increase in saturation magnetization. For the as-deposited films in-plane uniaxial magnetic anisotropy is determined to be in the range of 103–104 erg/cm3, showing strongly dependent to film thickness. After annealing a fourfold cubic magnetic anisotropy is witnessed. Structural ordering is observed to improve with increasing film thickness. Similiar trend of the magnetic anisotropy with sputtering power is witnessed, which can be explained by equivalent annealing effect of the high-power sputtering. Our results show that magnetic anisotropy properties of the CFS alloy films are strongly dependent to film thickness and structural ordering, tuned by anealing tempeature and sputtering power. These findings may be helpful for designing Co2FeSi-based spintronic devices.

Itinerant-localized dichotomy in magnetic anisotropic properties of U-based ferromagnets

The electronic structure, spin and orbital magnetic moments, and the magnetic anisotropy energy in selected U-based compounds are investigated making use of the correlated band theory. First, we demonstrate that the LSDA+U approach with exact atomic limit implemented as a combination of the relativistic density functional theory with the Anderson impurity model provides a good quantitative description for UGa{}_2. Further, the method is applied to UFe_{12} and UFe{}_{10}Si{}_2 ferromagnets. The calculated positive uniaxial magnetic anisotropy together with negative enthalpy of formation for UFe{}_{10}Si{}_2 make it as a candidate for the magnetically hard materials. Our studies suggest a viable route for further development of the rare-earth-lean permanent magnets by replacing a part of U atoms by some rare-earth like Sm in UFe{}_{10}Si{}_2.

Field-Free Current-Induced Switching of L 1 0 - FePt Using Interlayer Exchange Coupling for Neuromorphic Computing

$L{1}_{0}$-phase $\mathrm{Fe}\mathrm{Pt}$ is well known for its unusually robust perpendicular magnetic anisotropy (PMA) properties arising from strong conduction-electron spin-orbit coupling (SOC) with the $\mathrm{Fe}$ orbital moment. The strong PMA enables stable magnetic storage and memory devices with ultrahigh capacity. Meanwhile, SOC is also the premise of the recently discovered spin-orbit-torque (SOT) effect, which opens avenues for possible electrical manipulation of magnetization for $L{1}_{0}$-$\mathrm{Fe}\mathrm{Pt}$. The bulk SOT of the $L{1}_{0}$-$\mathrm{Fe}\mathrm{Pt}$ single layer was discovered recently; this leads to the magnetization of $L{1}_{0}$-$\mathrm{Fe}\mathrm{Pt}$ reversibly switching on itself. However, deterministic SOT switching of bulk perpendicularly magnetized $\mathrm{Fe}\mathrm{Pt}$ magnets relies on an external magnetic field to break the symmetry. Here, the symmetry-breaking issue is resolved by interlayer exchange coupling, where the $\mathrm{Fe}\mathrm{Pt}$ layer is coupled with an in-plane magnetized $\mathrm{Ni}\mathrm{Fe}$ layer through a $\mathrm{Ti}\mathrm{N}$ spacer layer. Furthermore, our device also presents memristive or gradual switching behaviors, even without an external field, offering the potential for constructing spin synapses and spin neurons for neuromorphic computing. An artificial neural network with high accuracy (\ensuremath{\sim}91.17%) is realized based on the constructed synapses and neurons. Our work paves the way for field-free SOT switching of single bulk PMA magnets and their potential applications in neuromorphic computing.

Preparation, Characterization of New Antimicrobial Antitumor Hybrid Semi-Organic Single Crystals of Proline Amino Acid Doped by Silver Nanoparticles.

Proline is water soluble amino acid extensively used in drug delivery systems. Compounds of cobalt (Co) transition metal have potent antimicrobial and anticancer activities. However, a drug delivery system combining proline cobalt is not reported yet. For the first time, new hybrid semi-organic single crystals of proline cobalt chloride (PCC) are prepared. The novelty of the article is also that single crystal proline cobalt chloride showed potent antimicrobial and antitumor activity. Doping of PCC by Ag0NPs significantly increased these biological activities. The anisotropic magnetic properties of single crystals can mitigate the cytotoxicity of Ag0NPs on normal cells. Silver nanoparticles (Ag0NPs) improved the crystal habits and physicochemical properties. Ag0NPs showed the best performance, paramagnetic materials n-type semiconductors due to delocalized excess electrons of Ag0NPs incorporated in the crystal lattice interstitially. Crystals have high absorptivity for UV-radiation electromagnetic radiation. Ag0NPs enhanced AC electrical conductivity up to 2.3 × 104 Ω cm-1 due to high electron density. Proline doped crystals are obtained in good purity as triclinic unit cell with having anisotropic magnetism. PCCAg0NPs crystal exhibited: high antimicrobial activities to various bacterial and fungal species, inhibition zone (mm): 21, 25, 24, 26, 30, 28, 12, and 46 for S. aureus, E. faecalis, S. typhi, E. coli, P. aerugino, K. pneumoniae, A. braselienses, and C. albicans, respectively, in comparison to ciprofloxacin antibiotic (23, 0, 26, 26, 25, 0, 0, 0) for the same tested species, respectively; higher cytotoxicity against breast cancer cells (IC50 22.1 μM) than the reference drug cisplatin (IC50 11.7 μM); and lower cytotoxicity to normal healthy lung cells MRC-5, (IC50 145.5 μM) than cisplatin (IC50 30.2 μM). Hence, this crystal is a candidate for chemotherapy of breast cancer.