Alternative Energy Storage Research Articles

Electrochemo-Mechanics insights of Sn foil anode in Sodium-Ion batteries.

The development of high-performance sodium-ion batteries (SIBs) is crucial to meeting the growing demand for low-cost, sustainable energy storage alternatives to lithium-ion batteries (LIBs). However, achieving stable cycling performance in SIBs is challenging, particularly with tin (Sn) foil anodes, which suffer from issues like sodium trapping and structural degradation due to significant volume changes during sodiation and desodiation. In this study, we investigate the electrochemo-mechanical behavior of Sn foil anodes, focusing on the mechanisms of sodium trapping and structural evolution that impair battery performance. We demonstrate that sodiation forms a porous coral-like structure in Sn, which, while increasing surface area, also contributes to severe volume expansion, crack formation, and diffusive sodium trapping. We further explore zinc (Zn)-doped Sn foils, revealing that Zn-rich phases create additional fast sodium diffusion channels, significantly reducing sodium retention and enhancing the anode's structural integrity. Based on these insights, we propose several improvement strategies, including electrolyte additives, optimized electrode architecture, microstructural defect engineering, and artificial solid-electrolyte interface (SEI) coatings, all aimed at enhancing cycle stability and performance. This work provides a comprehensive understanding of Sn-based anodes and offers practical pathways for advancing SIBs technology.

High Performance Sodium‐Ion Hybrid Capacitor Based on Graphene‐Tin Pyrophosphate Nanocomposite Anode

AbstractThe development of alternative energy storage technologies such as sodium‐ion hybrid capacitors, which do not rely on critical raw materials such as cobalt or nickel, for the replacement of conventional lithium‐ion batteries for some niche applications, is extremely important to successfully achieve a sustainable development in our planet. In this work, we introduce a novel sodium‐ion hybrid capacitor system formed by the combination of an optimized nanostructured composite material containing reduced graphene oxide and tin pyrophosphate as negative electrode, and a high specific surface area graphene‐carbon composite as positive electrode. The electrochemical performance of each material has been individually evaluated using NaPF6 in EC/DMC as electrolyte, showing impressive specific capacity values above 100 mAh g−1 at 2 A g−1, for both faradaic and capacitive‐type electrodes. The integration of the electrodes in an optimized full cell with anode‐to‐cathode mass balance of 1.5 : 1, enabled stable full cells that can provide energy densities of almost 60 Wh kg−1 at 3,000 W kg−1, showcasing the potential of these type of materials in the design of next generation energy storage systems.

Spray-Flame Synthesis (SFS) and Characterization of Li1.3Al0.3-xYxTi1.7(PO4)3 [LA(Y)TP] Solid Electrolytes.

Solid-state electrolytes for lithium-ion batteries, which enable a significant increase in storage capacity, are at the forefront of alternative energy storage systems due to their attractive properties such as wide electrochemical stability window, relatively superior contact stability against Li metal, inherently dendrite inhibition, and a wide range of temperature functionality. NASICON-type solid electrolytes are an exciting candidate within ceramic electrolytes due to their high ionic conductivity and low moisture sensitivity, making them a prime candidate for pure oxidic and hybrid ceramic-in-polymer composite electrolytes. Here, we report on producing pure and Y-doped Lithium Aluminum Titanium Phosphate (LATP) nanoparticles by spray-flame synthesis. The as-synthesized samples consist of an amorphous component and anatase-TiO2 crystalline particles. Brief annealing at 750-1000 °C for one hour was sufficient to achieve the desired phase while maintaining the material's sub-micrometer scale. Rietveld analysis of X-Ray diffraction data demonstrated that the crystal volume increases with Y doping. At the same time, with high Y incorporation, a segregation of the YPO4 phase was observed in addition to the desired LATP phase. Another impurity phase, LiTiOPO4, was observed besides YPO4 and, with higher calcination temperature (1000 °C), the phase fraction for both impurities also increased. The ionic conductivity increased with Y incorporation from 0.1 mS/cm at room temperature in the undoped sample to 0.84 mS/cm in the case of LAY0.1TP, which makes these materials-especially considering the comparatively low sintering temperature-highly interesting for applications in the field of solid-state batteries.

Enhancing Sodium-Ion Battery Performance: A Focus on Electrode Materials

As lithium-ion batteries (LIBs) near their performance limits, finding alternative energy storage solutions has become crucial for the future of electric vehicles. Sodium-ion batteries (SIBs) have emerged as a promising candidate due to their similar working mechanisms to LIBs, yet they hold the potential for more cost-effective and sustainable energy storage. However, the technology behind SIBs is still in its developmental stages, and achieving commercial viability remains a challenge. This review focuses on the importance of electrode materials in advancing high-performance SIBs. By analyzing several highly regarded studies, this article explores how different types of electrode materials, such as carbon-based anodes and layered oxide cathodes, can improve energy density, cycle life, charge/discharge rates, and overall efficiency. The review also addresses the current challenges these materials face and discusses possible strategies for overcoming them. Ultimately, this paper aims to provide a comprehensive understanding of the key role electrode materials play in driving the future of SIB technology and what advancements are needed to realize their full potential.

Long Durable Prussian-Blue Analogous Cathode for Aqueous Sodium-Ion Batteries

Aqueous sodium-ion batteries are attractive battery alternatives for stationary energy storage due to their inherently low cost and high safety. The development of advanced electrode materials with excellent performance and low cost is crucial for the success of aqueous Na-ion batteries. We recently have studied Prussian-blue analogous based electrodes as promising cathodes for aqueous Na-ion batteries. We found that Na1.88Fe[Fe(CN)6]·0.7H2O exhibited fast ionic diffusion that enables the fast charging rate (> 100C), super long cycle life (> 17,000 cycles), high capacity retention and rate capability. In combination of electrochemical characterization and multimodal synchrotron X-ray scattering and spectroscopy methods, we attributed the superior performance to the sodium deficiency and new phase induced through the ball-milling processes. Our work also underlines the importance of fabricating aqueous batteries on the basis of the Earth-abundant, cost- effective, and non-toxic elements.

Zn-Sn Alloy Seed Layer-Coated Cu Current Collector for Anode-Free Aqueous Zn Ion Batteries

Zn ion batteries (ZIB) stand at the forefront of alternative advanced energy storage technologies due to the intrinsic properties of Zn, including its low reduction potential (-0.76 V vs. SHE), and high theoretical specific capacity (820 mAh g-1) acquired by its multi-electron redox processes. Nonetheless, the utilization of current thick Zn foil anode remains a big challenge to commercialization, caused by the dendrite growth, severe surface side reaction, and high N/P ratio, which leads to the limitation of cell energy density. Herein, we report anode-free technology based on ultra-thin Zn-Sn alloy seed layer-coated Cu foil (ASL@Cu), to break through the limit of cell energy density. Incorporating Sn and carbon in the seed layer results in a strong affinity towards Zn, inhibiting the irreversible surface reactions, and eventually offering efficient electron transport routes. The resulting ASL showed rapid kinetics for Zn2+ deposition (lower nucleation overpotential) and exhibited an extended cycle life at a current density of 4 mA cm-2. This work sheds light on the strategic design of anode-free to achieve outstanding performance with a constrained amount of Zn on the Cu current collector.

Examing Competitive Coordination Structure in Eutectic Electrolyte for Zinc-Ion Batteries

Designing next-generation alternative energy storage devices that feature high safety, low cost, and long operation lifespan is of the utmost importance for future wide range of applications. Aqueous zinc-ion batteries play a vital part in promoting the development of portability, sustainability, and diversification of rechargeable battery systems. Based on the theory of electrolyte solvation chemistry, deep understanding of interaction between electrolyte components and their impact on the chemical properties have significant influence on revitalizing the rechargeable zinc-ion batteries field. Characterized by intermolecular forces and tunable compositions, reorganized ligand-oriented solvation shell in eutectic system can bring potential benefits for Zn plating/stripping. Instead of forming [Zn(H2O)6]2+, the use of organic ligands in deep eutectic solvent electrolytes will allow the formation of multiple Zn coordination. In this case, we tentatively propose a plausible strategy to induce competing organic ligand for original eutectic electrolyte. The competing eutectic ligands enter coordination structure, weakening original interaction and form hydration-deficient complexes. The presence of competing agent enables the enhanced cation-anion binding. Building upon the competitive coordination, four-coordinated ligand-cation-anion cluster enables broadened electrochemical window, shielded active water and enhanced zincophilicity. The altered coordination further leads to robust hybrid organic-inorganic enriched solid electrolyte interphase, enabling passivated surface and suppressed dendrite growth. The in-depth mechanism is demonstrated by a series of excellent performance with high Coulombic efficiency and long working life. This design principle leveraged by eutectic electrolytes with competitive coordination offers a new approach to improve battery performance.

Beyond Lithium: Future Battery Technologies for Sustainable Energy Storage

Known for their high energy density, lithium-ion batteries have become ubiquitous in today’s technology landscape. However, they face critical challenges in terms of safety, availability, and sustainability. With the increasing global demand for energy, there is a growing need for alternative, efficient, and sustainable energy storage solutions. This is driving research into non-lithium battery systems. This paper presents a comprehensive literature review on recent advancements in non-lithium battery technologies, specifically sodium-ion, potassium-ion, magnesium-ion, aluminium-ion, zinc-ion, and calcium-ion batteries. By consulting recent peer-reviewed articles and reviews, we examine the key electrochemical properties and underlying chemistry of each battery system. Additionally, we evaluate their safety considerations, environmental sustainability, and recyclability. The reviewed literature highlights the promising potential of non-lithium batteries to address the limitations of lithium-ion batteries, likely to facilitate sustainable and scalable energy storage solutions across diverse applications.

Exfoliating Ti3AlC2 MAX into Ti3C2Tz MXene: A Powerful Strategy to Enhance High‐Voltage Dielectric Performance of Percolation‐Based PVDF Nanodielectrics

AbstractAll‐solid‐state polymer dielectrics benefit from a superior voltage window and conveniently circumvent fire hazards associated with liquid electrolytes. Nevertheless, their future competitiveness with alternative energy storage technologies requires a significant enhancement in their energy density. The addition of conductive 2D MXene particles is a promising strategy for creating percolation‐based nanodielectrics with improved dielectric response. However, a full understanding of the nanodielectric production – microstructure – dielectric performance correlations is crucial. Therefore, this research considered Ti3AlC2 MAX phase and Ti3C2Tz MXene as electrically conductive ceramic fillers in polyvinylidene fluoride (PVDF). Microstructural characterization of both nanodielectrics demonstrated excellent filler dispersion. Additionally, the exfoliation of Ti3AlC2 brought forth extensive alignment and interface accessibility, synergistically activating a pronounced interfacial polarization and nanocapacitor mechanism that enhanced the energy density of PVDF by a factor 100 to 3.1 Wh kg−1@0.1 Hz at 22.9 vol% MXene filler. The stellar increase in the PVDF energy density occurred for a broad MXene filler loading range owing to the unique 2D morphology of MXenes, whereas the addition of Ti3AlC2 fillers only caused a detrimental reduction. Hence, this study buttressed the importance to exfoliate the parental MAX phase into multi‐layered MXene as a decisive strategy for boosting nanodielectric performance.

Applications of Graphene Derivatives in All‐Solid‐State Supercapacitors

AbstractThe recent progression in electronics and humankind's increased dependence on electronic gadgets have significantly impacted energy supply and demand metrics. In the past, batteries have been able to meet these demands adequately. However, their low power density (Ps) has inspired alternative energy storage advancements that can foster a transition to net‐carbon‐zero via renewables. Supercapacitor (SC) innovations, such as the recent emergence of solid‐state supercapacitors (SSCs), have gained tremendous attention owing to their mechanical robustness, safety, possible flexibility, long cycle life, portability, prospective high Ps, and suitability for advanced energy technologies. Complimentary to the affordable and lightweight material design requirements is the enormous potential of the graphene family in SSCs owing to facile synthesis advantages, easy scalability and, processing high electrical conductivity, low costs, and mechanical robustness among others. Therefore, the review highlights the recent efforts to advance SSCs with the graphene family in electrodes and electrolytes. The work discusses SC basic concepts and main characterization techniques, and applications of the graphene family in both electrolytes and electrodes of SSCs. Finally, the merits, demerits and prospects of incorporating graphene derivatives to advance SSC performance and sustainability are outlined. Key research directions, including machine learning, are also recommended from the reviewed studies.

Effect of glycerin on the physical properties of polyvinyl alcohol/sodium alginate blend

Because of the abundance of sodium resources, sodium-ion batteries (NIBs) offer a promising alternative electrochemical energy storage solution. One of the current roadblocks to the development of NIBs technology is a lack of electrode materials capable of reversibly storing/releasing sodium ions for a sufficiently long time. Thus, this work aims to study, theoretically, the effect of glycerin incorporation on polyvinyl alcohol (PVA)/sodium alginate (Na Alg) blend as electrode materials for NIBs. The electronic, thermal, and quantitative structure-activity relationship (QSAR) descriptors of polymer electrolytes based on a blend of PVA and Na Alg and glycerin are the main topics of this work. These properties are examined here using semi-empirical methods and the density functional theory (DFT). Bandgap energy (Eg) is examined because the structural analysis reveals details regarding the interactions between PVA/Na Alg and glycerin. The findings indicate that the addition of glycerin caused the Eg value to drop to 0.2814 eV. The molecular electrostatic potential surface, or MESP, shows the electron-rich and deficit regions throughout the electrolyte system as well as the distribution of molecular charges. Thermal parameters that are studied include enthalpy (H), entropy (ΔS), heat capacity (Cp), Gibbs’ free energy (G), and heat of formation. Additionally, the study examines several QSAR descriptors, such as total dipole moment (TDM), total energy (E), ionization potential (IP), Log P, and Polarizability. The results show that H, ΔS, Cp, G, and TDM increased with increasing temperature and glycerin content. Meanwhile, heat of formation, IP, and E decreased, improving reactivity and polarizability. Additionally, the cell voltage increased to 2.488 V due to glycerin addition. The overall DFT and PM6 calculations of cost-effective PVA/Na Alg based glycerin electrolytes indicate that they can partially replace lithium-ion batteries due to their multifunctionality, but requires further improvement and investigations.

Summary, Future, and Challenges of Fluoride‐Ion Batteries

Due to the limitations of lithium‐ion batteries (LIBs), there is an urgent need to explore alternative energy storage technologies. However, the high‐energy density of fluoride‐ion batteries (FIBs) has attracted widespread attention as a potential successor to LIBs. FIBs are emerging as a low‐cost, safe, and versatile energy storage solution, with a broad operating temperature range. With continuous efforts from researchers, significant progress has been made in the field of FIBs. Nevertheless, compared to traditional batteries, research on FIBs remains limited, and many challenges and unexplored avenues persist. This article elucidates the principles of FIBs, summarizes the materials for both cathodes and anodes, discusses electrolytes, and addresses existing issues. It also outlines future directions and potential applications of FIBs. As it is continued to innovate and explore, FIBs hold promise for revolutionizing energy storage technology, offering enhanced performance, safety, and sustainability.

An electrical double-layer supercapacitor based on a biomass-activated charcoal electrode and ionic liquid with excellent charge-discharge cycle stability 

Supercapacitors that exhibit high power density and safety are emerging as alternative energy storage devices. The construction and performance of a supercapacitor using the ionic liquid, triethylammonium thiocyanate, as the electrolyte and biomass-activated charcoal films as the electrode are described. Enhancements in both energy and power density were observed even for 10,000 charge-discharge cycles. The fabricated supercapacitor with ionic liquid and activated charcoal-based electrodes showed an impressive specific capacitance retention of 142% even after 10,000 cycles at a scan rate of 500 mv s-1, which is attributed to the clearing of ion conducting pathways and enhanced charge transport with increasing temperature. Impedance analysis confirmed the reduction of resistive losses with increasing cycle numbers. The initial energy and power densities of the Electrical double-layer capacitance (EDLC) were 0.926 W h kg-1 and 5681 W kg-1, and they showed 42.2 % and 60.6 % increments after supercapacitors cycles. The study reveals low-cost biomass-based activated carbon electrodes and trimethylamine thiocyanate can be used to prepare supercapacitors with remarkable cycling performances.

An Organic Acid-Alkali Coregulated Ionic Liquid Electrolyte Enabling Wide-Temperature-Range Proton Battery.

The broad applications of rechargeable batteries urge people to develop alternative energy storage devices with sustainable resources, high capacity, long cycling life, and wide-temperature operability. Aqueous proton batteries are considered as a state-of-the-art energy storage system due to their intrinsic safety and low cost. However, aqueous electrolytes have a low boiling point and narrow electrochemical stability window, limiting their applications in wide-temperature and high-energy batteries. Herein, a hybrid organic ionic liquid electrolyte with organic alkali 1-methyl-1,2,4-triazole (MTA) protonated by organic acid bis(trifluoromethysulfonyl)imide (HTFSI) as proton carriers and tetramethylene sulfone (TMS) as the solvent, noted as HTFSI-MTA-TMS, exhibited the stable electrochemical windows exceeding 5V at -20°C and 3.5V at 80°C. Benefiting from this electrolyte, the assembled MnO2-S//MoO3 button proton full battery can display an operation voltage up to 1.8V, energy density of 44.8Wh kg-1, and good cycling stability at room temperature when bis(trifluoromethanesulfonyl)imide manganese (II) salt (Mn(TFSI)2) is introduced into the electrolyte, and run well in a wide-temperature range (-20°C-60°C). The work reveals the potential of organic acid-alkali coregulated electrolytes to meet the need of energy storage in a wide-temperature range and will advance the development of high-energy proton batteries.

Three-component NiO/Fe3O4/rGO nanostructure as an electrode material towards supercapacitor and alcohol electrooxidation

A nanocomposite made of nickel oxide and iron oxide (NiO/Fe3O4) and its hybrid with reduced graphene oxide (rGO) as a conductive substrate with a highly functional surface (NiO/Fe3O4/rGO) was synthesized using a simple hydrothermal approach. This study addresses the challenge of developing efficient materials for energy storage and alcohol fuel cells. After confirming the synthesis through structural analysis, the potential of these nanocomposites as supercapacitor electrodes and catalysts for methanol and ethanol oxidation in alcohol fuel cells were evaluated. The synergy of combining the two metal oxides and adding rGO to the composite structure led to excellent electrocatalytic activity in alcohol oxidation. For the modified NiO/Fe3O4/rGO electrode in the methanol oxidation reaction (MOR), a current density of 450 mA/cm2 at 0.67 V and excellent catalyst stability of 98.7 % over 20 h in chronoamperometric analysis were observed. In the ethanol oxidation reaction (EOR), an oxidative current of 235 mA/cm2 at a peak potential of 0.76 V was seen, with catalyst stability of 96.4 % after 20 h. As a supercapacitor electrode, the NiO/Fe3O4 composite demonstrated a specific capacitance of 946 F/g, while NiO/Fe3O4/rGO showed 1155 F/g. The stability of these electrodes after 10000 GCD cycles was 83.6 % and 90.6 %, respectively. These findings suggest that the proposed structures are cost-effective and reliable alternatives for energy storage and production, suitable for alcohol fuel cells and supercapacitors.

From Bulk to Nanosheet: How Tellurene Can Influence the Performance of Li‐S Batteries on Both Electrodes

AbstractIn the face of growing environmental challenges and the need for alternative energy storage, lithium‐sulfur (Li‐S) batteries stand out for their high theoretical energy density and sulfur's eco‐friendliness. However, the practical application of Li‐S batteries faces significant obstacles, particularly at the cathode and anode. This study explores the transformative impact of 2D tellurene, focusing on how its dimensional variations influence Li‐S battery performance. At the cathode, tellurene not only improves the conductivity and sulfur utilization but also accelerates the conversion of lithium polysulfides (LiPSs). Its reduced size, compared to the bulk counterpart, offers numerous active sites for efficient Li‐ion migration and promotes LiPSs decomposition. At the anode, the protective polytellurosulfides are formed, thereby establishing a stable solid‐electrolyte interphase (SEI) and enhancing reversible lithium deposition. Diminishing the dimensions of tellurene improves its catalytic interface, leading to faster polysulfide conversion kinetics at the cathode and robust SEI formation at the anode. Li‐S batteries equipped with ultra‐thin tellurene‐modified separators demonstrate exceptional performance, exhibiting high areal capacity and significantly reduced capacity decay. Computational simulations further validate the advantages of optimizing tellurene dimensions, confirming its essential role in LiPSs decomposition and overall battery efficiency.

Thermal management analysis with different PCMs in Sodium-Ion batteries

The advent of modern technology has led to a significant increase in the utilisation of rechargeable secondary batteries. Despite the sustainability of lithium-ion (Li-ion) batteries, the limited availability of lithium has driven research into alternative energy storage technologies. Sodium-ion (Na-ion) batteries, as a potential alternative to Li-ion batteries, have emerged as a highly promising contender. However, for these batteries to become industrially viable, certain properties such as energy and power density need to be enhanced. To address this issue, batteries have been a focus of research, and battery thermal management systems have been developed. These systems aim to evaluate battery performance, which is strongly influenced by temperature. Effective thermal management ensures that the battery operates within the optimal temperature range. This study models a pouch-type battery and evaluates the effects of phase changing materials (PCM) on battery temperature control. Comparative analysis is conducted using different PCMs to understand their impact. The study analyses the battery's response to specific temperature ranges and assesses how different PCMs affect battery cooling performance. The results provide critical insights for ensuring efficient battery operation. Furthermore, this research supports the broader adoption of Na-ion batteries in industrial applications and contributes to the development of sustainable energy storage systems.

Electron-Efficient Co-Electrosynthesis of Formates from CO2 and Methanol Feedstocks.

The electrochemical conversion of CO2 into valuable chemicals using renewable electricity shows significant promise for achieving carbon neutrality and providing alternative energy storage solutions. However, its practical application still faces significant challenges, including high energy consumption, poor selectivity, and limited stability. Here, we propose a hybrid acid/alkali electrolyzer that couples the acidic CO2 reduction reaction (CO2RR) at the cathode with alkaline methanol oxidation reaction (MOR) at the anode. This dual electro-synthesis cell is implemented by developing Bi nanosheets as cathode catalysts and oxide-decorated Cu2Se nanoflowers as anode catalysts, enabling high-efficiency electron utilization for formate production with over 180 % coulombic efficiency and more than 90 % selectivity for both CO2RR and MOR conversion. The hybrid acid/alkali CO2RR-MOR cell also demonstrates long-term stability exceeding 90 hours of continuous operation, delivers a formate partial current density of 130 mA cm-2 at a voltage of only 2.1 V, and significantly reduces electricity consumption compared to the traditional CO2 electrolysis system. This study illuminates an innovative electron-efficiency and energy-saving techniques for CO2 electrolysis, as well as the development of highly efficient electrocatalysts.

Hybrid Core-Shell TiCN@SiO2 Nanoparticles in Percolation-Based Polyvinylidene Fluoride Dielectrics for Improved High-Voltage Capacitive Energy Storage.

Solid-state polymer dielectrics offer an exceptional dielectric breakdown, but require an enhanced energy density to be competitive with alternative electrolyte-based energy storage technologies. Therefore, this research introduces conductive titanium carbonitride (TiCN) nanoparticles in a polyvinylidene fluoride (PVDF) matrix to obtain flexible percolation-based nanodielectrics by ultrasonication-based suspension processing and hot pressing. Well-dispersed TiCN nanoparticles in PVDF were obtained for a wide range of filler volume fractions, and an exceptional peak in the dielectric constant equal to 1130 (0.1 Hz) and 29 (10 kHz) was observed near the percolation threshold (9.2 vol %). The enhanced dielectric constant was ascribed to massive interfacial polarization occurring, resulting from Maxwell-Wagner-Sillars (MWS) polarization and a nanocapacitor mechanism that are dominant at low and high frequencies, respectively. An improvement by 30% in the energy density (0.042 Wh kg-1) compared with the neat PVDF matrix was achieved for the PVDF/TiCN nanodielectrics. The first successful uniform deposition of a nanometer-thin (3 nm) silica (SiO2) shell via the Stöber process on TiCN nanoparticles significantly suppressed the dielectric losses near percolation for the PVDF/TiCN@SiO2 nanodielectrics by more than 1 order of magnitude while offering dielectric constants of 34 (0.1 Hz) and 10 (10 kHz). This study demonstrates the potential of hybrid (core-shell) percolation-based dielectrics for an improved capacitive dielectric performance by an integrated dielectric characterization approach that simultaneously optimizes the dielectric constant, loss tangent, breakdown strength, and energy density.

ULPING-Based Titanium Oxide as a New Cathode Material for Zn-Ion Batteries

The need for alternative energy storage options beyond lithium-ion batteries is critical due to their high costs, resource scarcity, and environmental concerns. Zinc-ion batteries offer a promising solution, given zinc’s abundance, cost effectiveness, and safety, particularly its compatibility with non-flammable aqueous electrolytes. In this study, the potential of laser-ablation-based titanium oxide as a novel cathode material for zinc-ion batteries was investigated. The ultra-short laser pulses for in situ nanostructure generation (ULPING) technique was employed to generate nanostructured titanium oxide. This laser ablation process produced highly porous nanostructures, enhancing the electrochemical performance of the electrodes. Zinc and titanium oxide samples were evaluated using two-electrode and three-electrode setups, with cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and galvanostatic charge–discharge (GCD) techniques. Optimal cathode materials were identified in the Ti-5W (laser ablated twice) and Ti-10W (laser ablated ten times) samples, which demonstrated excellent charge capacity and energy density. The Ti-10W sample exhibited superior long-term performance due to its highly porous nanostructures, improving ion diffusion and electron transport. The potential of laser-ablated titanium oxide as a high-performance cathode material for zinc-ion batteries was highlighted, emphasizing the importance of further research to optimize laser parameters and enhance the stability and scalability of these electrodes.