Al Steel Research Articles

The Role of Al/Ti in Precipitate-Strengthened and Austenite-Toughened Co-Free Maraging Stainless Steel.

The strength of ultra-low carbon maraging stainless steels can be significantly enhanced by precipitating nanoscale intermetallic secondary phases. Retained or reversed austenite in the steel can improve its toughness, which is key to achieving an ideal combination of strength and toughness. Ti and Al are often used as cost-effective strengthening elements in maraging stainless steels but the synergistic toughening and strengthening mechanisms of Ti and Al have not been studied. To investigate the synergistic toughening and strengthening mechanisms of Ti and Al in Co-free maraging stainless steels, this paper focuses on the microstructure and mechanical properties of three alloys: Fe-12Cr-11Ni-1.7Al-0.5Ti (Steel A), Fe-12Cr-11Ni-0.5Ti (Steel B), and Fe-12Cr-11Ni-1.7Al (Steel C). The impact of Ti and Al on the microstructure and mechanical properties was investigated using X-ray diffraction (XRD), high-resolution transmission electron microscopy (TEM), and thermodynamic simulations. The relationship between microstructure, strength, and toughness is also discussed. The results indicated that Steel A, containing both Al and Ti, exhibited the highest strength level after solution treatment at 900 °C, with an ultimate tensile strength reaching 1571 MPa after aging at 540 °C. This is attributed to the simultaneous precipitation of spherical β-NiAl and rod-shaped η-Ni3Ti phases. Steel B, with only Ti, formed a significant amount of Ni-rich reversed austenite during aging, reducing its ultimate tensile strength to 1096 MPa. Steel C, with only Al, showed a high strength-toughness combination, which was achieved by forming dispersive nano-sized intermetallic precipitates of β-NiAl in the martensitic matrix with a slight amount of austenite. It is highlighted that Al has superior toughening and strengthening effects compared to Ti in the alloy system.

Evolution of nonmetallic inclusions in high Mn–high Al steel during heat treatment

In order to reveal the evolution behaviours of the inclusions in a high Mn–high Al steel ( w(Mn) = 18 wt% and w(Al) = 1.5 wt%) at 1200 °C, heat treatment experiments were carried out in laboratory for different hours (0–10 h). It was found that, CaO-Al2O3-MnO-MgO system oxides (Type I), CaO-Al2O3-MnO-MgO + (Ca, Mn)S complex oxysulphides (Type II) and (Ca, Mn)S sulphides (Type III, w(MnS) > 95 wt%) were detected before and after heat treatment. During heat treatment, the dominant inclusions changed from Type I (oxides) into Type II (oxysulphides), and the size of the inclusions increased slightly. With heating time, the Al2O3 content increased in the oxide part of Type I and Type II inclusions, while the content of CaO decreased. MnS was quite stable in the steel, and it can precipitate on the oxides, thus forming a (Ca, Mn)S transition layer in between the MnS outer layer and the oxides. The MnS outer layer might be helpful to reduce the stress concentration during rolling.

A novel method to establish friction coefficient model for numerical simulation of inertia friction welding

The precise friction coefficient at interface determines the friction behavior in inertia friction welding (IFW), its model is the basis to precisely describe the friction behavior in the numerical simulation of IFW. To measure the friction coefficient related to the temperature, pressure, and sliding velocity, the IFW trials between 2219-O Al alloy and 304 stainless steel were conducted with the simultaneous measurement of temperature and angular velocity evolutions. Two types of friction coefficient models were established by considering whether the effects of temperature and friction pressure were independent. The S-(T&P) L model, which considered the couple effect of temperature and friction pressure, was recommended as the best suitable model with its very high accuracy and best simplicity. The proposed model was successfully used in simulating the temperature evolution of IFW between Al alloy and steel tubes. The effect of the influencing variables on the friction coefficient was also discussed.

Effect of Interface Property on the Agglomeration Characteristic of Inclusions in High Al Steel with Different Al Contents

Herein, a 3D stability diagram is established in the AlON system. Based on that, four sets of experiments with different Al contents are designed to prepare different inclusions. Subsequently, the agglomeration behavior of inclusion is observed in situ by using confocal laser scanning microscopy (CLSM) combined with an infrared image furnace. The sample with inclusions is heated to melt and the agglomeration behavior of inclusion is recorded by the CRT monitor of CLSM. The calculated agglomeration force of inclusion shows that when the Al content increases from 0.5 to 3 pct, the agglomeration force of Al2O3 inclusions decreases from 7.2 × 10−16 ≈ 6.0 × 10−14 N to 1.2 × 10−16 ≈ 3.2 × 10−15 N. As the Al content increases from 6.5 to 10 pct, the agglomeration force of AlN inclusions increases from 2.2 × 10−17 ≈ 1.1 × 10−15 N to 1.7 × 10−16 ≈ 7.9 × 10−15 N. The theoretical calculation also shows that the agglomeration force of Al2O3 inclusions decreases and that of AlN inclusions increases with the increasing Al content. When the Al content is >4.7 pct, the agglomeration force of AlN inclusions is larger than that of Al2O3 inclusions.

Wettability and reactivity of liquid aluminium and highly deformed steel

The high-temperature liquid Al - solid S355J2N steel interaction was studied using a modified wettability test. A sessile drop method with a capillary purification procedure was employed for the first time, involving non-contact aluminium isothermal heating followed by the dropping of a pure liquid Al drop onto the severely deformed steel substrate and isothermal contact heating of Al with steel. The calculated contact angles and wetting kinetics curves demonstrated a good spreading and wetting of the investigated system. Scanning electron microscopy investigations played an important role in interpretation of the microstructural characteristics of the specimen, especially those located at the drop/substrate interface. The electron backscattered diffraction measurements allowed to characterize the microstructure of the interface zone to obtain more detailed information about the grain size, type of the intermetallic phases: θ-Al13Fe4, Fe2Al5, FCC Al and ferrite and their distribution in the neighborhood of the interface zone. These intermetallics were also confirmed via transmission electron microscopy studies coupled with energy-dispersive X-ray spectroscopy analysis of the drop/substrate interface. Research findings provide valuable insights into the liquid Al and steel interaction during the explosive welding process, where the local melting of metal takes place at the interface of colliding plates, strongly deformed due to the collision.

Laser Machining at High ∼PW/cm2 Intensity and High Throughput

Laser machining by ultra-short (sub-ps) pulses at high intensity offers high precision, high throughput in terms of area or volume per unit time, and flexibility to adapt processing protocols to different materials on the same workpiece. Here, we consider the challenge of optimization for high throughput: how to use the maximum available laser power and larger focal spots for larger ablation volumes by implementing a fast scan. This implies the use of high-intensity pulses approaching ∼PW/cm2 at the threshold where tunneling ionization starts to contribute to overall ionization. A custom laser micromachining setup was developed and built to enable high speed, large-area processing, and easy system reconfiguration for different tasks. The main components include the laser, stages, scanners, control system, and software. Machining of metals such as Cu, Al, or stainless steel and fused silica surfaces at high fluence and high exposure doses at high scan speeds up to 3 m/s were tested for the fluence scaling of ablation volume, which was found to be linear. The largest material removal rate was 10 mm3/min for Cu and 20 mm3/min for Al at the maximum power 80 W (25 J/cm2 per pulse). Modified surfaces are color-classified for their appearance, which is dependent on surface roughness and chemical modification. Such color-coding can be used as a feedback parameter for industrial process control.

Investigation of effects of aluminum additions on microstructural evolution and mechanical properties of ultra-high strength and vanadium bearing dual-phase steels

The effects of aluminum (Al) additions (0.04, 0.4, and 0.8 wt%) on the microstructural evolution, tensile properties, and sheared-edge ductility of dual phase (DP) steels were investigated. The DP steels were processed with distinct coiling temperatures after finish rolling, cold rolled, and subjected to two continuous galvanizing line (CGL) simulations: standard galvanizing (GI) and supercooling process (SC). Al expanded both the ɑ-ferrite and (ɑ+γ) phase fields at the expense of the γ-austenite region. Continuous cooling transformation (CCT) diagrams showed that Al increased ferrite start temperatures, broadened the ferrite transformation zone, and reduced austenite stability. Austenite growth kinetics during intercritical annealing, quantified using a modified Johnson-Mehl-Avrami-Kolmogorov (JMAK) model, revealed Avrami exponents ranging from 0.72 to 0.81 and apparent activation energies increasing from 422.9 to 496.7 kJ mol−1 with Al additions. Microstructural characterization revealed larger ferrite grain sizes and higher ferrite volume fractions with higher Al levels. Ultimate tensile strength (UTS) was influenced by Al contents, coiling temperatures, and CGL simulation methods. Global ductility (total elongation, TE) was highest for the 0.8Al Steel with a high coiling temperature and GI annealing, while local ductility (hole expansion ratio, HER) was maximized for the 0.04 Al Steel with a low coiling temperature and SC annealing. The majority of the CGL simulated DP steels exhibited good strength-ductility combinations, with the 0.8Al Steels demonstrating superior properties compared to current automotive advanced high-strength steel (AHSS) grades.

Effect of thermal fluctuations on mold coating delamination during continuous casting of high-alloy (Mn, Al) steel

During the continuous casting of high-alloy (Mn, Al) steels, mold coating delamination occurs specifically at the narrow face (NF) mold corner immediately below the meniscus, different from where mold surface problems are generally known to occur. Most mechanical analyses have been performed assuming negligible thermal fluctuations and steady state interfacial heat fluxes. However, high-alloy steels exhibit larger thermal fluctuations than general steels during continuous casting, attributable to the reaction between the high-alloy steels and mold flux. Therefore, in this study, thermo-mechanical analyses are performed under both steady and fluctuating interfacial heat fluxes to compare the effects of thermal fluctuations on the continuous casting mold, with the results indicating that monotonic stresses are generated under steady interfacial heat fluxes at the corner of the NF mold, whereas cyclic stresses are induced by thermal fluctuations under fluctuating interfacial heat fluxes. Accordingly, the cyclic stresses at the corner of the NF mold, induced by thermal fluctuations, are determined as the major cause of mold coating delamination. These results can be applied to develop methods to reduce mold coating delamination, prevent the degradation of strand quality, and improve mold life.

An in-situ investigation on the microstructure and viscosity characteristic of mold flux during slag-metal reaction process

The slag-metal reaction during the continuous casting of high Al steel changes the molten slag structure from silicon-oxygen to silicon-oxygen-aluminum network structure, greatly affecting the viscosity properties of mold flux. In order to reveal the internal mechanism of the viscosity change during slag-metal reaction, the molecular dynamics simulation was employed to monitor the microstructure evolution characteristics of molten slag under different Al2O3/SiO2. The results showed that Q3Al decrease from 25.48% to 22.26%, Q4Al and Q5Al increase from 68.82% and 1.70% to 71.26% and 2.88%, respectively with an increase of Al2O3/SiO2 from 0.1 to 1.2. The [AlO4]5- tetrahedral structure changed from low coordination to high coordination structure, the degree of polymerization increased, and the viscosity increased. The viscosity calculated by molecular dynamics is in good agreement with the experimental measurement. Finally, A dynamic link model between structural transformation and viscosity was innovatively established.

Extrinsic-Riveting Friction Stir Lap Welding of Al/Steel Dissimilar Materials.

To obtain high-quality joints of Al/steel dissimilar materials, a new extrinsic-riveting friction stir lap welding (ERFSLW) method was proposed combining the synthesis advantages of mechanical riveting and metallurgical bonding. SiC-reinforced Al matrix composite bars were placed in the prefabricated holes in Al sheets and steel sheets, arranged in a zigzag array. The bars were stirred and mixed with Al sheets under severe plastic deformation (SPD), forming composite rivets to strengthen the mechanical joining. SiC particles were uniformly dispersed in the lower part of the welding nugget zone (WNZ). The smooth transition between the SiC mixed zone and extrinsic-riveting zone (ERZ) ensured the metallurgical bonding. The maximum tensile shear load of the joints reached 7.8 kN and the maximum load of the weld per unit length was 497 N/mm. The fracture occurred at the interface between the rivets and steel sheets rather than the conventional Al/steel joining interface. Moreover, ERFSLW can prolong the service life of joints due to three fracture stages. This method can be further extended to the welding of other dissimilar materials that conform to the model of "soft/hard".

Microstructure Evolution and Mechanical Properties of Laser Welded Dissimilar/Similar Joints Between Medium‐Mn Transformation‐Induced Plasticity Steel and DP980/22MnB5 Steels

In this article, the microstructure and mechanical properties of the Fe–0.31C–6.86Mn–3.53Al steel and DP980 and 22MnB5 steel dissimilar/similar joints by fiber laser welding are studied. Based on experimental results, fusion zone (FZ) of transformation‐induced plasticity (TRIP)‐welded joint mainly consists of 77 vol% martensite and 23 vol% ferrite. The FZ of TRIP‐DP980 and TRIP‐22MnB5 welds mainly consist of martensite. The hardness profile of weld cross‐section exhibits significant asymmetry, and softening zones hardness of TRIP‐DP980 and TRIP‐22MnB5 accounts for 82% and 64% of DP980 and 22MnB5 base materials (BM), respectively. However, no softening zone is observed on TRIP steel side, primarily due to the lack of martensite in TRIP BM. The tensile results showed that welding efficiency of TRIP‐TRIP reached 99%, but elongation of welded specimen is only 50% of TRIP BM due to the high hardness and brittleness of FZ region. TRIP‐DP980 and TRIP‐22MnB5 joints did not fail in softening zone, because the constraint stress is generated on both sides of softening zone to inhibit the plastic deformation in softening zone during tensile process. The tensile stress is distributed on the surface of tensile specimens and concentrated in BM on the side with low yield strength (YS), resulting in the final fracture.

Effect of Al on the low cycle fatigue deformation behavior and microstructure evolution of Fe–22Mn-0.6C TWIP steel

The dependence of low cycle fatigue (LCF) behavior and microstructure evolution of Fe–22Mn-0.6C twinning-induced plasticity (TWIP) steel on the alloying element Al has been investigated under fully reversed total strain amplitude control with a nominal strain rate of 0.006 s−1 and strain amplitudes ranging from 0.002 to 0.010 at room temperature. The results indicate a strong dependence of LCF response and evolved microstructure on the addition of Al, owing to its effect on the stacking fault energy (SFE). At all strain amplitudes, the 3Al steel with a higher SFE exhibits a visibly lower cyclic hardening and a higher cyclic softening, resulting in a lower cyclic yield strength than the 0Al steel. As compared with the 0Al steel, the relatively higher SFE of the 3Al steel causes higher accumulated plastic strain, decreased slip planarity and weaker reversibility of dislocations, thereby decreasing the fatigue life. The optical microstructure is featured by increase in slip band density with increasing strain amplitude for both steels. However, the slip band density of the 3Al steel is higher than that of the 0Al steel. Moreover, cyclic loading promotes the formation of dislocation cells, rough labyrinths as well as planar dislocation arrays. Deformation twins are observed only in the 0Al steel with a visible lower critical twinning stress due to its low SFE as compared to the 3Al steel.

Electrocoagulation using Ti/Ti for the remediation and reuse of aqueous Dispersive Blue-79.

The entire ecology is contaminated by the synthetic dyes that are widely utilised in the textile industries. They can be handled using a variety of technologies, but an eco-friendly method called electrocoagulation has been used to prevent additional contamination. Textile wastewater containing disperse dyes are successfully treated in Electrocoagulation (EC) utilizing Al, Fe, and Stainless Steel (SS), but it is not cost effective, also the treated water contains certain mg/L of the metals used, along with dye components, which obstructs the reuse of the same. The effects of initial pH, applied voltage, dye concentration, supporting electrolyte, and treatment time on the colour removal efficiency (CRE) and consumption of energy were examined in EC process followed by activated charcoal filtration (hybrid process) with a monopolar Ti/Ti electrode on the remediation of aqueous solution of Dispersive Blue-79 (dye 3G). The maximum CREobtained was 99.4%, chemical oxygen demand (COD) 93%, and biological oxygen demand (BOD) 85%, under the following optimized operating conditions, applied voltage 15V, pH = 7, concentration of dye, electrolyte 110mg/L, 0.2g/L and time = 15min. The overall operating cost for the treatment of aqueous dye 3G was 0.455US/m3. The mechanism of EC was studied using XPS analysis in the sludge obtained. For the purpose of the reuse, FTIR, AAS, and ICP-OES analysis were done and compared with the aqueous dye 3G, after EC and hybrid process to ensure the maximum removal of the degraded dye components and metal. ICP-OES results showed that there were no traces of metal in the treated aqueous dye 3G using this method. Throughout the study, the experimental outcomes indicated that the hybrid process upgraded the quality of the treated aqueous dye 3G.

New insights into the effect of Al on the selective oxidation of advanced high-strength steels prior to hot-dip galvanizing

Advanced high-strength steels (AHSSs) enable the manufacture of lighter, safer and more energy-saving body-in-white. However, the poor galvanizability induced by the surface selective oxidation during annealing makes the production of high-grade galvanized AHSS quite challenging. It is generally believed that replacing Si with Al enhances the galvanizability of AHSS, but a recent industrial practice shows the opposite for a high Al steel grade, which indicates complex competing mechanisms introduced by Al. Here, we study the selective oxidation of a model system Fe-Mn-Si-Al systematically by varying the Al content and dew point of annealing atmosphere. We suggest that Al has a dual-side effect on the galvanizability of AHSS via: i) promoting the outward diffusion and subsequent external oxidation of Mn and Si, ii) deteriorating the surface chemistry of galvanizing by enhancing the Si/Mn ratio of surface oxides, iii) facilitating the formation of amorphous film-like external oxides, and iv) a comparatively low trend for Al to segregate to the surface, where the first three function negatively while the last positively. Our work would change the perspective away from a focus solely on the deceleration effect of Al to also consider its acceleration on the surface selective oxidation, insights critical for developing strategies against galvanizing problems of AHSSs.

Sound dissimilar linear friction welding of A7075-T6 Al and mild steel by simultaneous interfacial deformation using higher forging speed

Sound dissimilar welding of heat-treatable A7075-T6 aluminum and mild steel is extremely difficult due to the formation of interfacial cracks. The present study aims to attempt linear friction welding (LFW) of high-strength A7075-T6 Al alloy and mild steel to obtain sound joints with the highest strength ever by controlling the quality deteriorating phenomena that previous studies have faced. In this study, LFW joints were fabricated under two different applied pressures of 100 MPa and 300 MPa at a forging speed of 5 mm/s, along with various forging speeds ranging from 5 mm/s, 10 mm/s, to 20 mm/s under an applied pressure of 300 MPa, and the joint microstructure, mechanical properties and interface macrostructure were investigated. Furthermore, thermal dependence behaviors of both alloys were systematically investigated to optimize the processing parameters, especially applied pressure during LFW. At lower forging speeds of 5 mm/s and 10 mm/s, the weld defects and un-bonded regions were observed near the center of the weld accompanied by unevenness of butt surface due to the relatively thick intermetallic compound (IMC) formed in the interface which greatly influenced the joint strength. In contrast, at the higher forging speed of 20 mm/s, weld defects at the joint interface were effectively suppressed by promoting the simultaneous and uniform interfacial deformation of both alloys thanks to the extremely thin IMC during LFW. Consequently, a highly efficient joint with 100 % efficiency was successfully obtained at higher forging speed of 20 mm/s and despite the occurrence of softening towards A7075, the fabricated joint displayed a base metal fracture towards the steel side.

Effect of Ni interlayer on interfacial microstructure and fatigue behavior of friction stir lap welded 6061 aluminum alloy and QP1180 steel

In this work, the interfacial microstructure and fatigue properties of friction stir lap welding (FSLW) joint of 6061 aluminum (Al) alloy and QP1180 steel with a Ni interlayer were characterized, and the effects of Ni on the intermetallic compounds (IMCs) evolution and fatigue behavior were revealed. The results show that an Al-Ni transition layer with a thickness of ∼ 200 nm appears at the interface of Al-Ni-Fe joint. No Al-Fe IMC is formed in the joint, because the Ni interlayer effectively blocks the reaction between Al alloy and steel. The fatigue strength of Al-Ni-Fe joint is 50 % higher than that of Al-Fe joint. The failure modes of Al-Fe joints are affected by the load levels. The joint breaks at the interface at high load levels, while the joint tends to break along the thickness direction of Al plate at low load levels. After adding Ni interlayer, the joint breaks along the thickness direction of Al plate at both high and low load levels. Based on the theoretical calculation, all Al-Fe IMCs exhibit brittleness, and most of Al-Ni IMCs exhibit toughness. Hence, Al-Ni phases effectively prevent crack propagation by enhancing the interface bonding strength of Al alloy and steel, and improve the fatigue strength of joint.

Comparative Study of Quench and Partition Processes in High Si and High Al Steels

The quench and partition process is a means to develop third-generation high-strength steels using many possible process variants. In this work, two variants of quench and partitioning heat treatments, one-step and two-step, were carried out for high Si and high Al steel alloys. The kinetics of isothermal transformation occurring during the one-step quench and partition process were analysed using dilatometry. Experimental analysis revealed the swing-back phenomenon in high Si steel, and the transformation characteristics above and below the Ms temperature differed. The high Al alloy resulted in higher retained austenite (19%) compared to high Si steel (17%) during the one-step quench and partition process. Aluminium addition favoured bainite formation more than silicon addition. A comparison of two heat treatment variants shows the two-step quench and partition heat treatment seemed preferable as it produced more retained austenite (22%) in the high Si steel.

Modeling the Precipitation of Aluminum Nitride Inclusions during Solidification of High‐Aluminum Steels

High‐aluminum advanced high‐strength steels have received increasing interest due to their excellent combination of strength and ductility. The control of nonmetallic inclusions in steel is among the most important issue for the production of high‐aluminum steel. This study proposes a model for the evolution of size distributions of AlN inclusions during solidification of steel based on the Kampmann–Wagner numerical model and microsegregation calculation. Both homogeneous (pure AlN) and heterogeneous precipitations (AlN+oxide or MnS) are described using homogeneous nucleation and free growth models of Greer et al. respectively. The model is applied to calculate the size distributions of AlN in high‐Al (up to 5%) Fe–Cr–Al steels and high‐ and medium‐manganese steels and validated by the experimental data in the literature. The model correctly describes the influence of cooling rates on the precipitation of AlN in Fe–Cr–Al steels and high‐manganese steels, and the sizes of AlN are reduced and the number densities of AlN inclusions are increased by increasing the cooling rate. The effects of nitrogen and aluminum concentration in medium‐manganese steel on inclusion precipitation are investigated by the model calculation. The increases in nitrogen and aluminum concentration facilitate the homogeneous precipitation of AlN inclusions.

Effect of different friction coefficient models on numerical simulation of inertia friction welding of 2219 Al alloy to 304 stainless steel

In inertia friction welding (IFW) of Al alloy to steel, the friction coefficient of interface influences the friction heat production and determines the accuracy of the numerical simulation of welding process. A fully coupled three-dimensional model was established to simulate the IFW process of 2219 Al alloy to 304 stainless steel. By taking different simplifications in the influencing factors (i.e., temperature, sliding velocity, and pressure) of friction coefficient, three types of friction coefficient models were established and utilized in the simulation of IFW process. The strain compensated Arrhenius and Johnson-Cook models were employed to describe the deformation behavior of Al alloy and steel, respectively. Both Al alloy and steel were assumed to be the elastic-plastic body, and the friction stress was calculated by the Coulomb friction model. The friction interface temperature, angular velocity attenuation, axial shortening distance, and joint appearance were measured to verify and compare the accuracy of the established models. The temperature and stress evolutions during the IFW process were also analyzed. With the smallest error in validation, the friction coefficient model, which was a function of temperature, sliding rate, and pressure, showed the best accuracy in describing the friction behavior. By considering the effect of pressure, a more accurate shear stress at the center region of the interface was calculated with a lower value. It means that the friction resistance at the region was lower, promoting the flow of internal Al alloy and the formation of curly-shape flash.

Influence of banded ε-martensite and deformation twin on cryogenic toughness of Fe–Mn–xAl–C steel

Fe–Mn–xAl–C steel ingots have been fabricated by vacuum melting with Al compositions varied from x = 0 to 3 and 5 wt.%, respectively. After properly hot-forging and hot-rolling as well as solution heat treatments, impact toughness tests were carried out at 77 K using a standard full-size of Charpy impact V-notch configuration. It was found that the addition of Al element is more conducive to enhance the cryogenic toughness. The relationship between the cryogenic toughness and the Al composition has been revealed through detailed microstructural studies by electron back scatter diffraction and transmission-electron microscopy. The stack fault energy (SFE) increases with the increase of Al content at various temperature. The plastic deformation is dominated by deformation bands which are dominated by deformation twins (DTs) and ε-martensite at x = 0 and DTs at x = 3 and 5%, respectively. The DTs near fracture the notch-tip area increased in the order of the 0Al, 3Al, and 5Al steel. The DTs with high density, together with their contented dislocations, significantly contributed to the high cryogenic toughness of the studied high manganese steel with higher Al content. Banded ε-martensite will deterioration cryogenic toughness due to its large size compared to DTs at 0Al steel.