Acrylonitrile Butadiene Styrene Research Articles

Environmental Durability of Bio-Based and Synthetic Thermoplastic Composites in Large-Format Additive Manufacturing.

This research investigates the durability of large-format 3D-printed thermoplastic composite material systems under environmental exposure conditions of moisture and freeze-thaw. Durability was evaluated for two bio-based composite material systems, namely wood-fiber-reinforced semi-crystalline polylactic acid (WF/PLA) and wood-fiber-reinforced amorphous polylactic acid (WF/aPLA), and one conventionally used synthetic material system, namely short-carbon-fiber-reinforced acrylonitrile butadiene styrene (CF/ABS). The moisture absorption, coefficient of moisture expansion, and reduction of relevant mechanical properties-flexural strength and flexural modulus-after accelerated exposure were experimentally characterized. The results showed that the large-format 3D-printed parts made from bio-based thermoplastic polymer composites, compared to conventional polymer composites, were more susceptible to moisture and freeze-thaw exposure, with higher moisture absorption and greater reductions in mechanical properties.

Structural and nonlinear J-integral fracture toughness for nanoclay toughened ternary HDPE/LDPE-g-MA/ABS blend nanocomposites

High-density polyethylene (HDPE) has a higher strength-to-density ratio and stiffness but a low branching degree for the packed linear chains that restrict the ability to bond and resist cracking. This study conducts the role of inserting rigid nanoclay (NC) and soft acrylonitrile butadiene styrene (ABS) on the structural, nonlinear fracture toughness and crack resistance of a ternary HDPE/low-density polyethylene-grafted maleic anhydrite (LDPE-g-MA)/ABS blend. Varying additions of 1, 3, 5, and 7 % NC and 5, 10, 15 wt. % ABS were inserted into neat HDPE and HDPE90/LDPE-g-MA10. All materials were hand-mixed before feeding into a single screw extruder and directly melt-blended twice to achieve a good dispersion of nanofiller in the matrix. The structural characteristics and the fracture surfaces of NC/HDPE/LDPE-g-MA and NC/HDPE/LDPE-g-MA/ABS were investigated by TEM, XRD, SEM, and FTIR spectra. Tensile strength and the critical dissipated energy (JIc) determined by quasi-static J-integral fracture mechanic revealed a higher absorbing fracture energy of 75 KJ/m2 for the binary and 85 KJ/m2 for the ternary nanocomposites. The synergistic percolated role of the NC particles and ABS copolymer in front of the crack tip region hinders crack growth for the presence of micro-void coalescence and massive shear-yielding toughening mechanisms.

Optimization of Parameters for Fluidized Bed-Type Tribo-Electrostatic Separation of End-of-Life Vehicle Waste Polymer Particles by Response Surface Methodology

End-of-life vehicles (ELVs) have resulted in huge quantities of waste vehicle polymers, the reuse of which could be effective in mitigating pollution and creating economic value. Based on the developed fluidized bed-type electrostatic separation equipment, this paper investigated the separation of two groups of commonly used mixed vehicle-use polymer particles, namely, acrylonitrile-butadiene-styrene (ABS)-polyamide (PA)-polypropylene (PP) (black) and polyethylene (PE)-PP (white)-polyvinyl chloride (PVC). First, the force of the particle in an electric field was analyzed, and the kinetic model of the particle in a high-voltage electrostatic field was established. Then, individual factor experiments were conducted on the fluidization time (T), the first-stage electrostatic separation chamber electrode voltage (U 1), the second-stage electrostatic separation chamber right field electrode voltage (U 3) and the second-stage electrostatic separation chamber left field electrode voltage (U 5) to investigate the pattern of separation results affected by each of these factors, individually. Finally, based on response surface methodology (RSM) experiments, the effects of the abovementioned three factors and their interactions on the purity of the separation of the three types of particles in each group were analyzed. The optimum separation parameters for ABS-PA-PP (black) particles in the experiments were determined as follows: T of 385 s, U 1(U 3) of −32 kV and U 5 of −37 kV. The optimum separation parameters for PE-PP (white)-PVC particles were found as follows: T of 398 s, U 1(U 3) of −40 kV and U 5 of −38 kV. The experimental validation of the abovementioned parameters obtained the purities of the three set of ABS-PA-PP (black) types of particles being 95.67%, 91.34% and 99.12%, respectively. The purities of the three set of PE-PP (white)-PVC types of particles being 96.21%, 93.20% and 86.74%.

Pyr-GC-Orbitrap-MS method for the target/untargeted analysis of microplastics in air

Pyrolysis-gas chromatography coupled to Orbitrap-mass spectrometry is a novel technique that allows the low level and precise determination of microplastics in environmental samples. In this paper, we develop and assess the target and untargeted performance of Pyr-GC-Orbitrap-MS. The method was optimized for 10 plastic polymers: polymethyl methacrylate, nylon-6,6, polypropylene, nitrile butadiene rubber, polyvinyl chloride, polyethylene terephthalate, acrylonitrile butadiene styrene, polyethylene, polycarbonate, and polystyrene. Standards were home-made using a diamond driller to attain mean sizes within the range of 45–382 µm. A step-by-step optimization of the analytical procedure was carried out. First, accurate mass measurement of each polymer at 60,000 resolution was studied to select the 3 most intense and selective quantification and confirmation ions. Second, internal standard quantification was optimized, and good linearity, repeatability, and reproducibility were obtained. Blank contribution and instrumental detection limit were evaluated for each polymer. Finally, the combined and expanded uncertainty of the Pyr-GC-Orbitrap-MS method was calculated to determine the sources of variation, considering that home-made standards were used. To evaluate method performance, targeted and non-targeted analysis of indoor air samples collected from gyms and department stores were carried out. The Pyr-GC-Orbitrap-MS methodology herein described can be applied for the quantitative assessment of MPs and other substances in different matrices.

Impact of recyclability on the mechanical properties of coated plastic materials for the automotive and electronic sectors

This research focuses on the study of the mechanical properties (tensile and impact strength) of Acrylonitrile-Butadiene-Styrene (ABS) and its blends with Polycarbonate (ABS/PC) including recycled and painted material. A comprehensive assessment was done to determine the impact of reprocessing cycles, remaining coating and their combined effect in the final properties of the recycled polymer. Post-consumer materials are in an already-aged state, lowering their initial properties. Mechanical recycling methods showed that the reprocessing cycles have a higher impact on the mechanical performance than the amount of recycling material content. Also, the material is often coated when they are about to be recycled. The remaining coating impurities play a major role in the recycling process, losing up to 42% of the impact strength for ABS and 28% for ABS/PC. It was demonstrated that below a 10% of remaining paint, both materials retained is performance as a neat product. Impurities was declared to be the most pernicious element on the recycling process and their elimination must be a priority regarding this objective. These results provide a better knowledge of the recycling effect and can be used to decide the potential recyclability of plastic. The ascribed project of this study (DECOAT) aims to develop efficient systems to remove coatings at the end-of-life of the part, to reduce the damage and promote the use of recycled material in high-tech applications.

A machine learning approach to characterise fabrication porosity effects on the mechanical properties of additively manufactured thermoplastic composites

The investigation of the mechanical properties of additively manufactured (AM) composite has been the focus of several research over the past decades. However, testing constraints of time and cost have encouraged the exploration of more pragmatic methods such as machine learning (ML) for predicting these characteristics. This study builds on experimental investigations of the flexural, tensile, compressive, porosity, and hardness properties of 3D printed carbon fibre-reinforced polyamide (CF-PA) and carbon fibre-reinforced acrylonitrile butadiene styrene (CF-ABS) composites, proposing the application of ML for predicting these mechanical properties. A comprehensive comparative analysis of various machine learning approaches was executed, with a resultant accuracy ranging between 80 and 99%. The results unveiled the superior predictive performance of ensemble tree learners and the K-NN regressor algorithms when temperature and porosity are selected (based on correlation analysis) as predictors for material hardness and strength in tension, compression, and flexion. In particular, the model built on the extra-tree regressor algorithm demonstrated a remarkably robust fit, with R-squared evaluation scores of 0.9993 and 0.9996 for CF-PA and CF-ABS, respectively. This work develops a ML model that relates porosity to the other mechanical properties of AM composites and the prediction models’ exceptional accuracy, along with their precise alignment with experimental data, provide invaluable insights for the autonomous control and data-driven optimization of the structures.

Pengaruh Proses Annealing Terhadap Akurasi Dimensi Dan Kuat Tarik 3D Printing Menggunakan Filamen ST-PLA

3D printing is a tool used to make objects / test specimens in 3 dimensions, using the main material made from polymer. In 3D printers there are two types of filaments that are often used today, namely Polylactic acid or polylactide (PLA) material and Acrylonitrile butadiene styrene (ABS), the material used in this study is PLA material, this material was chosen because it has several advantages. Poly(lactic acid) (PLA) biodegradable thermoplastics have been used in various industrial fields including automotive, computer, food, and electrical equipment also used in medical devices, PLA is a biodegradable thermoplastic sourced from natural starches such as corn and sugarcane. Therefore, this study aims to find the highest tensile strength in PLA materials using several levels of testing, The highest tensile test result at one parameter level will be carried out by the annealing process to determine the effect of the annealing process on the tensile test specimen. The research method used in this study is the Taguchi method designed L9 with 3 factors and 3 levels, using the Analysis of Variance (ANOVA) analysis method. The test results showed that the highest tensile strength was located in study number 5, which was 44.866 Mpa, and the lowest average tensile test value was in study number 4, which was 40.033 Mpa.

Reducing the Environmental Impacts of Plastic Cosmetic Packaging: A Multi-Attribute Life Cycle Assessment

The global packaging industry has been growing significantly, resulting in an increase in waste and emissions. Social responsibilities, regulations and targets are shifting companies’ priorities to various sustainable practices. This study comprised a life cycle assessment (LCA) to quantify and compare key initiatives influencing the sustainability of plastic cosmetic packaging. The life cycle environmental effects of dematerialisation, recycled content, energy-saving initiatives and renewable energy powering the manufacturing processes, and the end-of-life (EoL) recycling rates of various scenarios, were evaluated. Moreover, a variety of fossil-based and bio-based polymers, such as acrylonitrile butadiene styrene (ABS), polypropylene (PP), polyethylene terephthalate (PET), wood–polymer composite (WPC) and polylactic acid (PLA), were considered. The study determined that dematerialisation and recycled content had the most beneficial impacts on packaging sustainability. When 100% recycled materials were used, an overall impact reduction of 42–60% was noted for all the materials considered. Using 100% renewable energy and applying measures to reduce the energy consumption in the manufacturing stage by 50% reduced the total impact by approximately 9–17% and 7–13%, respectively. Furthermore, it was concluded that PP had the lowest environmental impacts in the majority of the case scenarios considered, by an average of 46%.

Evaluation on Material Anisotropy of Acrylonitrile Butadiene Styrene Printed via Fused Deposition Modelling

Thermoplastic polymers are widely used in industry to generate parts with reasonable production costs, lightweight, chemical stability, sustainability, and recyclability compared to other materials such as metals, metalloids, or even thermoset polymers. The innovative additive manufacturing (AM) techniques, e.g., fused deposition modelling (FDM), can be used to fabricate thermoplastic products with complex geometries and specific properties. However, the mechanical integrity of those FDM-printed plastic parts can be greatly impacted by a phenomenon named material anisotropy. In this study, an experimental study on a popular 3D printing polymer material—acrylonitrile butadiene styrene (ABS)—is performed to determine how FDM process parameters affect the mechanical properties of the printed ABS parts. This study uniquely concentrates on investigating mechanical anisotropy in FDM-printed ABS, delving into a combination of key printing parameters for a comprehensive exploration. Meanwhile, a finite-element-based numerical analysis is also utilised to numerically evaluate the influences of infill percentage and build orientations on the mechanical properties of the 3D-printed ABS materials for comparison. It generates a better understanding of material anisotropy and helps to find the optimal FDM process parameters to print high-quality ABS parts and may attract industrial interests in transitioning from traditional ABS part production methods such as injection moulding or hot pressing to additive manufacturing.

Investigation of the structure-property relation for graphene oxide based acrylonitrile butadiene styrene nanocomposites

The improvement of the structure-property relation in nanocomposites between different polymer matrices and the embedded nano-additives has become a strategic blueprint for many academic counterparts around the globe. In this work, different loadings of graphene oxide (GO) varied from 1.0 to 3.0 wt. % were mixed with acrylonitrile butadiene styrene (ABS) using solution casting approach. The resulted nanocomposites underwent to spectral, structural, morphological, mechanical, thermal and thermomechanical tests. Different kinds of instruments associated with each test were employed to draw a professional conclusion about the potential improvement in structure-property relation. The targeted improvement was achieved as spectral, structural and morphological investigations confirmed the interaction, structural variation, and good dispersion of GO in ABS; respectively. Furthermore, as GO loadings went higher, the mechanical, thermal, and thermomechanical performances for the nanocomposites were improved compared to the neat polymer. Young’s modulus, tensile strength, thermal decomposition, and visco-elastic properties showed an enhancement compared to the neat polymer. The mechanical and thermomechanical performances for the nanocomposites recorded significant promotions.

3D-Printed Polymer Spare Parts for Various Applications

3D-printed polymer component parts and spare parts are now being widely used in various applications. In this paper, the 3D printing technologies and materials for spare part production in several applications are presented. Some opportunities and challenges faced when using 3d-printed spare parts are also discussed. The acrylonitrile butadiene styrene (ABS) has mostly been used. And it was found out that the durability of the spare parts could vary depending on the application.

Design, Multiperspective Investigations, and Performance Analysis of Multirotor Unmanned Aerial Vehicle for Precision Farming

Farming and agriculture are the oldest professions, but they are adapting to the technology revolution to accommodate the world’s growing population. UAV technology is part of the agriculture revolution, which aims to boost crop yields, properly monitor fields, and handle manpower shortages and resource efficiency. Rural India’s tiny farmers cannot afford UAV technology; therefore, it has not yet spread. Payload capacity, endurance, and selective spraying are other considerations. Thus, a low-cost, long-lasting UAV is necessary. This study modified the arm assembly to create a cheap hexacopter UAV. The endurance increased by 10% when 1.5 kg was lost. ABS plastic was used to make the modular arm. For working loads of 9 kg and 10 kg, pesticide/fertilizer spraying saves time, money, and manpower. Thus, a pressure-area coverage-cone angle connection is needed. This study examined spray patterns at different pressures and heights by varying flat fan nozzle and complete cone nozzle orifice diameters. These factors were linked, helping farmers choose the right nozzle. This nozzle was installed in the UAV and field-tested for paddy crops, showing a significant production improvement and lower operational cost. Chemical use pollutes and leaves traces in produce. Precision farming with artificial intelligence (AI) has solved this problem. In this experiment, AI algorithms were used to lemon leaves. Three AI systems were tested on different datasets to forecast plant stress by analyzing leaves due to technical constraints. CNN’s accuracy and computing speed make it ideal for precision farming. This work’s UAV was 30% cheaper than commercial UAVs and had more durability. Farmers will also benefit from the flat fan and complete cone nozzles’ pressure-area coverage connection.

Characterizing ABS–copper chemistry-dependent adhesion: From the atomic to macro level

The electroplating of copper layers on acrylonitrile–butadiene–styrene (ABS) polymer surfaces is a common need in industrial applications. The development of new eco-friendly techniques to promote ABS–copper adhesion is crucial due to the harsh and expensive chemicals used in the existing processes. The initial path involves establishing a better understanding on chemistry-dependent ABS–copper adhesion mechanisms. By formulating the material with more functional groups, the adhesion between ABS and the coated copper layer was characterized through a multiscale approach. At the atomic scale, we performed ab initio density functional theory simulations to obtain the variations in the adsorption energy. At the nano and micro scales, we adopted atomic force microscopy to measure the adhesion forces on the bulk polymer surfaces. At the macro scale, we compared these adhesion results with both 90-degree peeling tests and finite element model analyses. This study presents the first comprehensive approach for bridging information gaps across the scales (from nano to macro) with computational and experimental data, facilitating the design of formulated ABS additives.

Acoustic properties of ABS and PLA parts produced by additive manufacturing using different printing parameters

Abstract This study investigates the effect of printing parameters on the acoustic performance of specimens produced using 3D printing technology. The specimens were fabricated with square and hexagonal cell shapes with 10, 20, 30, and 50 % infill ratios from acrylonitrile butadiene styrene (ABS) and polylactic acid (PLA) materials. The sound absorption coefficient and sound transmission loss results of the samples were measured with an impedance tube at 1/3 octave band values in the range of 500–6400 Hz. The highest sound absorption coefficient results were determined for cylindrical samples with a square internal structure made of ABS material with a 50 % infill ratio in the frequency range of 2500–3500 Hz. The sound transmission loss values of the samples vary between approximately 13 and 58 dB at 1/3 octave band values in the range of 500 and 6300 Hz. The highest sound transmission loss values were determined in the sample produced of PLA with a square cell shape at a 30 % infill ratio. It was concluded that different geometric shapes, materials, and infill ratios affect the acoustic performance of parts produced by 3D printing technology.

Dual material fused filament fabrication of composite core‐shell structures with improved impact resistance and interfacial adhesion

AbstractThe mechanical performance of parts produced by fused filament fabrication (FFF) has been limited due to the presence of voids and poor interlayer welding. Recent advancements in FFF have enabled the fabrication of void‐free objects with strong interlayer welding through the use of semicrystalline polymer shells such as high‐density polyethylene (HDPE) along with a high viscosity core polymer like acrylonitrile‐butadiene‐styrene (ABS). The zero‐shear viscosity (η0) of ABS is three orders of magnitude higher than HDPE making the ABS‐HDPE core‐shell configuration preferable. ABS holds the shape by preventing bulk flow and part bending while HDPE promotes full surface contact across the layers. Most polymers, however, are immiscible which causes a weak weld line along the core‐shell interface. Herein, maleic anhydride (MAH) is grafted to the butadiene segment of the ABS core thereby compatibilizing the interface with HDPE, improving the interfacial adhesion. Attenuated total reflectance‐Fourier transform infrared spectroscopy was employed to confirm successful grafting. Using a custom‐made die affording the core‐shell structure, the ABS‐g‐MAH is shown to improve the impact resistance by 253% and 16% compared to neat HDPE and ABS specimens, respectively. Additionally, a 10% increase compared to the unmodified ABS‐HDPE core‐shell configuration is observed.

Evaluating and Comparing Flexure Strength of Dental Models Printed Using Fused Deposition Modelling, Digital Light Processing, and Stereolithography Apparatus Printers.

The introduction of three-dimensional (3D) printing in dentistry has mainly focused on applications such as surgical planning, computer-guided templates, and digital impression conversions. Additive manufacturing (AM), also known as 3D printing, involves layering resin material sequentially to construct objectsand is gaining recognition for its role in creating custom-made medical appliances. The field of orthodontics has also embraced this technological waveand with the advent of cost-effective printers and biocompatible resins, 3D printing has become increasingly feasible and popular in orthodontic clinics. The limitations of traditional plaster models may have prompted the emergence of 3D-printed models, but it led to enhancing treatment planning and device fabrication, particularly in orthodontics. Notable desktop printing technologies include fused deposition modelling (FDM), digital light processing (DLP), and stereolithography (SLA), each employing distinct methods and materials for fabricating appliances. Evaluating mechanical properties, like flexure strength, is crucial to determine the material's ability to withstand bending forces and thus prove useful in fabricating thermoformable appliances, surgical templates, etc. This study aims to assess the flexure strength of 3D-printed models using FDM, DLP, and SLA technology, providing insights into their suitability as replacements for conventional models and shedding some light on the durability and sustainability of 3D-printed models. Cuboids measuring 20 x 5 x 2 mm were cut from models, creating 10 samples per printer group. These samples underwent flexure strength testing using a three-point bending system in a universal testing machine. The FDM group exhibited the highest flexure strength at 69.36 ± 6.03 MPa, while the DLP group showed the lowest flexure strength at 67.47 ± 20.58 MPa. The results can be attributed to the differences in resin materials used for fabrication, with FDM using acrylonitrile butadiene styrene (ABS) polymer and SLA/DLP using polymethyl methacrylate (PMMA), and also to the variation in their printing mechanism. The findings affirm the suitability of FDM models for orthodontic applications, suggesting enhanced efficiency and reliability in clinical practices.

In-situ background-free Raman probe using double-cladding anti-resonant hollow-core fibers.

This study presents the development of an in-situ background-free Raman fiber probe, employing two customized double-cladding anti-resonant hollow-core fibers (AR-HCFs). The Raman background noise measured in the AR-HCF probe is lower than that of a conventional multi-mode silica fiber by two orders of magnitude. A plug-in device for fiber coupling optics was designed that was compatible with a commercially available confocal Raman microscope, enabling in-situ Raman detection. The numerical aperture (NA) of both AR-HCF claddings exceeds 0.2 substantially enhancing the collection efficiency of Raman signals at the distal end of the fiber probe. The performance of our Raman fiber probe is demonstrated by characterizing samples of acrylonitrile-butadiene-styrene (ABS) plastics, alumina ceramics, and ethylene glycol solution.

Enhancing the Strength of Acrylonitrile–Butadiene–Styrene with Gas-Phase-Synthesized Graphene for Injection-Molding Applications

Enhancing the Strength of Acrylonitrile–Butadiene–Styrene with Gas-Phase-Synthesized Graphene for Injection-Molding Applications

Evaluation of Fused Deposition Modeling Materials for 3D-Printed Container of Dosimetric Polymer Gel.

Accurate dosimetric verification is becoming increasingly important in radiotherapy. Although polymer gel dosimetry may be useful for verifying complex 3D dose distributions, it has limitations for clinical application due to its strong reactivity with oxygen and other contaminants. Therefore, it is important that the material of the gel storage container blocks reaction with external contaminants. In this study, we tested the effect of air and the chemical permeability of various polymer-based 3D printing materials that can be used as gel containers. A methacrylic acid, gelatin, and tetrakis (hydroxymethyl) phosphonium chloride gel was used. Five types of printing materials that can be applied to the fused deposition modeling (FDM)-type 3D printer were compared: acrylonitrile butadiene styrene (ABS), co-polyester (CPE), polycarbonate (PC), polylactic acid (PLA), and polypropylene (PP) (reference: glass vial). The map of R2 (1/T2) relaxation rates for each material, obtained from magnetic resonance imaging scans, was analyzed. Additionally, response histograms and dose calibration curves from the R2 map were evaluated. The R2 distribution showed that CPE had sharper boundaries than the other materials, and the profile gradient of CPE was also closest to the reference vial. Histograms and dose calibration showed that CPE provided the most homogeneous and the highest relative response of 83.5%, with 8.6% root mean square error, compared with the reference vial. These results indicate that CPE is a reasonable material for the FDM-type 3D printing gel container.

Extraction of volatile organic compounds liberated upon filament extrusion by 3D pen and its comparison with a desktop 3D printer using solid-phase microextraction fiber and Arrow

Desktop 3D printers that operate by the fused deposition modeling (FDM) mechanism are known to release numerous hazardous volatile organic compounds (VOCs) during printing, including some with potential carcinogenic effects. Operating in a similar manner to FDM 3D printers, 3D pens have gained popularity recently from their ability to allow users to effortlessly draw in the air or create various 3D printed shapes while handling the device like a pen. In contrast to numerous modern 3D printers, 3D pens lack their own ventilation systems and are often used in settings with minimum airflow. Their operation makes users more vulnerable to VOC emissions, as the released VOCs are likely to be in the breathing zone. Consequently, monitoring VOCs released during the use of 3D pens is crucial. In this study, VOCs liberated while extruding acrylonitrile butadiene styrene (ABS) filaments from a 3D pen were measured by solid-phase microextraction (SPME) combined with gas chromatography/mass spectrometry (GC/MS). SPME was investigated using the traditional fiber and Arrow geometries with the DVB/Carbon WR/PDMS sorbent while four different brands of ABS filaments—Amazon Basics, Gizmodork, Mynt 3D, and Novamaker—were used with the 3D pen. Heatmap analysis showed differentiation among these brands based on the liberated VOCs. The nozzle temperature and printing speed were found to affect the number and amount of released VOCs. This study goes a step further and presents for the first time a comparison between 3D pen and a desktop 3D printer based on liberated VOCs. Interestingly, the findings reveal that the 3D pen releases a greater number and amount of VOCs compared to the printer. The amounts of liberated VOCs, as indicated by the corresponding chromatographic peak areas, were found to be 1.4 to 62.6 times higher for the 3D pen compared to the 3D printer when using SPME Arrow.