Strength Absorption Research Articles

Improvement of the mechanical properties of the cement mortar by the incorporation of silica particles with low and high surface area

In recent years, nanoaprticules with different sizes have been incorporated in the cement mortar in order to improve their mechanical characteristics. The present work focuses onto the influence of the silica nanoparticles (SiO2) with low and high surface area over the stability and mechanical properties of the cement mortar. The quantities of nanosilica added into the cement mortar to ameliorate their mechanical characteristics vary from 0.5 % to 1.5 %wt. The obtained material after the incorporation of the SiO2 nanoparticles have been characterized by several techniques such as TG, DTG, DSC and their morphologies were determined by using SEM analysis. The workability, water absorption, compressive and flexural strengths of these materials have also been evaluated. The results obtained show that the introduction of the SiO2 nanoparticles into the cement mortar has been greatly improved their compressive and flexural strengths, and the specimens incorporated by nanosilica with high surface area are found more effective than those containing the silica nanoparticles with low surface area, suggesting that the specific surface play a crucial role in the improvement of their mechanical properties. The results show also that the appropriate dosage of silica nanoparticles in the cement mortar to have a maximum enhancement of their mechanical properties was found around 1.5 wt% by weight of cement for the nanosilica with high surface area.

Green Composite Concrete Incorporating with Non-Biodegradable Wastes

This research studied the properties of the green composite concrete for paving blocks comprised of the non-biodegradable wastes of PET bottle flake (15-35 wt%), metalized plastic film from food packaging (0-5 wt%), colored glass powder (5-15 wt%), and ground tire rubber (5-20 wt%) as low cost and ecofriendly reinforced materials. The various concentrations of those wastes in the concrete can be grouped into 14 compositions. The properties of the composite paving blocks were compared to those of standard concrete in terms of density moisture absorption, water absorption, and compressive strength. The results showed that the standard paving blocks had better properties than those of composite paving blocks. The combination of colored glass powder in the concrete can enhance all properties of the concrete block; moreover, the insertion of scrap tires can improve moisture absorption property. However, the addition of metalized plastic, and plastic bottle wastes induced the void inside the concrete decreasing the properties of the concrete.

Low‐velocity impact characterization of polyurethane rubber/nano‐clay enriched sustainable sandwich composites: Synergy of experimentation and simulations

AbstractThis research proposes a novel sustainable composite using basalt (B), hemp (H) and polyurethane rubber (Pu) reinforced in nano clay functionalised epoxy matrix for sacrificial structural applications prone to low‐velocity impact (LVI). To this end, symmetric and asymmetric laminates such as HHHH, BBBB, BHHB, BHPuHB, BBPuHH and BPuBPuHPuH are fabricated using compression molding techniques and subjected to LVI at three different impact energies of 19.66, 39.39, and 59.05 J. The hemp fibers were treated with NaOH solution before fabrication. Material characterization such as X‐ray diffraction, Raman spectroscopy and morphological studies has been carried out. The impact and post‐impact properties of the proposed composites are experimentally evaluated and validated with the finite element (FE) results. The effect on the residual tensile strength degradation of laminates at different interlayers and energy levels is also investigated using the Caprino analytical model. The barely visible impact damages (BVID) are investigated through non‐destructive dye‐penetration tests, which facilitate easy identification of the prominent LVI damages like “Plateau” and “Cliff‐drop” impressions. Based on the impact energy absorption and residual tensile strength, proposed laminates followed BHPuHB > BBBB > BHHB > HHHH. The experimentation suggests that Polyurethane core laminates support maximum impact energy absorption by favoring a structural change in interlayers. Also, the residual tensile strength decreases as impact velocity increases.Highlights Low‐velocity impact behavior of sustainable composites is experimented. Basalt, hemp and polyurethane rubber are reinforced in nano clay epoxy matrix. A FE framework to validate the experimentation is proposed. Dye penetrant NDT is adopted to investigate the damages. Morphological studies are conducted to understand LVI responses.

Effect of natural Sapindus mukorossi treatment process on bio-waste bagasse fibers for biocomposite fabrication and application purposes

In the present research investigation, a novel natural treatment technique consists of Sapindus mukorossi and citric acid was used to treat the fibers as an alternative to conventional chemical treatments that can have adverse effects on both the environment and human health. The fibers were treated with natural solution for varying time intervals of 24, 48, 72, 96 and 120 h, and reinforced with poly-lactic acid using injection moulding machine. The thermal, mechanical and moisture absorption properties of developed naturally treated biocomposites were examined through FTIR spectroscopy, thermogravimetric analysis, and mechanical analysis to explore the optimal treatment period. The optimal treatment period for the fibers was determined to be 72 h, during which overall properties of biocomposite were observed highest. The biocomposites fabricated with 72 h of treatment exhibited 16.8 % improvement in tensile modulus and 22.8 % increment in flexural modulus as compared to untreated fiber biocomposites. Furthermore, the highest levels of water absorption and impact strength were achieved through treatment duration of 96 h and 48 h, resulting in significant improvements of 63.2 % and 22.2 %, respectively. The assessment of surface characteristics was carried out through the use of optical microscopy and scanning electron microscopy (SEM).

Analysis of low-velocity impact responses in bidirectional gradient double-arrow auxetic metamaterials

In this paper, we propose double-arrowed auxetic metamaterials (DAMs) featuring bidirectional wall thickness gradients. Their crushing behavior under low-velocity impact is systematically investigated using a validated finite element (FE) model. The results show that the bidirectional gradient design effectively improves the transverse necking effect observed in uniform DAMs. The bidirectional gradient configuration contributes to improved energy absorption and impact strength. Specifically, there is a 60.7% increase in specific energy absorption (SEA) and a 40.5% improvement in plateau stress, compared to uniform DAMs. Furthermore, the bidirectional gradient configuration reduces the initial peak stresses generated during the dynamic crushing process and exhibits higher crash load efficiency (CLE).

Electrochemiluminescence of Ultrasmall Silica Nanoparticles from Size Modulation and Multipath Surface State Adjustment for Ultrasensitive HIV-DNA Fragment Detection.

Here, ultrasmall SiO2 nanoparticles (u-SiO2 NPs, <5 nm) with obvious electrochemiluminescence (ECL) phenomenon, which was absent for conventional silica nanoparticles (c-SiO2 NPs), were reported. In a finite ultrasmall volume, the u-SiO2 NPs exhibited increasing ground state energy and higher optical absorption strength due to the electron-hole confinement model and favored catalyzing the reaction through the rapid diffusion of bulk charge, resulting in apparent ECL emission. Then, Zn2+-induced u-SiO2 nanoaggregates (Zn/u-SiO2-Ov nAGG) were synthesized and exhibited improved ECL performance via multipath surface state adjustment of u-SiO2 from several aspects, including aggregation-induced ECL, the generation of oxygen vacancy (Ov), and more positive surface charge. In addition, an ECL biosensor was constructed for ultrasensitive human immunodeficiency virus-related deoxyribonucleic acid detection from 100 aM to 1 nM with a low limit of 50.48 aM, combining the ECL luminescence of Zn/u-SiO2-Ov nAGG with three-dimensional DNA nanomachine-mediated multioutput amplification for enhanced accuracy and sensitivity compared to the single-output method. Therefore, exploring the ECL of ultrasmall nanoparticles via the adjustment of size and surface state provided a valuable indication to a wider investigation and application of novel ECL materials for clinical diagnostic.

Medieval and Restoration Bricks: Water Transport (Hygric) and Microstructural Properties – A Compatibility Study

ABSTRACT The aim of this work was to analyze and ascertain the physical, hygric and mechanical properties of historical bricks, in order to deepen knowledge about the properties of existing historical building brick structures. Laboratory tests, such as density, water absorption and compressive strength, were conducted. In order to assess the microstructural characteristics of the tested bricks, mercury intrusion porosimetry (MIP) tests were performed. These tests were conducted on clay bricks from four medieval buildings (14th Century) of great historical significance, as well as on those currently produced, in order to identify the similarities and differences between specific groups of material properties. The results of this study and previous research will form a basis for creating a database of complete information in terms of physic, hygric and mechanical properties of historical bricks from different time periods, from the Middle Ages to modern times. The results will supplement modeling programmes utilizing materials specific to Polish construction periods, which can help simulate, as closely as possible, humidity transfer in real conditions. Moreover, the results will lead to the development of a useful tool for selecting materials in restoration processes, that will correspond with those used historically.

Cleaner Production of Cementitious Materials Containing Bioaggregates Based on Mussel Shells: A Review

This text provides a bibliographic review on bioaggregates obtained from mussel shells and similar materials, evaluating the main properties altered with the use of this type of recycled aggregate in cementitious materials. The bibliographic analysis highlights the main problems and challenges of using bioaggregates related to the presence of organic impurities and chlorides and due to the lamellar and flat shape of the grains, which impair adhesion in the transition zone. The advantages of mussel shell bioaggregates include their limestone-based chemical composition, properties that are inert and compatible with the application, and a specific mass close to conventional aggregates. Regarding their use in cementitious materials, in general, there is a reduction in workability and an increase in incorporated air, porosity, and water absorption, resulting in a reduction in compressive strength. However, it is observed that lower replacement levels make it possible to use bioaggregates, especially fine aggregates, in cementitious materials for different applications, such as structural concrete, coating mortar, and sealing systems. The positive points are related to the promotion of thermal insulation and the reduction in density, which allow for various uses for cementitious materials with bioaggregates, such as lightweight concrete, permeable concrete, and thermal and acoustic insulation mortars. It is concluded that the use of bioaggregates in concrete and mortars is viable, but the need for more experimental work to solve the main problems encountered, such as high water absorption and low compressive strength, is highlighted.

Sandwich structures with TPMS core and printed circuit board faces

Sandwich structures are widely used in the aerospace industries due to their mechanical properties that give them high energy absorption, low density, and high mechanical strength. These structures are composed of two faces interspersed by a core that can have various geometric configurations. One of the most widely used geometric cells are honeycomb structures, highly used in structural applications since the early 20th century. However, new geometric core configurations, as well as alternative materials and manufacturing processes, are being studied for space applications. Triply Periodic Minimal Surfaces (TPMS) are lattice structures composed of periodic surface structures in three independent directions. Among the available models, the most notable TPMS structures are Schwartz-type, Diamond-type, and Gyroid-type. Since the structures are too complex to be manufactured by subtractive manufacturing, additive manufacturing is excellent, being able to produce complex structures much faster and easier. One of the most common types of 3D printing is Fused Deposition Modeling (FDM), which is based on the fusion and deposition of various materials, such as thermoplastic materials. To save space and improve the mechanical strength of Cubesats, sandwich structures are being produced using printed circuit boards (PCB) of electrical and electronic components as outer faces. These faces are called laminates and are made of thermosetting materials such as fiberglass and epoxy resin, composites, or ceramic materials. The objective of this paper is to produce sandwich panels, with a core based on the TPMS architecture. They will be printed in thermoplastic material with laminated faces used in printed circuit boards. A numerical analysis using the finite element method was performed and its testing according to ASTM C393, furthermore, this paper aims to realize an optimized TPMS core with mass distribution based on the stress profile and compare them.

Effective sludge management: Reuse of biowaste and sewer sediments for fired bricks

ABSTRACT This study partially replaced the clay with sewer sludge (SS) and rice husk (RH-SS) to make fired bricks. The brick samples were examed in terms of shrinkage, water absorption, and compressive strength. Besides, they were analyzed via XRD and metal extraction to determine the heavy metal residuals in the products. The results showed that it was possible to fabricate fired bricks using sewer sludge or rice husk-blended sludge with up to 30% by weight. These brick samples complied with the technical standard for clay brick production, in which the compressive strength was more than 7.5 MPa, water absorption was from 11–16%, and the linear shrinkage was all less than 5%. The rice husk addition helped mitigate the heavy metal residuals in the bricks and leaching liquid, in which all the values were lower than the US-EPA maximum concentration of contaminants for toxicity characteristics. Implications: Previous studies have proved the possibility of mixing sewage sludge from different origins (sewage sludge, river sediment, canal sediment, sewer sediment, etc.) with clay and some wastes to make bricks. In which, mostof the studies used sewage sludge from wastewater treatment plants, very fewdealt with lake/river or sewer sediment. This study shall be the first to study the possibility of employing sewer sediments with the addition of rice husk powder to achieve two targets, including (1) the reuse of biowaste and sludge for brick fabrication and (2) the reduction of heavy metals in final calcined bricks. Different ratios of the rice-husk blended sewer sludge (RH-SS) – clay mixture shall be tested to find the optimized compositions. The results showed that it was possible to fabricate fired bricks using sewer sludge or rice husk-blended sludge with up to 30% by weight, which meant reduce 30% of clay in the brick production. The final products were proved to meet the quality standard in terms of compressive strength (more than 10 MPa), water absorption(from 11–16%), and the linear shrinkage (less than 5%). Larger scale of this study can be an evident to recommend for policy change in the waste reuse in construction field.

A new perspective on the effect of residual paste content on the properties of recycled fine aggregates

As a critical evaluation indicator for recycled fine aggregates (RFA), residual paste content (RPC) significantly impacts their performance and application. However, due to the different particle size gradients within RFA, their potential heterogeneity makes the relationships between RPC and the properties of RFA unclear. This ambiguity hinders the reuse of RFA in practical engineering. In this study, to elucidate these relationships, RFA were divided into 2.36–4.75 mm, 1.18–2.36 mm, and 0.60–1.18 mm. Within each size fraction, RFA were characterized by determining the RPC, water absorption, apparent density, crushing characteristics and compressive strength. The relationships between RPC and these properties were established. The results showed that even within narrower size fractions, the variation of RPC caused fluctuations in the properties of RFA. Higher correlations between RPC and the properties of RFA were revealed after the division compared to the undivided size fraction (0.60–4.75 mm). The limit values of RPC allowed the classification of RFA within each size fraction instead of time-consuming aggregate property tests. This study provides a new perspective on the effective application of RFA through the division of particle size gradients.

Physical and thermomechanical characterization of unidirectional Helicteres isora fiber-reinforced polylactic acid bio-composites

Identifying novel cellulose fiber bio-composites has become a vital initiative in the exploration of sustainable materials due to increased global concern for the environment. This growing focus on eco-friendly materials has gathered significant attention in recent years. The current investigation deals with one such material, Helicteres isora reinforced Polylactic acid composites. Surface chemical treatment of fiber is one of the most effective methods to modify the hydrophilic fiber to increase its compatibility with the polymer matrix. Sodium hydroxide was used as a pre-treatment chemical to remove any impurities from the fiber surface. Pre-treated fibers were treated with Methacryl silane and Potassium permanganate solution to chemically modify the fiber surface. Density, void content and water absorption behavior of the composites were analyzed as per the standard procedure. Tensile and flexural tests were conducted to evaluate the mechanical strength, modulus, and flexibility of the unidirectional composites. Thermogravimetric and differential thermal analyses were performed to investigate the thermal stability, melting behavior and degradation profiles of prepared composites. A study of failure mechanisms and morphology of the fractured surface through photographs and SEM images revealed fiber splitting and delamination as the dominant reasons behind the failure of composites under tensile loading. Silane-treated Helicteres isora fiber-reinforced Polylactic acid composite exhibited lower water absorption and higher tensile strength than its counterparts. Untreated fiber composite showed maximum flexural strength among the tested composites. By collectively evaluating the results of the tests and properties of the composites, silane-treated fiber-reinforced Polylactic acid composites stands out as the most favorable choice.

Predicting Mechanical Properties of Carbonate Rocks Using Spectroscopy Across 0.4–12 μm

Determining the mechanical characteristics of rocks is crucial in various civil engineering sectors. Traditionally, the mechanical properties of rocks are determined through on-site and laboratory tests carried out during geotechnical surveys. However, these extensive surveys require considerable time and resources. In contrast, hyperspectral remote sensing techniques offer a rapid and simple means to determine the mineral composition and crystallographic structure of rocks. These features, in turn, influence the rocks' mechanical properties. This study focuses on characterizing the mechanical properties of carbonate rocks in a laboratory setting, using hyperspectral sensors. Approximately 150 cylindrical carbonate rock samples, spanning a wide strength range, were collected from diverse Israeli rock outcrops. Employing a point spectrometer (0.4 to 2.5 µm) and a spectral image sensor (8.0 to 12.0 µm), we captured samples' light reflections and spectral emissivity. Mechanical attributes, including density, porosity, water absorption, and uniaxial compressive strength (UCS), were measured. Advanced data mining techniques identified statistical correlations between hyperspectral signatures and mechanical properties, pinpointing key wavelengths for prediction. The developed models exhibited excellent predictability for the specified properties, attributing accuracy to discernible mineralogy and internal crystalline structure through spectroscopy. However, predicting UCS showed slightly weaker results due to influences from internal flaws not entirely reflected in spectroscopic data. Nonetheless, outcomes regarding rock UCS were deemed satisfactory. These findings open avenues for non-destructive tools in assessing the mechanical properties of rocks in quarrying operations.

Microwave‐Assisted Confining Growth and Liquid Exfoliation of sp3‐Hybrid Carbon Nitride Nano/Micro‐Crystals

As one promising carbon‐based material, sp3‐hybrid carbon nitride has been predicted with various novel physicochemical properties. However, the synthesis of sp3‐hybrid carbon nitride is still limited by the nanaoscale, low crystallinity, complex source, and expensive instruments. Herein, we have presented a facile approach to the sp3‐hybrid carbon nitride nano/micro‐crystals with microwave‐assisted confining growth and liquid exfoliation. Actually, the carbon nitride nano/micro‐crystals can spontaneously emerge and grow in the microwave‐assisted polymerization of citric acid and urea, and the liquid exfoliation can break the bulk disorder polymer to retrieve the highly crystalline carbon nitride nano/micro‐crystals. The obtained carbon nitride nano/micro‐crystals present superior blue light absorption strength and surprising photoluminescence quantum yields of 57.96% in ethanol and 18.05% in solid state. The experimental characterizations and density functional theory calculations reveal that the interface‐trapped localized exciton may contribute to the excellent intrinsic light emission capability of carbon nitride nano/micro‐crystals and the interparticle staggered stacking will prevent the aggregation‐caused‐quenching partially. Finally, the carbon nitride nano/micro‐crystals are demonstrated to be potentially useful as the phosphor medium in light‐emitting‐diode for interrupting blue light‐induced eye damage. This work paves new light on the synthesis strategy of sp3‐hybrid carbon nitride materials and thus may push forward the development of multiple carbon nitride research.

Analysis of contaminant dispersion in constructed wetland flows with absorptive boundaries

Pollution in wetland flows poses a significant challenge to ecosystem preservation, underscoring the importance of wetland restoration. Constructed wetlands have emerged as a widely embraced solution for contaminant mitigation. In this study, we focus on the contaminant removal process within the wetland flows to contribute to wetland restoration. A constructed wetland with ecological floating and bottom absorptive beds has been employed to enhance the capacity of contaminant removal within wetland flows. However, the environmental dispersion in constructed wetland flows is further complicated by the presence of irreversible first-order absorptive boundaries at the upper and bottom beds. Therefore, our work focuses on comprehending the expansion processes of contaminant clouds under absorptive boundaries through a multiscale analysis to demonstrate the removal effects of constructed wetlands. The findings highlight significant deviations in the spatial distribution of contaminant clouds, particularly in the vertical dimension, attributed to absorptive effects. To analyze the impact of removal mechanisms on the dispersion patterns of contaminant clouds, variations in the vertical concentration peak are examined. A predictive model is developed to estimate the position of the concentration crest in the vertical direction based on changes in absorptive ratios between the upper and bottom boundaries. Furthermore, in order to explore the key factor on removal capacity and efficiency within constructed wetland flows, we look into the process of contaminant depletion by examining variations in removed mass and local absorptive and removal efficiency along the streamwise direction in response to deviations in absorptive strengths at the upper and bottom beds. The ratios of the two boundary removal intensities play a significant role in the absorptive dynamics within wetland flows, particularly during the early stages of cloud expansion. By adjusting the absorption ratio between two absorptive beds to 1:1 with a certain total depletion strength in wetland flows, the enhancement ratio of depletion efficiency can increase by nearly 30%. It has been proven that employing identical absorption strengths at two absorptive beds is an economical and efficient means to amplify the absorption efforts within designed constructed wetland flows. This study provides guidelines for the design of constructed wetlands aimed at enhancing their capacity for sewage treatment.

Feasibility of Treated Sand Brick Waste with Silica Fume Based Geopolymer for Coarse Aggregate Application

Construction and demolition waste (CDW) management should focus on reducing CDW or properly recycling the materials since this waste is now a global problem. Sand brick waste, a component of a building’s structure, is one type of CDW. To be used as recycled aggregate, these wastes are invariably categorised as low grade. Due of the improved qualities provided, geopolymer research has recently become more popular. The objective of this study is to investigate the physical and mechanical properties of recycled sand brick aggregate (RSB) treated with silica fume based geopolymer coating. Additionally, the effectiveness of the treated RSB will be applied in concrete as coarse aggregate. The sample was made using a solid-to-liquid ratio of 1.0, 1.2, 1.4, 1.6, and 1.8. At 2.5 and 10 M, alkaline activator is a constant variable. Testing of specific gravity, water absorption, and aggregate impact value were analysed. The treated RSB concrete will then be evaluated against normal concrete. In terms of density, water absorption, and compressive strength, natural concrete performs better than treated RSB concrete. In comparison to natural concrete, treated RSB concrete absorbs 5.8% more water. Treated RSB concrete has a density of 1815 kg/m3, compared to natural concrete’s 2080 kg/m3. The compressive strength of concrete made using treated RSB aggregate is 18.1 MPa after 7 days, and 27.1 MPa at 28 days. The testing revealed that the treated RSB aggregate concrete met the specifications. As a result, treated RSB aggregate concrete offers an advantage over natural OPC concrete while saving the environment.

Assessment of the properties of mortars made of sorel cement

The purpose of laboratory tests was to determine the effect of sodium silicate and selected hydrophobic agents on the basic physical parameters and freeze-thaw durability of mortars made with Sorel cement in variable proportions. In order to determine the mortars’ parameters, samples of the dimensions of 4x4x16 cm and boards of the diameters of 1x4x16 cm were prepared. Parameters such as water absorption, capillary absorption, compressive and flexural strength and frost resistance were tested. Mortar supplemented with sodium silicate in the quantity of 2.6% of all components demonstrated the best properties. None of the other hydrophobic agents that were used to mitigate the negative effects of water on Sorel cement mortars demonstrated such positive properties. Flexural strength tests of all mortar batches, performed on cuboid samples and boards of the thickness of 1 cm, demonstrated a similar improvement in strength. The lowest value of compressive strength was recorded for the reference batch at 46.6 MPa, whereas the highest value was recorded for the second batch containing sodium silicate, at 49.8 MPa. During the testing of frost resistance, the lowest reduction of compressive and flexural strength was recorded for the reference mortar and for mortar with sodium silicate. All mortars were varied in the MgO/MgCl2 ratio and the total amount of water, the observed effects may be caused by other variables. However it is possible to notice the positive effect of selected hydrophobic agents.

Experiment on MICP-solidified calcareous sand with different rubber particle contents and sizes

Microbially induced calcite precipitation (MICP) is a new environmentally friendly technology, with the ability to improve the mechanical properties of calcareous sand. Rubber is a high-compressibility material with a higher damping ratio than that of calcareous sand. In this study, calcareous sand was replaced by equal volume contents (0%, 1%, 3%, 5%, 7%, and 9%) and different sizes (0–1, 1–2, and 2–3 mm) of rubber, and a series of water absorption and unconfined compressive strength (UCS) tests were conducted on MICP-solidified rubber–calcareous sand (MRS). The results showed that the water absorption is reduced when the rubber content is larger. The UCS of 0–1-mm MRS decreased with the increase in rubber content. For 1–2-mm and 2–3-mm MRS, the UCS was improved by 11.30% and 15.69%, respectively, compared with the clean sand. Adding rubber promoted the formation of calcium carbonate, but the strength and stiffness of rubber particles were lower than those of the calcareous sand. Therefore, higher rubber content weakened the sand frame bearing system, and the UCS decreased when the rubber content was more than 5%. Moreover, a large amount of 0–1-mm rubber led to the increase in transverse deformation of the samples, which caused the acceleration of the destruction of the sand structure. The water absorption of 0–1-mm MRS was higher than that of 1–2-mm and 2–3-mm MRS, but the UCS of 0–1-mm MRS was lower. The best rubber size is 1–2 mm and 2–3 mm, and the best rubber content is 3%–5%. The outcome of this study may, in the authors’ view, prove beneficial in improving the strength of calcareous sand when it is reinforced by MICP-combined rubber.

Clay influence on lightweight brick’s properties: Investigating the impact of waste’s nature and amount as secondary variables

The present study aims to examine whether incorporating a specific proportion of a particular waste material consistently yields bricks with favorable properties, regardless of the raw clay type utilized. In this context, different mixtures were produced with a clay named AMD2 and 0 wt%, 5 wt% and 10 wt% addition of two wastes named argan nut shell and wheat straw. A first investigation of the used raw clay material revealed the presence of Quartz as a dominant mineral, along with Orthoclase, Illite, and Hematite. Furthermore, the elaborated bricks have been subjected to a physical, mechanical, and structural characterization including loss on ignition (LOI), linear shrinkage (LS), water absorption (WA), apparent porosity (AP), bulk density (BD), and compressive strength (CS). A comparison between the current study and a previous one using the same waste materials and identical proportions of addition but employing a different clay type revealed notable differences in outcomes. In the previous study, bricks fabricated with AMD1 clay and 5 wt% of argan nut shell displayed excellent characteristics. However, in the current investigation using AMD2 clay, bricks with the same waste addition ratio exhibited less favorable properties. Specifically, bricks made with AMD2 clay and 5 wt% argan nut shell showed a loss on ignition of 7.30 %, a linear shrinkage of 3.7 %, a water absorption of 23.3 %, an apparent porosity of 38.20 %, a bulk density of 1.64 g/cm3, and a compressive strength of 9.90 MPa. These outcomes indicated a water absorption above the specified limit and significantly higher apparent porosity compared to bricks produced with AMD1 and 5 wt% argan nut shell, which met standard specifications. This variation highlights how the mineral composition of clay significantly impacts brick properties, even when using the same waste materials and proportions, confirming the importance of considering the raw clay material's nature in bricks’ production, and thus emphasizing the need for a preliminary study before combining clay and wastes in order to achieve excellent results.

Comment on: "Toward Accurate Two-Photon Absorption Spectrum Simulations: Exploring the Landscape beyond the Generalized Gradient Approximation".

A recent benchmark study of two-photon absorption (2PA) strengths using meta-generalized gradient approximation (MGGA) exchange-correlation functionals by Ahmadzadeh, Li, Rinkevicius, Norman, and Zaleśny (ALRNZ24) [ J. Phys. Chem. Lett. 2024, 15, 969] misrepresents the state of the field in this area. Not only was an assessment of 2PA strengths for the exact same benchmark published previously; ALRNZ24 also uses a gauge-variant form of MGGA response theory which produces erratic behavior for certain benchmark systems. Applications of MGGAs to optical and magnetic response properties should use a gauge-invariant extension of MGGA functionals such as paramagnetic current-dependent MGGAs.