14C Ages Research Articles

Complex facies architecture of unusual pyroclastic density current deposits at the Rincón de la Vieja Volcano, Costa Rica

Pyroclastic Density Currents (PDCs) constitute a complex, multiphase, and multiscale volcanic process generated in a wide spectrum of eruptive scenarios and being among the most deadly and destructive volcanic hazards. Over the north flank of the Rincón de la Vieja Volcano, Costa Rica, previous works identified PDC deposits related to the plinian Río Blanco eruption, which is the largest Holocene explosive event recorded at this volcano. However, so far, there have been no in-depth studies aimed at understanding the eruptive style, and dynamics of the parental PDCs. This work presents, for the first time, a detailed facies analysis and architecture reconstruction (plus a geochemical characterization and novel C14 age determinations) of these outstanding deposits. The presence of cauliflower bombs, juvenile mega-blocks, scorias, and pumices, coupled with the scarcity of accidental and/or accessory lithics, is interpreted here as evidence of an unusual eruptive style. We propose that the Río Blanco eruption was a single complex eruption consisting of two successive phases, each involving the drainage of distinct magma batches. The PDCs were related to the sudden spill out of a lava-pool (Arenal-type PDC), during the collapse of an ultraproximal pyroclastic cone that was built in an initial plinian phase. The collapse of this ultraproximal cone produced a leading-edge pumice-rich PDC, which increased its mobility through fragmentation-induced fluidization. This leading edge PDC was followed by successive high concentrated, mafic, modified granular flow pulses derived from the lava-pool spill out. These modified granular flows were highly channelized in proximal zones, but when they reached the main break in slope, the basal underflow froze en masse while its upper, more diluted part started to decouple and move in a more unconfined manner. After the decoupling, the material feeding towards the basal zone of the surviving current produced a new underflow by rapid suspension sedimentation (“surge-derived pyroclastic flows”). Finally, our results indicate that the generation of Arenal-type PDCs is an underestimated scenario that should be considered in future short-term hazard and risk assessments at the Rincón de la Vieja Volcano, as well as in many other stratovolcanoes worldwide.

ADVANCING ANTARCTIC SEDIMENT CHRONOLOGY THROUGH COMBINED RAMPED PYROLYSIS OXIDATION AND PYROLYSIS-GC-MS

ABSTRACT Radiocarbon (14C) dating of sediment deposition around Antarctica is often challenging due to heterogeneity in sources and ages of organic carbon in the sediment. Chemical and thermochemical techniques have been used to separate organic carbon when microfossils are not present. These techniques generally improve on bulk sediment dates, but they necessitate assumptions about the age spectra of specific molecules or compound classes and about the chemical heterogeneity of thermochemical separations. To address this, the Rafter Radiocarbon Laboratory has established parallel ramped pyrolysis oxidation (RPO) and ramped pyrolysis-gas chromatography-mass spectrometry (Py-GC-MS) systems to thermochemically separate distinct carbon fractions, diagnose the chemical composition of each fraction, and target suitable RPO fractions for radiocarbon dating. Three case studies of sediment taken from locations around Antarctica are presented to demonstrate the implementation of combined RPO-AMS and Py-GC-MS to provide more robust age determination in detrital sediment stratigraphy. These three depositional environments are good examples of analytical and interpretive challenges related to oceanographic conditions, carbon sources, and other factors. Using parallel RPO-AMS and Py-GC-MS analyses, we reduce the number of radiocarbon measurements required, minimize run times, provide context for unexpected 14C ages, and better support interpretations of radiocarbon measurements in the context of environmental reconstruction.

HORIZONTAL WATERMILL CHRONOLOGIES BASED ON 14C DATING OF ORGANICS IN MORTARS: A CASE STUDY FROM JARASH, JORDAN

ABSTRACTHorizontal watermills in the southern Levant have proved difficult to date. This study investigates the use of radiocarbon (14C) dating of various organic carbon fractions in structural mortars and carbonate deposits to identify terminus post quem (TPQ) construction dates for seven arubah watermills and two chute watermills in northern Jordan. Dating results from the various organic fractions are discussed in the contexts of carbon fraction integrity and mortar type. The arubah watermill construction dates fall into two chronological groups. Four arubah watermills have Middle Islamic (late 12th to early 14th century AD) construction dates based on macrocharcoal and bulk organic fraction ages, whereas the bulk organic fraction ages of two earlier arubah watermills straddle the Byzantine-Early Islamic transition. Their possible fifth to seventh-century construction dates are among the earliest in the southern Levant. Limited 14C data from the chute water mills suggests that the earliest may date to the sixth–seventh century period, concurrent with the older arubah watermills. The study supports the viability of the AMS 14C method to provide estimated TPQ construction dates for watermills, providing caution is exercised. Short-lived macrocharcoals have the highest integrity but are subject to severe sample loss during pretreatment. 14C ages from humic and humin fractions in earthen mortars are influenced by “old carbon” contamination, possibly a soil reservoir effect, and are centuries older than the probable construction date. Attention is drawn to the potential use of arubah carbonate deposits as proxy records of water flow, watermill use, and hydroclimate.

RETREATMENT OF BONE MATERIAL IN THE GLIWICE RADIOCARBON LABORATORY USING ULTRAFILTRATION

ABSTRACTPreparation of bones for radiocarbon (14C) dating is still quite a challenge for researchers. The methods are being tested and improved, to increase reliability of dating results and to verify the previous ones. In this work, a set of gelatine samples, extracted from Cervus elaphus and Cervus canadensis bones from various sites in Europe and a set of human bones from archaeological sites in Poland were subjected to retreatment using ultrafiltration in Gliwice Radiocarbon Laboratory. The tested samples represent a wide range of ages, from older than 40,000 14C years BP to modern. The prepared material was subjected to the measurement of C/N atomic ratios and 14C dating using the accelerator mass spectrometry (AMS) technique. Also, the stable isotopes (δ13C and δ15N) values were determined. In a few cases ultrafiltration allows to improve gelatine quality for long-stored samples, by increasing the %C and %N as well as decreasing C/Nat ratios. Nevertheless, this effect was not observed for majority of the samples. Remeasurements of long-term stored samples give mostly the same 14C ages for ultrafiltered ones and for those without ultrafiltration.

Pumping-induced groundwater aging and rejuvenation in aquifer-aquitard systems: A perspective from regional groundwater flow

As an indicator of the renewability of a groundwater basin, the spatial distribution of groundwater age has attracted intensive research. As reported in the literature, 3H measurements in 74 US aquifers showed pumping-induced groundwater rejuvenation, whereas 14C ages in two heavily developed aquifers in France and China indicated pumping-induced groundwater aging. Unfortunately, the mechanisms leading to the seemingly opposite behavior of pumping-induced aging and rejuvenation remain unclear. In this study, we conducted numerical simulations of groundwater age in layered aquifer-aquitard systems under different pumping scenarios and aquitard permeability to show that pumping-induced groundwater rejuvenation and aging always occur simultaneously. Groundwater rejuvenation widely occurs throughout the basin wherever the well is located, whereas groundwater aging mainly occurs to the downgradient parts of the basin. Although groundwater rejuvenation is larger in area, groundwater aging is greater in magnitude, and the magnitude of aging increases with pumping intensity and duration. Moreover, when pumping occurs in the discharge area, aging could occur in almost the entire aquifer to the downgradient of the pumping well, and the magnitude of aging is larger. The large area and large magnitude of aging in the discharge area is a direct result of upward leakage of old groundwater from underlying aquitards/aquifers, which is controlled by the topography-driven groundwater flow. By demonstrating the importance of topography-driven groundwater flow and underlying formations in groundwater age redistribution, this study has implications for determining the bottom of a groundwater flow and solute transport model and interpretation of various tracers.

AMS 14C DATING AND STABLE ISOTOPE ANALYSIS ON AN 8-KYR OYSTER SHELL FROM TAIPEI BASIN: SEA LEVEL AND SST CHANGES

ABSTRACT Seven accelerator mass spectrometry radiocarbon (AMS 14C) dates (7260±106∼7607±95 BP averaged 7444±103 BP) on a giant oyster shell, collected from an ancient shore of the Taipei Basin, are similar to the LSC (liquid scintillation counting) 14C age (7260±46 BP) of a grass sample inside the shell. The calibrated 14C ages of the C. gigas by Marine20 are 7490±240∼7805±230 cal BP (average 7660±96 cal BP), generally agreed with the calibrated LSC 14C ages of the grass and the oyster shell. Combined with other 14C ages of shoreline samples in the Taipei Basin, it is evident that sea level rose from 8600 to 7600 cal BP and reached a stand higher than modern sea level. During this marine transgression, the sedimentation rate along the shoreline was very high because 14C dating was not able to detect age differences for 4–5 m thick sediment sequences. Sixty-nine analyses of δ18O and δ13C from the oldest part of the shell exhibit clear seasonal cycles, with a 4-year period of growth in the 5.5-cm section. According to the δ18O values, the ancient oyster grew in a warmer-than-present shoreline environment, suggesting that the current absence of the giant oyster in Taiwan is not due to warming conditions.

Radiocarbon Chronology/Growth Rates of Ooids from Great Salt Lake, Utah

Ooids (calcium carbonate coated grains) are common in carbonate environments throughout geologic time, but the mechanism by which they form remains unclear. In particular, the rate of ooid growth remains elusive in all but a few modern marine environments. In order to investigate the rate of ooid growth in a non-marine setting, we used 14C to date ooids from Great Salt Lake, Utah, a well-known site of aragonitic ooids. Bulk ooids obtained from the northern shore of Antelope Island and the northeast shore of Great Salt Lake near Spiral Jetty were sieved into different size fractions and produced mean ages ranging between 2728±15 and 4373±20 14C yr BP. Larger ooids were older than smaller ooids, implying that larger ooids grew in the environment for a longer duration, with the caveat that bulk age dating integrates the growth history of an ooid. To better resolve growth history, ooids from the coarse fraction were sequentially dissolved, and 14C ages were obtained for each dissolution step to create a time series of ooid growth. The results of the sequential dating indicate that the coarse Great Salt Lake ooid growth began between 5800-6600 ± 60 14C yr BP while their outer cortices are nearly modern. Sequentially dated ooids from the South Arm of Great Salt Lake at Antelope Island record a nearly linear growth history (~ 10-15 µm/kyr), whereas ooids from Spiral Jetty record somewhat faster growth between ~6000 and 4000 years ago (0.03 – 0.06 µm/yr) followed by a 10x slower growth history for the remainder of their lifespan (0.003 – 0.008 µm/yr). The lifespan of Great Salt Lake aragonitic ooids is two to six times longer than those from modern marine environments, and thus provides a unique end member for understanding the mechanisms behind ooid formation. The ooid age range indicates that geochemical parameters measured from bulk ooid dissolution integrates over ~6000 years and thus does not represent a geochemical snapshot in time, as some previous studies have suggested.

Plant macrofossil data for 48-0 ka in the USGS North American Packrat Midden Database, version 5.0

Plant macrofossils from packrat (Neotoma spp.) middens provide direct evidence of past vegetation changes in arid regions of North America. Here we describe the newest version (version 5.0) of the U.S. Geological Survey (USGS) North American Packrat Midden Database. The database contains published and contributed data from 3,331 midden samples collected in southwest Canada, the western United States, and northern Mexico, with samples ranging in age from 48 ka to the present. The database includes original midden-sample macrofossil counts and relative-abundance data along with a standardized relative-abundance scheme that makes it easier to compare macrofossil data across midden-sample sites. In addition to the midden-sample data, this version of the midden database includes calibrated radiocarbon (14C) ages for the midden samples and plant functional type (PFT) assignments for the midden taxa. We also provide World Wildlife Fund ecoregion assignments and climate and bioclimate data for each midden-sample site location. The data are provided in tabular (.xlsx), comma-separated values (.csv), and relational database (.mdb) files.

An integrated study of constraining the initial 230Th of a stalagmite and its implications

High-precision U–Th age is the key to promoting speleothem as an important archive for paleoclimate study. Notably, obtaining reliable U–Th age primarily relies on the accurate initial 230Th correction. However, correcting the U–Th age of stalagmite with the average 232Th/238U value in the crust is sometimes not enough to eliminate the effect of the initial 230Th, using other dating methods (e.g., 14C) and referring to the characteristics of speleothem δ18O values are useful to guide its age correction and establish the chronology. This paper presents a comprehensive study of the chronology and isotopic record of a stalagmite XBL-5 from Xiaobailong Cave, Yunnan, China, using a combination of stalagmite U–Th dating, 14C dating, and δ18O wiggle match dating. The low uranium content of this stalagmite and the apparent inversion of U–Th dating prevent us from establishing the proxy profiles with reliable chronology. We determined the actual age range based on 14C ages assuming various dead carbon proportion (DCP) and uncorrected U–Th ages, along with the characteristic of stalagmite δ18O variations, and then established a credible chronology of this stalagmite through wiggle match of δ18O records. Taking the tuned ages as a reference, the initial 230Th/232Th values were reciprocally calculated. The initial 230Th/232Th atomic ratio of the studied samples was back-calculated to be 75.7 ± 11.4 × 10−6, an order of magnitude higher than the commonly used correction value. The reconstructed XBL-5 δ18O record spans the Younger Dryas (YD) period, indicating that the precipitation δ18O generally increased within the YD chronozone with significant centennial scale oscillations in regions affected by the Indian summer monsoon, in contrast to the speleothem records from East Asian summer monsoon domains which show no or even weakly decreased long-term trend in precipitation δ18O. This study highlights the importance of initial thorium correction in stalagmite chronology study and provides a paradigm for sequence reconstruction of similar samples.

New radiocarbon age constraints on the eruption history of the Quill volcano, St. Eustatius, Dutch Caribbean

Abstract The late Pleistocene to Holocene subaerial pyroclastic deposits of the Quill stratovolcano on the Caribbean island of St Eustatius form seven stratigraphic divisions. New radiocarbon ages of charcoal are presented for the second, third and seventh divisions in order to better constrain the Quill’s eruption history. Three samples from the same layer of Division 2 at two localities on the northeast coast yield ages of 18,020 ± 40 (1σ), 18,310 ± 45 and 18,490 ± 45 14C yr BP (∼19,800–20,600 yr cal BC). These are considerably younger (∼4400 yr) than a previously published result for this division. A single sample of Division 3 gave an age of 8090 14C yr BP (∼7100 yr cal BC) and overlaps with previously published 14C ages for this division. A charred root in the pyroclastic unit deposited by the last eruption of the Quill (Division 7) gave an age of 919 14C yr BP (∼1100–1200 yr cal AD). This result is ∼600 years younger than a previously published age, and its origin is attributed to human activity. The timing of the last eruption of the Quill therefore remains poorly constrained but is older than 600 AD. Terrestrial gastropods found in paleosols and organic material found in small streams that developed in Division 3 indicate that Division 4 must be younger than 6100 ± 500 yr cal BC. The oxygen and carbon isotope composition of the terrestrial gastropods derived from Division 3 paleosols indicates that the C4 and CAM-type vegetation was dominant and that the climate subsequently changed to wetter conditions. The minimum eruption frequency for the Quill volcano is one eruption every ∼1400 years during the past 22,000 years. This eruption frequency of the Quill volcano is of the same order of magnitude as other recent northern Lesser Antilles volcanoes, Soufrière Hills (Montserrat, ∼5000 years) and Mt Liamuiga (St. Kitts, ∼2500 years).

Transformation and aging of organic matter during degradation and preservation in marine sediment of the northern South China Sea

Organic matter (OM) preservation in marine sediments is an important sink in the carbon cycle and the isotopic records of the preserved OM provide useful information on the sources, biodegradation, and transformation of organic carbon during early diagenesis. Here, we present radiocarbon data combined with stable carbon isotope measurements of total organic carbon (TOC) and four organic fractions, namely, total lipids, hydrolysable amino acids (THAAs), humic acids (HAs), and acid-base insoluble OM, separated from four sediment cores collected from the South China Sea (SCS), to reveal their sources and transformation. The total lipids, THAAs, HAs and acid-base insoluble OM fractions account for 1.1 ± 0.4%, 3.1 ± 1.6%, 12.7 ± 9.4% and 61.6 ± 10.0% of the TOC (the percentages of organic fraction in TOC), respectively, and the acid-base insoluble OM is the dominant fraction of TOC preserved in the sediments. Distinct differences in both 13C and 14C values are found among these organic fractions. The δ13C values are more depleted in total lipids and HAs (−23.1‰ to −30.2‰) than in THAAs and the acid-base insoluble OM (−15.3‰ to −20.6‰), which indicates that HAs could be polymerized from lipid-like materials. The acid-base insoluble OM has the lowest Δ14C values (−848‰ to −358‰), with the oldest 14C ages (mean of 7330 years before present) compared to total lipids (−574‰ to −253‰, 3860 years), THAAs (−331‰ to −66‰, 1527 years) and HAs (−569‰ to −168‰, 2916 years) in these sediment cores. The δ13C and Δ14C values of THAA in the sediment are similar to those of pore-water dissolved organic carbon (DOC), indicating that THAA is preferentially degraded and converted to DOC. These results reveal that OM derived from marine and terrestrial sources decompose selectively and contribute differently to the organic fractions during early diagenesis and preservation in marine sediment. The very aged acid-base insoluble fraction is likely formed as a complex of the most refractory OM during microbial degradation and alteration of TOC, representing a major mechanism of OM sequestration in marine sediments.

The marine reservoir age of Greenland coastal waters

Abstract. Knowledge of the marine reservoir age is fundamental for creating reliable chronologies of marine sediment archives based on radiocarbon dating. This age difference between the 14C age of a marine sample and that of its contemporaneous atmosphere is dependent on several factors (among others, ocean circulation, water mass distribution, terrestrial runoff, upwelling, and sea-ice cover) and is therefore spatially heterogeneous. Anthropogenic influence on the global isotopic carbon system, mostly through atmospheric nuclear tests, has complicated the determination of the regional reservoir age correction ΔR, which therefore can only be measured in historic samples of known age. In this study we expand on the few existing measurements of ΔR for the coastal waters around Greenland, by adding 92 new radiocarbon dates on mollusks from museum collections. All studied mollusk samples were collected during historic expeditions of the late 19th and early 20th centuries, and besides coastal sites around Greenland, the new measurements also include localities from the western Labrador Sea, Baffin Bay, and the Iceland Sea. Together with existing measurements, the new results are used to calculate average ΔR values for different regions around Greenland, all in relation to Marine20, the most recent marine radiocarbon calibration curve. To support further discussions and comparison with previous datasets, we use the term ΔR13, where the suffix 13 refers to the previous calibration curve Marine13. Our study explores the links between the marine reservoir age and oceanography, sea-ice cover, water depth, mollusk feeding habits, and the presence of carbonate bedrock. Although we provide regional averages, we encourage people to consult the full catalogue of measurements and determine a suitable ΔR for each case individually, based on the exact location including water depth. Despite this significant expansion of the regional reservoir age database around Greenland, data from the northern coast, directly bordering the Arctic Ocean, remain missing.

Identification and tentative removal of collagen glue in Palaeolithic worked bone objects: implications for ZooMS and radiocarbon dating

Collagen glue has been used for nearly two centuries to consolidate bone material, although its prevalence in museum collections is only now becoming visible. Identifying and removing collagen glue is crucial before the execution of any geochemical or molecular analyses. Palaeolithic bone objects from old excavations intended for radiocarbon dating were first analysed using ZooMS (Zooarchaeology by Mass Spectrometry) to identify the animal species, however peaks characteristic of both cattle and whale were discovered. Two extraction methods for ZooMS were tested to identify the authentic animal species of these objects, which revealed that these were originally whale bone objects that had been consolidated with cattle collagen glue. This is the first time animal collagen glue has been identified in archaeological remains with ZooMS, illustrating again the incredible versatility of this technique. Another technique, Fourier Transform Infrared Spectroscopy in Attenuated Total Reflectance mode (FTIR-ATR), was also tested if it could rapidly identify the presence of collagen glue in archaeological bone material, which was not the case. Two other cleaning methods were tested to remove bone glue contamination prior to radiocarbon dating, along with two modified collagen extraction methods for ZooMS. These methods were applied to bone blank samples (FmC = 0.0031 ± 0.0002, (n = 219), 47 336 ± 277 yr BP) that were experimentally consolidated with collagen glue and to the Palaeolithic bone material (ca. 15 000 and 12 000 yr BP). The experimental bone blanks produced excellent 14C ages, suggesting the cleaning methods were successful, however the 14C ages for some of the Palaeolithic material remained too young considering their contextual age, suggesting that the collagen glue contamination had most likely cross-linked to the authentic collagen molecule. More research is needed in order to gain a deeper understanding of the occurrence and elimination of cross-linked collagen-based glues in material from museum collections.

Using multiple isotopes to determine groundwater source, age, and renewal rate in the Beishan preselected area for geological disposal of high-level radioactive waste in China

Understanding hydrogeological conditions is crucial for selecting and assessing the long-term safety performance of a high-level radioactive waste (HLW) disposal repository. Utilizing environmental isotopes as effective markers for analysing groundwater movement, this study investigates groundwater recharge sources, age, and renewal rates using multiple isotopes in China's potential HLW repository site, the Beishan area. The results indicated deep bedrock groundwater primarily derives from ancient precipitation infiltration under cold climatic conditions. A noteworthy distinction is that loose sedimentary groundwater exhibits higher tritium content (>10 TU) compared to bedrock groundwater (<3.2 TU). Groundwater within the recharge area, especially within gullies and piedmont slope deposits, is relatively youthful, with an age of less than 30 years and an annual renewal rate exceeding 5 %. In contrast, the shallow groundwater age in the intermountain basins and depressions of the discharge area generally exceeds 50 years, with an annual renewal rate often falling below 0.5 %. At the Beishan underground research laboratory site, deep groundwater at the disposal repository depth displays a corrected 14C age exceeding 8,000 years, indicating an extremely slow movement and alteration rate. As a result, the hydrogeological conditions in the Beishan area are expected to be relatively beneficial for ensuring the safety of HLW repository.

COMPREHENSIVE UPDATE OF MARINE RESERVOIR VALUES FOR NEW ZEALAND COASTAL WATERS TO INFORM COASTAL HAZARD RESEARCH

ABSTRACTMarine radiocarbon (14C) ages are an important geochronology tool for the understanding of past earthquakes and tsunamis that have impacted the coastline of New Zealand. To advance this field of research, we need an improved understanding of the radiocarbon marine reservoir correction for coastal waters of New Zealand. Here we report 170 new ΔR20 (1900–1950) measurements from around New Zealand made on pre-1950 marine shells and mollusks killed by the 1931 Napier earthquake. The influence of feeding method, living depth and environmental preference on ΔR is evaluated and we find no influence from these factors except for samples living at or around the high tide mark on rocky open coastlines, which tend to have anomalously low ΔR values. We examine how ΔR varies spatially around the New Zealand coastline and identify continuous stretches of coastline with statistically similar ΔR values. We recommend subdividing the New Zealand coast into four regions with different marine reservoir corrections: A: south and western South Island, ΔR20 –113 ± 33 yr, B: Cook Strait and western North Island, ΔR20 –171 ± 29 yr, C: northeastern North Island, ΔR20 –143 ± 18 yr, D: eastern North Island and eastern South Island, ΔR20 –70 ± 39 yr.

LAGOA SALGADA: AN OVERVIEW OF A BRAZILIAN HYPERSALINE LAGOON ENVIRONMENTAL STUDIES OVER THE LAST 5000 YEARS USING RADIOCARBON DATE CORRECTIONS

ABSTRACTThe Lagoa Salgada is located in the Paraíba do Sul river delta plain on the coast of Rio de Janeiro state, Brazil, and is one of the few lagoons in the world that have well-developed recent stromatolites. Lagoa Salgada is a hypersaline lagoon formed in a very complex environmental system subjected to terrestrial and oceanic influences under different sea level regimes and climate variations. In addition, sediment and stromatolites are characterized by unusually positive inorganic δ13C VPDB values. For this reason, it has been the target of several geological and paleoenvironmental studies, which, in their great majority, require a geochronological technique in order to determine the changes in the environment over time. When radiocarbon (14C) dating is used, it is necessary to consider some details as the source of 14C in the environment and perform 14C ages calibration accordingly. In the present paper, a bibliographic survey was carried out in order to review the data treatment and improve the environmental evolution discussion based on accurate calibration. Using the Marine20 curve and an undetermined ΔR, we generated growth and depositional models to establish an overview of the formation of this lagoon.

A SUMMARY OF RADIOCARBON MEASUREMENTS OF FLUVIAL AND COLLUVIAL DEPOSITS IN CATCHMENTS OF SOUTH-CENTRAL ONTARIO, CANADA

ABSTRACTFluvial and colluvial deposits of Late Holocene age in South-Central Ontario catchments have provided few 14C dates, most by conventional methods registering century-old ages. Other young deposits, dated by conventional and accelerator mass spectrometry radiocarbon (AMS 14C), have yielded bomb-affected post-1950 ages over variable time limits. Attempts to date the base of Ah and lower-in-section soil horizons, in Early to Late Holocene stream terrace deposits, have yielded atomic bomb effects. Comparing bomb contamination in Late Holocene fluvial deposits, using both conventional and AMS methods, identifies a mix of bomb-affected beds juxtaposed with dated beds, the latter yielding ages with narrow standard deviations. Colluvial deposits overlying key glacial sections in the Rouge Catchment, while rare, yield bracketed AMS ages for an Ahbk horizon that refines weathering times relative to previously obtained conventional 14C dates. Bomb-affected sediment appears variably distributed within floodplain soils and in the ground soil of a colluvial section. Mass wasted deposits, with AMS 14C ages spread over the last few centuries, appear related to Little Ice Age (LIA) changes in climate, corroborated by pollen records. Further, these AMS-14C dated beds calibrate weathering of secondary Fe-Al oxihydroxides over the first half a millennium of weathering time.

The mid‐latitude hydrolaccolith of the Spanish Central System (Southern Europe): A top‐to‐bottom integration of geomatic, geophysical and sedimentary datasets for characterising a singular periglacial landform

AbstractPermafrost study in the Spanish Central System (~41°N) has remained elusive in past decades. Although numerous periglacial features have been described, none has yielded conclusive information about the existence/distribution of permafrost across these mountains. This work focuses on integrating light detection and ranging and unmanned aerial vehicle data with geophysical methods and sedimentary records, along with preliminary thermal information, for the comprehensive study of a frost mound. The singularity of this feature resides in its location, currently dominated by a seasonal frost regime, and its size reaching 59 m long, 22.5 m wide and 4 m high, representing the largest landform of this type in Iberia. From top‐to‐bottom, the internal structure comprises three resistivity units (G1, G2 and G3). The most superficial unit (G1) consists of a sequence of burial soils alternating with sand and silts, with pebbles and gravel at the bottom, followed by a high porous layer that belongs to a landslide deposit (G2), likely composed of gravel and pebbles laying over unit G3 (bedrock). Calibrated 14C ages suggest this landform formed at least ~4300 years ago during the mid‐Holocene. Finally, the preliminary surface thermal map indicates the presence of sectors affected by strong thermal gradients likely driven by water table variations. Our results conclude that the dynamics are primarily controlled by the seasonal frost regime influencing local subsurface drainage, which allows us to classify this landform as a hydrodynamic pingo‐like structure. We also demonstrate that our approach is suitable for assessing the evolution of this type of periglacial landform. Implementing long‐lasting annual monitoring programmes would help to understand local periglacial dynamics better.

Early Holocene ice retreat from Isle Royale in the Laurentian Great Lakes constrained with 10Be exposure-age dating

Abstract. The timing of the Laurentide Ice Sheet's final retreat from North America's Laurentian Great Lakes is relevant to understanding regional meltwater routing, changing proglacial lake levels, and lake-bottom stratigraphy following the Last Glacial Maximum. Recessional moraines on Isle Royale, the largest island in Lake Superior, have been mapped but not directly dated. Here, we use the mean of 10 new 10Be exposure ages of glacial erratics from two recessional moraines (10.1 ± 1.1 ka, one standard deviation; excluding one anomalously young sample) to constrain the timing of Isle Royale's final deglaciation. This 10Be age is consistent with existing minimum-limiting 14C ages of basal organic sediment from two inland lakes on Isle Royale, a sediment core in Lake Superior southwest of the island, and an estimated deglaciation age of the younger of two subaqueous moraines between Isle Royale and Michigan's Keweenaw Peninsula. Relationships between Isle Royale's landform ages and Lake Superior bottom stratigraphy allow us to delineate the retreat of the Laurentide ice margin across and through Lake Superior in the early Holocene. We suggest that Laurentide ice was in contact with the southern shorelines of Lake Superior later than previously thought.

Identification of modern meteoric water, glacial meteoric water, and fossil seawater in a deep borehole at the coastal area of Horonobe, north Japan, using groundwater dating and paleoclimatic proxy methods

Groundwater flow in deep areas of coastal regions has attracted significant attention for geological radioactive waste disposal or geological CO2 storage. To investigate groundwater flow in coastal areas, groundwater dating methods with the potential to assess slow groundwater flow were used at depths of up to 1200 m at Hamasato, Horonobe, northern Japan. Multiple groundwater dating methods were applied using pore water in drilling core and pumping groundwater. This study shows that modern meteoric water, glacial meteoric water, and fossil seawater are distributed in sand and silt layers at 300–360 and 90–300 m in depth and in silt and mud layers below 800 m in depth, respectively. Modern meteoric water infiltrated after and glacial meteoric water infiltrated during the latest glacial period were identified using δD and δ18O values, estimated recharge temperature from noble gas concentrations, and 14C concentrations. The estimated recharge temperatures of modern and glacial meteoric waters were 8.1 ± 2.0 and 2.1 ± 2.0 °C, respectively, whereas the δD and δ18O values were −68 ± 3‰ and −10.3 ± 0.2‰, −81 ± 2‰ and −11.4 ± 0.3‰, respectively. The 14C age of modern meteoric water was 10–16 ka. However, the 14C age of glacial meteoric water could not be estimated because it was highly diluted by 14C-free CO2 from methanogenesis and marine carbonate dissolution. Fossil seawater was identified using δD, δ18O, 36Cl, and 4He. δD and δ18O values underwent water-rock interaction and approached inland fossil seawater with increasing depth. 36Cl/Cl values did not reach secular equilibrium in situ in the Yuchi Formation due to its relatively short geological age and consolidation-induced porosity changes. However, the Yuchi Formation seawater is considered extremely old because its 36Cl/Cl ratio is higher than that of modern seawater as a result of 36Cl production, which also explains the observed 36Cl/Cl increases with depth toward the secular equilibrium ratio (36Cl/Clse). 4He concentrations were in the order of 10−6 ccSTP/gw, corresponding to an in situ accumulation age of 1–2 Ma, neglecting the external flux. The contribution of external flux could be negligible for the short geological age and rapid sedimentation rates. 4He ages were equivalent to the geological age of the Yuchi Formation. Core investigations can interpolate groundwater investigations because cores, particularly those from low-hydraulic conductivity layers, can be collected continuously. In addition, stable and radioactive isotopes and noble gases can help identify modern meteoric water, glacial meteoric water, and fossil seawater, assisting in understanding the groundwater flow velocity.