An integrated study of constraining the initial 230Th of a stalagmite and its implications

Abstract

High-precision U–Th age is the key to promoting speleothem as an important archive for paleoclimate study. Notably, obtaining reliable U–Th age primarily relies on the accurate initial 230Th correction. However, correcting the U–Th age of stalagmite with the average 232Th/238U value in the crust is sometimes not enough to eliminate the effect of the initial 230Th, using other dating methods (e.g., 14C) and referring to the characteristics of speleothem δ18O values are useful to guide its age correction and establish the chronology. This paper presents a comprehensive study of the chronology and isotopic record of a stalagmite XBL-5 from Xiaobailong Cave, Yunnan, China, using a combination of stalagmite U–Th dating, 14C dating, and δ18O wiggle match dating. The low uranium content of this stalagmite and the apparent inversion of U–Th dating prevent us from establishing the proxy profiles with reliable chronology. We determined the actual age range based on 14C ages assuming various dead carbon proportion (DCP) and uncorrected U–Th ages, along with the characteristic of stalagmite δ18O variations, and then established a credible chronology of this stalagmite through wiggle match of δ18O records. Taking the tuned ages as a reference, the initial 230Th/232Th values were reciprocally calculated. The initial 230Th/232Th atomic ratio of the studied samples was back-calculated to be 75.7 ± 11.4 × 10−6, an order of magnitude higher than the commonly used correction value. The reconstructed XBL-5 δ18O record spans the Younger Dryas (YD) period, indicating that the precipitation δ18O generally increased within the YD chronozone with significant centennial scale oscillations in regions affected by the Indian summer monsoon, in contrast to the speleothem records from East Asian summer monsoon domains which show no or even weakly decreased long-term trend in precipitation δ18O. This study highlights the importance of initial thorium correction in stalagmite chronology study and provides a paradigm for sequence reconstruction of similar samples.