Abstract
A novel example of Ugi/Palladium-catalyzed intramolecular cyclopropyl direct alkenylation cascade reaction providing access to novel azacycles in one pot has been developed. Palladium-catalysed direct alkenylation of cyclopropyl C–H bonds proceeds in high efficiency with easy work-up. This transformation was adjusted by 2-substituent on cyclopropyl providing alternative access to cyclopropyl-fused azacycles or ring-expending products.
Published Version
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