Abstract
1. The liquid-phase oxidation of dimethylaniline (DMA) proceeds through a radical-chain mechanism with second-power chain rupture. Rate constants for chain propagation and rupture have been determined. 2. The DMA peroxide radicals (RO2.) differ from the corresponding radicals of β-CH and NH bonded amines insofar as they cannot reduce inhibitors. The latter can only oxidize the DMA RO2.. 3. Rate constants have been determined for the interaction of the DMA RO2. radicals with various aromatic amines and phenols at 40°C.
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