Abstract
1. Aliphatic amines are oxidized according to a radical-chain mechanism. The ratios of the rate constants of chain propagation and termination were measured for cyclohexyl-, dicyclohexyl-, and di-n-butylamines. 2. In primary and secondary aliphatic amines undergoing oxidation, one molecule of the organic inhibitor participates repeatedly in events of chain termination. 3. The relative rate constants of peroxide radicals of cyclohexyl- and di-n-butylamine with inhibitors of various classes were measured at 75°.
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