Abstract
The results of an X-ray two-dimensional analysis of the crystal structure of trimeric phosphonitrilic bromide are reported. The compound is isomorphous with trimeric phosphonitrilic chloride, as found by Bode. The refinement of the structure has been carried out by means of Fourier differential synthesis on the projections (100) and (001). On the basis of the results obtained the most important aspects of the molecular geometry are discussed with reference to the other phosphonitrilic halides thus far investigated.
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