Abstract
Measurements are reported of the solubilities of calcium iodate and copper iodate in buffered solutions of sodium lactate. Copper lactate has been studied by a pH titration method also. Thermodynamic association constants are derived for the formation of the species CaLa + at 25°, 30°, 35°, 40° and 45°C and of the species CuLa +, CuLa 2 at 25°, 30°, 35°, 40° and 45°C where La = Lactate. Δ H°, Δ G° and δD S° are calculated for the formation reactions of these complexes; hydration entropies Δ S hyd. ( MX) of these complexes are also derived.
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