Abstract
Some dimethyl sulphoxide (DMSO) and dimethyl sulphide (DMS) compounds of ruthenium, viz. [Ru(DMSO) 6]X 3 (X = Cl, ClO 4), yellow and red isomers of [Ru(DMSO) 4Cl 2], M[Ru(DMSO) 2Cl 4] [M = Na, Bu 4N (Bu 4N = tetrabutylammonium)], [Ru(DMS) 3Cl 3] and [Ru(DMS) 3Cl 3] 2 have been prepared and their conductivities, thermograms and IR spectra are discussed. Ru-S(DMSO) and Ru-O(DMSO) bonding is found to be present in those complexes containing more than two DMSO ligands. In the case of [Ru(DMSO) 2Cl 4] −, Ru-DMSO bonding involves only sulphur coordination. Form far IR data, [Ru(DMS) 3Cl 3] and its dimer are assigned a mer-configuration.
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