Abstract
Trisdithiocarbamates of arsenic and antimony with pyrrolidine, piperidine, diisobutylamine and dibenzylamine have been prepared by directly mixing either AsCl 3 or SbCl 3 with CS 2 and the corresponding amine. A reasonable mechanism is proposed. The frequencies of bands in the electronic spectra depend on the electron releasing ability of amine groups and probably on steric hinderence effects. Interpretation of the spectroscopic results indicates a distorted octahedral stereochemistry. The distortion is attributed to the stereochemically active lone pair of electrons on the arsenic and antimony atoms.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
