Abstract
In the title compound, [Cu(C7H3NO7S)(C10H8N2)(H2O)]·0.5C10H8N2, the CuII atom is six-coordinated by two N atoms from two different bipyridine (bipy) ligands, one sulfonate O atom and two carboxylate O atoms from three 2-nitro-5-sulfonatobenzoate ligands and one water O atom in a distorted octahedral geometry. The bipy solvent molecule lies on an inversion center. The CuII atoms are linked by the bipy ligands, forming one-dimensional chains, which are connected by the 2-nitro-5-sulfonatobenzoate ligands into a two-dimensional layer-like network. The two-dimensional structure is extended by O—H⋯O and O—H⋯N hydrogen bonds into a three-dimensional supramolecular network.
Highlights
In the title compound, [Cu(C7H3NO7S)(C10H8N2)(H2O)]Á0.5C10H8N2, the CuII atom is six-coordinated by two N atoms from two different bipyridine ligands, one sulfonate O atom and two carboxylate O atoms from three 2-nitro-5sulfonatobenzoate ligands and one water O atom in a distorted octahedral geometry
The bipy solvent molecule lies on an inversion center
The CuII atoms are linked by the bipy ligands, forming one-dimensional chains, which are connected by the 2-nitro-5-sulfonatobenzoate ligands into a two-dimensional layer-like network
Summary
Absorption correction: multi-scan (SADABS; Bruker, 2001) Tmin = 0.767, Tmax = 0.850. Refinement R[F 2 > 2(F 2)] = 0.065 wR(F 2) = 0.135 S = 1.00 4260 reflections 331 parameters. In the title compound, [Cu(C7H3NO7S)(C10H8N2)(H2O)]Á0.5C10H8N2, the CuII atom is six-coordinated by two N atoms from two different bipyridine (bipy) ligands, one sulfonate O atom and two carboxylate O atoms from three 2-nitro-5sulfonatobenzoate ligands and one water O atom in a distorted octahedral geometry. The bipy solvent molecule lies on an inversion center. The CuII atoms are linked by the bipy ligands, forming one-dimensional chains, which are connected by the 2-nitro-5-sulfonatobenzoate ligands into a two-dimensional layer-like network. The two-dimensional structure is extended by O—HÁ Á ÁO and O—HÁ Á ÁN hydrogen bonds into a three-dimensional supramolecular network
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