Abstract
The title compound, {[Mn(C10H8N2)(H2O)4](C9H7O3)2·2H2O}n, was obtained by the hydrothermal reaction of manganese chloride with mixed 3-hydroxylcinnamic acid (H2 L) and 4,4′-bipyridine (4,4′-bipy) ligands. The structure contains [Mn(C10H8N2)(H2O)4]2+ cations with the MnII atoms lying on a centres of inversion and bridged into a linear chain along the a axis by 4,4′-bipy ligands, surrounded by HL − anions and uncoordinated water molecules. Extensive O—H⋯O hydrogen-bonding and weak π–π interactions [centroid–centroid distance = 3.7572 (3) Å] between the constituents lead to the formation of a three-dimensional supramolecular network.
Highlights
Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, People’s
The structure contains [Mn(C10H8N2)(H2O)4]2+ cations with the MnII atoms lying on a centres of inversion and bridged into a linear chain along the a axis by 4,40 -bipy ligands, surrounded by HL
[centroid–centroid distance = 3.7572 (3) Å] between the constituents lead to the formation of a three-dimensional supramolecular network
Summary
ISSN 1600-5368 catena-Poly[[[tetraaquamanganese(II)]-l4,40 -bipyridine] bis(3-hydroxycinnamate) dihydrate] Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, People’s
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