Poly[[diaqua-μ-4,4′-bipyridine-dinitratodi-μ-L-tyrosinato-dicopper(II)]: a chiral two-dimensional coordination polymer

Abstract

The title compound, [Cu(2)(C(9)H(10)NO(3))(2)(NO(3))(2)(C(10)H(8)N(2))(H(2)O)(2)](n), contains Cu(II) atoms and L-tyrosinate (L-tyr) and 4,4'-bipyridine (4,4'-bipy) ligands in a 2:2:1 ratio. Each Cu atom is coordinated by one amino N atom and two carboxylate O atoms from two L-tyr ligands, one N atom from a 4,4'-bipy ligand, a monodentate nitrate ion and a water molecule in an elongated octahedral geometry. Adjacent Cu atoms are bridged by the bidentate carboxylate groups into a chain. These chains are further linked by the bridging 4,4'-bipy ligands, forming an undulated chiral two-dimensional sheet. O-H...O and N-H...O hydrogen bonds connect the sheets in the [100] direction. This study offers useful information for the engineering of chiral coordination polymers with amino acids and 4,4'-bipy ligands by considering the ratios of the metal ion and organic components.