Phase stability of La0.5Sr0.5CoO3−y films upon annealing in hydrogen atmosphere

Abstract

The effect of annealing epitaxial La0.5Sr0.5CoO3−y films in forming gas (FG) mixed with 0.01%, 0.1%, and 1%mol oxygen was investigated using in situ x-ray diffraction at temperatures up to 800°C. The phase transition that occurs at 275°C in pure FG is shifted to higher temperatures by small admixtures of oxygen in FG. Electron diffraction patterns demonstrate that this is a transition into an oxygen-deficient ordered phase with 0,1∕3,0 and 0,2∕3,0 superstructures. The La0.5Sr0.5CoO3−y phase can be recovered by annealing in oxygen at moderate temperatures as long as it has not decomposed at higher temperatures.