Abstract

It is shown that the anomalous triplet splitting observed in theC3 Δ term of the TiO molecule can be interpreted in good agreement with experiment, in addition to the spin-orbit and spin-spin interaction, by taking the centrifugal distortion of the spin-orbit and spin-spin interaction simultaneously into account. The exact values of the coupling constantsA and the other correction constants are also given for theC3 Δ term on the levelsv′=0 andv′=1.

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