Abstract
It will be shown that the anomalous triplet splitting of theC3 π−X3 π andA3 Δ−X3 π, (1,0) bands of the TiO molecule is due — similarly to the splitting of the (0,0) bands— to an anomalous triplet splitting of both the upper and the lower terms. The anomalous triplet splittings can be explained in terms of spin-orbit and spin-spin interactions. The accurate value of the multiplet splitting constantA has been determined for the levelv=1 of the statesC3 π andA3 Δ.
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