Abstract
AlCl 3 precipitates quantitatively as Al(8-quinolinolate) 3 at 20° in 0·5 hr, whereas the amount of aluminium precipitating from Al 2(OH) 5Cl ( 5 6 basic) as 8-quinolinolate depends on time and temperature with an apparent activation energy of 27·9 ± 1·4 kcal. This behaviour is interpreted as due to equilibria between polynuclear aluminium cations in the 5 6 basic solution.
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