Abstract
A convenient approximation is proposed for the correlation function of a pair of large hard-sphere particles in a bidisperse or binary hard-sphere mixture. This approximation is based on the solution of the Ornstein–Zernike/Percus–Yevick integral equations for a hard-sphere mixture. From this result, we obtain the potential of mean force and interaction force for a pair of colloidal spheres in a bidisperse hard-sphere fluid.
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