Electron transport properties of electrically doped guanine nano-sheet based bio-Zener diode: a first principle paradigm

Abstract

The quantum ballistic transmission properties of an electrically-doped guanine-nanosheet-based bio-Zener diode are investigated using density functional theory and nonequilibrium Green’s function-based first-principles calculations. The bio-Zener diode is gate-bias modulated, and its various quantum-electronic properties, for example, the V–I characteristic, the transmission spectra, and the device density of states, depend on both the electrical doping concentration and on the applied gate bias voltage. The junctionless highly doped bio-Zener diode shows high levels of reverse-bias current which is dominated by majority charge carriers. It is also found that, due to the presence of a wide bandgap and the backscattering effect, the forward-bias current is highly suppressed. The quantum simulation results confirm a strong reverse gate-bias-modulated biased current–voltage response as well as a charge transport phenomenon through the effective device region. The bio-Zener diode exhibits a specific reverse breakdown that can be varied from −0.78 to −3.2 V without affecting the forward current–voltage characteristic. The current findings are obtained by including the coherent tunneling and incoherent hopping processes with a minimal Hamiltonian model approach.