Abstract
Mg 0.5Ti 2(PO 4) 3 having NASICON-lattice was prepared by sol–gel method and evaluated as a cathode material for magnesium cells. The crystalline phase could be successfully obtained after heating at 600°C. Electrochemical magnesium insertion from a propylene carbonate solution into this host was found possible and one Mg 2+ ion could be accommodated per unit formula. However, the magnesium insertion process was under kinetic control of Mg 2+ diffusion due to the low mobility of Mg 2+ in this host.
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