Abstract

The influence of double layer structure on the kinetic parameters for the Pu(IV) + e = Pu(III) charge transfer in carbonate media is consistent with anionic depolarizing species associated with supporting cations (ion pairs) in the increasing order Na +, K + and Cs +, whose specific adsorption at the mercury electrode, increasing in the same way, could explain the observed variations in transfer coefficient with the nature of the supporting cation.

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