Abstract
Cu(I) halide complexes of bis(diphenylphosphino)methane (DPM) and 1,2-bis(diphenylphosphino)ethane (DPE) with Cu(I) X L ratio 2:1, 3:2, 4:3, 1:1 and 2:3 ( X = Cl, Br and often I; L = DPE for 2:3, DPM and DPE for the other complexes) were isolated and characterized by analytical data, conductivity and mole. wt. measurements, i.r. and NMR spectra. Almost always complexes are polymorphic and adducts with solvent of crystallization are frequent.
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