Abstract
TA curves can be interpreted kinetically by pattern recognition. Readily available symbol strings are compared with those of theoretical curves, stored in a data bank. Such kinetic codes fix the dependences of the mechanistic coordinates on the initial concentration ofone of the reactants; obviously, they are scarcely influenced by the prevailing values of the activation parameters. The foundations for a model-determinating computer program and the experiences with its application are presented. The program reveals the possible homogeneous two-reaction models from an experimental DTA- or non-isothermal UV-series; these are listed in the order of their evidence values. Similarly, the best superpositions of two two-reaction models are determined.
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