A novel method for assessing indoor di 2-ethylhexyl phthalate (DEHP) contamination and exposure based on dust-phase concentration

Abstract

Phthalates (PAEs) are a group of typical semivolatile organic compounds that are widely present in indoor environments with multiple phases. Indoor air, airborne particle and settled dust are considered to be typical indicators of PAE contamination as well as media of human exposure, and the interactions between them are complex. Among various phthalate compounds, di 2-ethylhexyl phthalate (DEHP) was identified as the predominant individual phthalate in settled dust. The existing DEHP contamination assessment requires multiphase sampling or solving the dynamic mass transfer models with multiple partial differential equations, which are both complicated and time-consuming. This study investigated the influence of the indoor source loading rate, surface type, particle size and cleaning frequency on the partitioning between the settled dust-phase, airborne particle-phase and gas-phase. The concentration correlations of DEHP between multiphases were consequently derived, which balance accuracy and complexity well. By comparison with field sampling data in the literatures, the rationality and accuracy of the concentration correlations were validated. Based on the concentration correlations, a new method of directly using dust-phase concentration to estimate the non-dietary exposure to DEHP was proposed. The results indicated that ingestion of settled dust contributes the most to non-dietary exposure. Special attention should be given to infants and toddlers, who suffer the highest daily exposure to DEHP among all age groups. This study provides a new and efficient solution for estimating indoor DEHP pollution loads conveniently and rapidly, offering valuable insights for future research in this field.