Abstract
Electronic spectra for AgMnO 4 in frozen solution are broad and diffuse and are not characteristic of the permanganate anion. Approximate thermochemical calculations indicate only a small energy difference between the limiting ionic forms Ag +; MnO 4 − and Ag 2+; MnO 4 2−. Vibrational analysis of AgMnO 4, potassium permanganate and barium manganate were carried out and support an intermediate manganese oxidation state in AgMnO 4.
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