Abstract
Size effects during phase transformations change the composition of coexisting phases in ternary mixtures. The consequence is a change in the distribution coefficients of the components, which is of interest for microextraction. The concentration dependence of the degree of extraction for separable mixtures (aniline - methylcyclopentane - hexane and water - phenol - toluene) in submicron drops was simulated by the methods of equilibrium chemical thermodynamics. The concentration dependence of the degree of extraction during microextraction for submicron droplets is constructed.
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