X-ray diffraction analyses of HgTeCdTe and CdTeZnTe superlattices (SL's) have revealed a few exceptional samples possessing complex satellite structures that cannot be attributed to a single modulation period of one specific average composition. All of the examined SL's were grown, by molecular beam epitaxy (MBE), to have one well-defined period. Four of these unique SL's are reviewed and the observed deviations with respect to a single period SL model are illustrated. The SL samples are characterized by several diffraction techniques. Extended x-ray ω − 2θ scans were performed with the scattering vector along the SL growth direction. These scans were complemented by ω scans to assess the lateral coherence of the diffracting planes. The complex diffraction spectra suggest that several SL regions coexist within one macroscopic sample. Differences in the period and average composition distinguish each domain by observing the satellite spacing and central peak position, respectively.
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