Zircon eHf Research Articles

Geochemistry and geochronology of the Miocene adakite-like potassic dikes in Tethyan Himalaya: New insights into Indian lithosphere slab tearing and breakoff

Adakitic and potassic magmatic rocks are widespread in the Himalaya and the Tibetan Plateau, and their petrogenesis might provide potential insights into the deep crustal processes. However, the detailed spatiotemporal distributions of these rocks and their controlling mechanisms remain ambiguous. Here we report geochemical data, zircon U-Pb ages and Hf isotopic compositions of east-west (E-W) directed Qunrang monzonite porphyry dikes located in the Tethyan Himalaya. These rocks are acid and potassic with low Mg, low abundances of compatible elements, low Y and HREE, but with high Al, high Sr (822–1386 ppm) and Ba (2027–6091 ppm), high Th (62–84 ppm), U (9–16 ppm) and Th/U ratios (4–7), and thus high Sr/Y and (La/Yb)N ratios. The above geochemical features, combined with their negative whole-rock εHf(t) values (−3.9 to −4) and negative to small positive zircon εHf(t) values (−7.2 to +0.5), suggest that they were derived from partial melting of a thickened lower continental crust consisting mainly of garnet-amphibolite which were triggered and hybridized by underplating enriched mantle-derived shoshonitic melts. Zircon U-Pb ages of the Qunrang monzonite porphyry yielded a weighted mean age of 10.02 ± 0.33 Ma. Based on these observations, synthesized with the spatiotemporal distribution of the Oligocene-Miocene adakitic and potassic rocks in the southern Tibet, we propose that lateral detachment and longitudinal tearing processes might be potentially accounted for the eastward and southward younging trend of these magmatic rocks, whereas slab rollback and hinge advance might result in the unique E-W directed Qunrang adakite-like potassic dikes and the northward reversal younging trend.

A linked evolution for granite-greenstone terranes of the Pilbara Craton from Nd and Hf isotopes, with implications for Archean continental growth

Granite-greenstone terranes, such as in the Pilbara Craton (Western Australia), record the growth and stabilisation of Archean (>2.5 Ga) continental crust. Yet, uncertainty surrounds the formation of the silica-rich portions of these terranes, important for preservation of continental lithosphere, specifically whether this involved reprocessing of older continental nuclei over hundreds of millions of years, or rapid differentiation of juvenile mantle additions, as preserved in the greenstone belt volcanic sequences. In part, the uncertainty reflects difficulties with establishing the isotope evolution of the early Archean mantle, critical for ascertaining the time gap between the extraction of new crust and granitic emplacement in Archean cratons. To investigate the formation of silica-rich Archean crust, we report Hf and Nd isotope data for 46 mafic–ultramafic samples and zircon Hf isotope data for 83 felsic igneous rocks from the Pilbara Craton, selected to be representative of the major magmatic episodes from 3.56 to 2.72 Ga. The strikingly similar secular isotope trends defined by mafic and felsic rocks reveal a linkage between mantle and crustal processes throughout the history of the craton. From 3.56 Ga to 3.12 Ga, craton evolution was dominated by the transformation of juvenile mantle derived inputs into felsic igneous rocks on short timescales, thus recording sustained continental growth over 400 million years. Incorporation of older crust by felsic magmas was minor during this interval. Evolution toward sub-chondritic Nd and Hf after collision of the East and West Pilbara terranes at 3.1 Ga signals greater involvement of pre-existing crust in magma generation, possibly by recycling of crustal material into mantle source regions or by enhanced reworking of older, thickened cratonic lithosphere. Mafic–ultramafic rocks provide no evidence for anomalous or strongly depleted mantle domains in the Paleoarchean. Rather, the flat zircon εHf–time array indicates extraction of continental materials from mildly super-chondritic mantle from ca. 3.6 to 3.12 Ga and attests to a distinctive style of crust production that operated in the Archean. This study highlights the importance of comparing the mantle and crustal isotope records in order to reconstruct the crustal growth rates in ancient terranes.

Petrogenesis of late Paleoproterozoic post-collisional magmatism in southern north China Craton: Insights from geochemistry and Nd–Hf isotopic compositions of A-type granites

A-type granites are produced commonly in extensional settings and they are important proxies to track breakup of continent. Here we report systematic studies on geochronology and geochemical features of A-type granites in Songxian–Ruyang region, southern margin of the North China Craton (NCC), in order to constrain their petrogenesis and tectonic implications. Zircons from these granites show oscillatory zoning and high Th/U ratios (0.12 to 1.26), indicating a magmatic origin. LA–ICP–MS zircon U–Pb dating shows that they were emplaced at 1813 to 1789 Ma, indicating that they were formed in late Paleoproterozoic. Geochemically, these rocks are high in SiO2 (67.51–74.42 wt%) and total alkalis (Na2O + K2O = 7.76–10.19 wt%), and low in MgO (0.09–1.31 wt%), CaO (0.09–1.11 wt%) and P2O5 (0.12–0.26 wt%) contents, with negative Nb, Ta, Sr, P and Ti anomalies. They are characterized by high FeOT/(MgO + FeOT), 10000 Ga/Al ratios (1.57–3.15) and Zr + Nb + Ce + Y contents (566–835 ppm). They are also characterized by high calculated Zr saturation temperatures (892–918 °C), high Ti-in-zircon temperatures (693–912 °C) and metaluminous to weakly peraluminous natures, which are typical features of aluminous A-type granites, further belonging to the A2 granites. The low zircon εHf(t) values (–13.8 to –8.6), along with the low whole rock εNd(t) values (–8.62 to –6.10) and low apatite εNd(t) values (–8.31 to –6.56), indicate that the Songxian–Ruyang A-type granites were derived from partial melting of the calc-alkaline tonalitic–trondhjemitic–granodioritic gneisses in Taihua Complex, and they were formed in post-collisional extensional setting. Combined with coeval regional granitoids, the south margin of the NCC is in a continuous extensional setting during 1.8–1.6 Ga, and the Songxian–Ruyang A-type granites can represent a response of the breakup of Columbia supercontinent.

Timing and Petrogenesis of the Permo-Carboniferous Larvik Plutonic Complex, Oslo Rift, Norway: New Insights from U–Pb, Lu-Hf, and O Isotopes in Zircon

Abstract The Permo-Carboniferous Oslo Rift is a narrow, aborted continental rift with comparatively little extension but voluminous magmatism, developed at a Proterozoic lithospheric discontinuity. On the southern flank of the onshore part of the rift, the multiple intrusive phase Larvik plutonic complex (LPC) encompasses almost the width of the rift with a conspicuous over- to undersaturated assemblage of monzonite (larvikite, tønsbergite) and nepheline syenite (lardalite, foyaite). We present new single-crystal U–Pb–, Lu–Hf–, and O–in–zircon isotope data for the intrusive centers of the complex. U–Pb ages of slightly over- to undersaturated monzonites show a shift in igneous activity from 299 Ma on the eastern edge of the complex to 289 Ma in the west. The western part of the complex is built of two consanguineous magmatic systems with a northward shift in the locus of magmatism, from 296 to 289 Ma (undersaturated monzonite) and 296 to ~288 Ma (nepheline syenite). Moreover, an early oversaturated monzonite was emplaced in the eastern part of the complex at ~302 Ma. The Hf and O isotope composition of the monzonites and nepheline syenites shows little variation with zircon εHf (295 Ma) values of +5.5 to +8 and δ18Ο values of +4.79‰ to +5.49‰. No change in isotope values is observed with varying alkalinity and the Hf and O isotope compositions are interpreted as mantle source values. The source of the precursors of the monzonitic and nepheline syenitic magmas was probably a mildly depleted, sublithospheric peridotite in the lithosphere-asthenosphere boundary zone (at 3–4 GPa). Rhyolite–MELTS modeling implies polybaric fractionation of weakly alkaline basaltic melts from the source having led to an oversaturated/saturated liquid line of descent at ~0.5 GPa and an undersaturated one at ~1 GPa. Magmatism had an imperative role in the evolution of the rift by localizing strain and weakening the lithosphere along the discontinuity. A fractionating crustal melt column was tapped at varying depths in the course of advancing rupturing with no significant mixing of the over- and undersaturated melts, and magma batches were emplaced as sequential nested plutons in response to differential opening of the rift. Among continental saturated-undersaturated alkaline complexes, the LPC may be unique in the emplacement of successive magma batches across a continental rift in the direction of opening, tapping of increasingly deeper parts of the melt column with advancing rifting, and intrusion of two contemporaneous, contrasting magmatic lineages at the end of igneous activity. The marked lithospheric step at the rift locus in the Precambrian basement of southeastern Norway was probably the driving force for the inception and evolution of the Larvik magmatic system.

Multiple episodes of early Precambrian magmatism and tectonism in the Tarim Craton: A North China connection

The accretion and recycling of Archean-Paleoproterozoic continental crust is the key to understanding the formation and evolution of early continental crust. Early Precambrian metamorphic basement is well developed in the Aktashtagh area, southeastern margin of the Tarim Craton, northwestern China. We report zircon SHRIMP UPb dating, LA-MC-ICP-MS LuHf isotopic analysis and whole-rock geochemical analysis on 16 samples (mainly TTG, tonalite-trondhjemite-granodiorite) from Aktashtagh. Multiple episodes of early Precambrain magmatism, including 3.72 Ga, 3.63 Ga, 3.10 Ga, 2.83–2.69 Ga, 2.55–2.50 Ga, 2.05–2.02 Ga and 1.93–1.82 Ga events, have been identified in the Aktashtagh region. The most intense magmatism occurred in the late Mesoarchean to early Neoarchean. Significantly, 3.63 Ga and 3.10 Ga TTG rocks are identified, together with more extensive 2.8–2.7 Ga and ∼ 2.5 Ga TTG rocks. The TTG suites are dominated by tonalitic, with some trondhjemitic and grandioritic rocks. They show large variations in REE contents, are mainly distributed in the high- and medium-pressure fields in the Sr/Y-Y and La/Yb-Yb diagrams, and the 2.7 Ga TTG rocks commonly show higher and more variable Sr/Y and La/Yb ratios. The 3.63–3.10 Ga TTG rocks have magmatic zircon εHf(t) values of −3.9 to +3.1 and tDM1(Hf) model ages of 3.9–3.6 Ga, whereas the ∼2.7–2.51 Ga TTG rocks have magmatic zircon εHf(t) values of −13.4 to +2.1 and tDM1(Hf) model ages of 3.3–3.0 Ga. The ∼2.7 to ∼2.0 Ga meta-gabbroic-dioritic rocks have magmatic zircon εHf(t) values of −19.7 to +0.6 and tDM1(Hf) model ages of 3.2–2.4 Ga. Metamorphic zircon ages of 3.56 Ga, 2.75–2.73 Ga, 2.53–2.51 Ga, 2.03–1.96 Ga and ∼ 1.85 Ga are also recorded, whereas ∼2.83 Ga, 2.53–2.40 Ga, 2.05–2.02 Ga and 1.86–1.83 Ga crustally-derived K-rich granites are identified, with the most important occurring in the late Neoarchean and late Paleoproterozoic. In this regard, the Tarim Craton is similar to the North China Craton in its early Precambrian geological evolution. The main difference is that the Paleoproterozoic tectonothermal event in the Tarim Craton started as early as 2.00 Ga, whereas in the North China Craton it occurred between 1.95 and 1.80 Ga.

Ca. 800 Ma I-type granites from the Hong’an Terrane, central China: New constraints on the mid-Neoproterozoic tectonic transition from convergence to extension in the northern margin of the Yangtze Block

The northern margin of the Yangtze Block was thought to have witnessed the tectonic shift from a compressional setting to an extensional setting at ca. 820 Ma, or to have remained as a subduction-related setting until ca. 700 Ma. Our new geochronological, isotopic, and geochemical data for the Daleishan granitic Pluton, which is the largest batholith in the Hong’an Terrane of the Qinling-Tongbai-Dabie Orogen, central China, provide new constraints on the Neoproterozoic magmatic and tectonic evolution of the Yangtze Block. Four representative samples from the Daleishan Pluton yield consistent zircon U–Pb ages within analytical errors of ca. 800 Ma. Samples from the pluton exhibit evolved compositions, including high SiO2 (71.53–77.05 wt%) and K2O (3.93–5.00 wt%) contents, low Zr/Hf (22–37) and Nb/Ta (7.9–16.4) ratios, enrichment in Rb, Th and U, and depletion in Ba, Sr, Eu, and Ti, with rare earth element tetrad effects in the chondrite-normalized element patterns. The studied samples have slightly elevated zircon δ18O values (+5.64 ‰ to + 7.11 ‰) relative to the mantle value but negative zircon εHf(t) (mostly of −12.0 to −5.5) and bulk rock εNd(t) (−9.6 to −7.9) values. Our new geochemical data classify the rocks as moderately to highly-fractionated I-type granite, rather than A-type granite as previously thought. These rocks may have been derived from the partial melting of mafic rocks in the region and the magma underwent fractional crystallization. Integrating the new and published data, we propose that the emplacement of the Daleishan Pluton was associated with the final stage of early Neoproterozoic oceanic-crust subduction along the northern margin of the Yangtze Block. Accordingly, a mid-Neoproterozoic tectonic transition from convergence to extension in response to the breakup of the Rodinia supercontinent may have occurred at 800–780 Ma.

Temperature and Hf-O isotope correlations of young erupted zircons from Tengchong (SE Tibet): Assimilation fractional crystallization during monotonic cooling

Young zircons from crystal-poor volcanic rocks provide the best samples for the investigations of pre-eruption magmatic processes and for testing a possible relationship between zircon Eu anomalies and crustal thickness. We report trace element chemistry and Hf-O isotope compositions of young zircons from 3 Holocene volcanoes in the Tengchong volcanic field, SE Tibet, in order to provide insights into magma evolution processes and conditions for high-K calc-alkaline volcanic rocks in a post-collisional setting. As decreasing zircon Ti content and falling temperature, zircon Hf content and Yb/Sm increase whereas zircon Eu anomaly and Th/U decrease, indicating fractional crystallization of plagioclase and zircon during magma cooling. More importantly, zircon Hf isotope ratio (εHf values) increases with decreasing zircon Ti content and falling temperature (T), suggesting gradually increasing incorporation of relatively high εHf juvenile materials in the crystallizing zircons during magma evolution. Negative correlations between zircon εHf and zircon δ18O also support open-system magma evolution. Our data suggest fractional crystallization of a magma with simultaneous contamination by high εHf and low δ 18O juvenile (immature) crustal materials during monotonic cooling after zircon saturation. The low-T, high-εHf and low- δ 18O zircons may indicate the involvement of the early Cretaceous juvenile granitic country rocks during shallow magma evolution. Average Eu anomalies in zircons from young Tengchong lavas yield crustal thickness of 40.7 ± 6.8 km, consistent with present crustal thickness (42.5 km) determined by geophysical methods.

Petrogenesis of the Triassic Sihaiping granite in the South Qinling orogen, central China: Implications for Mo-W mineralization

Late Triassic granites and related magmatic-hydrothermal Mo-W mineralization are common in the South Qinling orogen of central China, for which the Sihaiping granite pluton is a typical example. However, the petrogenesis of the Sihaiping granite remains enigmatic. Unraveling its petrogenesis can aid in our understanding of the Mo-W metallogeny in the South Qinling orogen. In this study, we present in situ zircon U-Pb ages, whole-rock geochemistry, and Sr-Nd-Hf isotopes of the Sihaiping granite. Zircon U-Pb dating by laser ablation inductively coupled plasma mass spectroscopy yielded Late Triassic ages of 206.6 ± 0.94, 206.5 ± 0.96, and 205.9 ± 0.75 Ma. The granite displayed high SiO2, K2O, and Rb contents, but low MgO, P2O5, TiO2, Sr, Ba, and Eu contents, indicating highly fractionated I-type granite affinity. The magma was interpreted to have been derived from Proterozoic crystalline basement in the South Qinling given its relatively low (87Sr/86Sr)i (0.704006 to 0.705039), negative εNd(t) (–4.9 to –3.5), and zircon εHf(t) (–6.2 to +1.6) values, with Nd model ages ranging from 1.39 to 1.27 Ga and two-stage Hf model ages ranging from 1.36 to 1.04 Ga. The strong fractional crystallization and suitable oxygen fugacity (ΔFMQ values mainly concentrated between +2 to +8) in the magmatic system played a major role in the Mo-W mineralization, indicating that the pluton has significant Mo(-W) metallogenic potential. Overall, the findings suggest that the Triassic Sihaiping granite and its related Mo-W mineralization likely formed in the transitional stage from syn- to post-collision between the South China Block and South Qinling along the Mianlue suture.

Lithospheric thinning and ignition of a Cordilleran magmatic flare-up: Geochemical and O-Hf isotopic constraints from Cretaceous plutons in southern Korea

Northeast Asian continental margins contain the products of magma emplacement driven by prolonged subduction of the (paleo-)Pacific plate. As observed in many Cordilleran arcs, magmatic evolution in this area was punctuated by high-volume pulses amid background periods. The present study investigates the early evolution of the Cretaceous magmatic flare-up using new and published geochronological, geochemical, and O-Hf isotope data from plutonic rocks in the southern Korean Peninsula. After a long (∼50 m.y.) magmatic hiatus and the development of the Honam Shear Zone through flat-slab subduction, the Cretaceous flare-up began with the intrusion of monzonites, granodiorites, and granites in the inboard Gyeonggi Massif and the intervening Okcheon Belt. Compared to Jurassic granitoids formed during the former flare-up, Albian (∼111 Ma) monzonites found in the Eopyeong area of the Okcheon Belt have distinctly higher zircon εHf(t) (−7.5 ± 1.3) and δ18O (7.78‰ ± 0.25‰) values and lower whole-rock La/Yb and Sr/Y ratios. The voluminous coeval granodiorite and granite plutons in the Gyeonggi Massif are further reduced in Sr/Y and to a lesser extent, in La/Yb, and have higher zircon εHf(t) values (−13 to −19) than the Precambrian basement (ca. −30). These chemical and isotopic features indicate that Early Cretaceous lithospheric thinning, most likely resulting from delamination of tectonically and magmatically overthickened lithospheric keel that was metasomatized during prior subduction episodes, and consequent asthenospheric upwelling played vital roles in igniting the magmatic flare-up. The O-Hf isotopic ranges of synmagmatic zircons from the Albian plutons and their Paleoproterozoic and Jurassic inheritance attest to the involvement of lithospheric mantle and crustal basement in magma generation during this decratonization event. Arc magmatism then migrated trenchward and culminated in the Late Cretaceous, yielding widespread granitoid rocks emplaced at shallow crustal levels. The early Late Cretaceous (94–85 Ma) granites now prevalent in Seoraksan-Woraksan-Sokrisan National Parks are highly silicic and display flat chondrite-normalized rare earth element patterns with deep Eu anomalies. Synmagmatic zircons in these granites mimic their host rock’s chemistry. Delamination-related rejuvenation of crustal protoliths is indicated by zircon εHf(t) values of granites (−6 to −20) that are consistently higher than the Precambrian basement value. Concomitant core-to-rim variation in zircon O-Hf isotopic compositions reflects a typical sequence of crustal assimilation and fresh input into the magma chamber.

Deformation Termination of the Kanggur Ductile Shear Zone in Eastern Tianshan, NW China: Insights from U-Pb Dating of Zircon and Apatite

The Kanggur ductile shear zone (KDSZ), located in the south margin of the Central Asia Orogenic Belt (CAOB), plays a critical role in the tectonic evolution and mineralization in eastern Tianshan. Although different isotopic chronologies have been reported, the termination of the KDSZ deformation remains controversial. Here, we provide new data obtained by U-Pb dating of zircon and apatite from Huangshandong synkinematic granite (HSG) and Huludong deformed granite (HDG) to constrain the termination of the KDSZ deformation. The U-Pb age of apatite from HSG (249.1 ± 1.8 Ma) is identical to that of zircon (256.5 ± 2.1 Ma) within the error range. In contrast, the U-Pb age of apatite from HDG (248.1 ± 4.0 Ma) is significantly younger than that of zircon (347.3 ± 2.5 Ma). The HDG and HDG have the geochemical characteristics of I-type granites petrogenesis, including high SiO2 (up to 75.47%), high alkaline (K2O + Na2O = 6.39%–8.05%), low FeOT/MgO (2.4–3.4), and peraluminous (A/CNK = 1.01–1.08). Combined with previous Sr-Nd isotope compositions, the positive zircon εHf(t) values and TDM2 ages indicate that the ca. 347 Ma HDG originated from the re-melting of juvenile crust crustal-derived magma in a volcanic arc environment during the northward subduction of the Kanggur oceanic basin, and the ca. 257 Ma HSG originated from the partial melting of thickened juvenile crust in a post-collisional environment. Although trace elements of zircon show typical magmatic characteristics, apatite does not. With the presence of distinct major and trace elements in apatite, the apatite from HSG is characterized by high Mn (>2500 ppm), slight enrichment in the middle rare earth elements (MREEs), and obvious negative Eu anomalies (δEu = 0.09–0.21), indicating that it is related to magmatic apatite. In contrast, the apatite from HDG, with low Mn (<860 ppm), depleted light rare earth elements (LREEs), and variable Eu anomalies (δEu = 0.30–1.34), demonstrated fluid metasomatism with metamorphic overprinting. Combined with the regional geology and published geochronology data, the HSG is interpreted to be derived from the magma experiencing cooling crystallization in the plastic state from 256.5 to 249.1 Ma, while the HDG is considered to have experienced metamorphism and deformation between 347.3 and 248.1 Ma. Owing to the relatively low closure temperature of the U-Pb isotopic system, the apatite U-Pb ages are interpreted as Early Triassic tectono-magmatism events, corresponding to the end of deformation of the KDSZ. This is inferred to be related to the continuous evolution of the Paleo-Asian Ocean in the Late Permian to Early Triassic.

Episodic mafic dike swarms (2.0 and 1.7 Ga) in the Quadrilátero Ferrífero Province, Brazil: Implications for the refinement of the São Francisco Craton magmatic barcode and the North China link

Late Archean to Paleoproterozoic dike swarms crosscut the basement and supracrustal sequences of the São Francisco Craton. Their spatial distribution and orientation patterns, as paleomagnetic signature, provide key evidence to the positioning of the cratonic area in ancient paleocontinental reconstructions through the refinement of the “magmatic barcode”. Zircon U–Pb data from dikes in the cratonic domain of the Quadrilátero Ferrífero Mineral Province, in the southern of São Francisco Craton, allowed the recognition of two magmatic stages: a Rhyacian-Orosirian pulse, belonging to the Paraopeba swarm, and a Statherian pulse that belongs to the Pará de Minas II swarm. The Ediacaran Brasiliano Orogeny later affected dikes from both swarms.The Paraopeba swarm consists of pulses related to the Rhyacian-Orosirian orogenic cycle, with dikes providing U–Pb zircon ages of 2019 + 23–11, 1944 ± 29 and 1918 ± 12 Ma. The zircon εHf values from these dikes are predominantly negative, suggesting reworking of preexisting crust, whereas the TDM ages vary from 4000 to 2500 Ma, which can be interpreted as a long period of crustal residence. The Statherian Pará de Minas II swarm, with a U–Pb zircon age of 1717 ± 9 Ma, is chronocorrelated to the lower stratigraphic sequence of the Espinhaço rift basin. Zircon grains from this dike have predominantly positive εHf values and TDM model ages between 3050 and 1950 Ma. Unlike the Paraopeba swarm, the Pará de Minas magmatism is marked by a striking input of juvenile mantle material with minor crustal contamination. The Ediacaran Brasiliano tectono-thermal event caused isotopic disturbance in both Paraopeba and Pará de Minas II swarms, resulting in lower intercepts at 595 ± 65 and 584 ± 27 Ma, respectively.Our data pinpoint dike emplacement related to tectonic events described in the southern of São Francisco. In the final stages of Rhyacian orogenic cycle, at ca. 2019–1918 Ma, data suggests an important crustal contamination. Thereafter, a crustal rifting event at ca. 1717 Ma involved dike swarm emplacement with magmatic source from a mantle plume. The Rhyacian-Orosirian ages obtained here are the first zircon U–Pb geochronological data presented for the Paraopeba dike swarm and allow for a refinement of the São Francisco Craton barcode, reinforcing previous suggestions of proximity with the North China Craton crosscut by the similarly aged Hengshan and Xiwangshan/Xuwujia dike swarms, whether or not those two cratonic pieces were part of the Columbia supercontinent.

Origin and Geodynamic Mechanism of the Tibetan Demingding Porphyry Mo (Cu) Deposit from Oceanic Subduction to Continental Collision

Demingding is a promising porphyry Mo-dominated deposit recently discovered in the eastern Gangdese metallogenic belt in Tibet, China. We present zircon U-Pb-Lu-Hf isotopic studies, as well as geochemical data of the late monzogranites and the prior rhyolites from the Demingding porphyry deposit to uncover their origin and geodynamic mechanism. Zircon U–Pb dating yielded precise crystallization ages of 17.3 ± 0.6 Ma (MSWD = 2.5) and 186.5 ± 3.0 Ma (MSWD = 2.0) for monzogranite and rhyolite, respectively. The monzogranite is characterized by high-K calc-alkaline, adakitic affinities, and positive zircon εHf(t) values (+0.9∼+5.6, avg.+3.1) with TDM2 (0.73–1.04 Ga), while the rhyolite has εHf(t) values of (+2.1∼+7.3, avg.+5.2) and TDM2 of (0.76–1.09 Ga) similar to the monzogranite. Our results suggest that the Demingding porphyry Mo (Cu) deposit is related to magma generated from the Neo-Tethyan oceanic subduction. The subsequent monzogranite porphyry was likely formed by the remelting of previously subduction-modified arc lithosphere, triggered by continental collision crustal thickening in Miocene. The lower positive εHf(t) values of monzogranites suggest minor inputs from the Mo-rich ancient crust, suggesting that Mo favors the silicate melt. Such magmatic events and special metallogenesis typify intracontinental processes and porphyry copper deposits, which are normally confined to oceanic subduction and Cu-dominated style, thereby making the continental setting and Mo-dominated style of Demingding exceptional and possibly unique.

Petrogenesis of Early Permian Intrusive Rocks from Southeastern Inner Mongolia, China: Constraints on the Tectonic Framework of the Southeastern Central Asian Orogenic Belt

AbstractThe late Paleozoic tectonic framework of the southeastern Central Asian Orogenic Belt is key to restricting the accretion orogeny between the Siberia Craton and the North China Craton. To clarify the framework, petrogenesis of early Permian intrusive rocks from southeastern Inner Mongolia was studied. Zircon U‐Pb dating for bojite and syenogranite from Ar‐Horqin indicate that they were emplaced at 288–285 Ma. Geochemical data reveal that the bojite is highly magnesian and low‐K to middle‐K calc‐alkaline, with E‐MORB‐type REE and IAB‐like trace element patterns. The syenogranite is a middle‐K calc‐alkaline fractionated A‐type granite and shows oceanic‐arc‐like trace element patterns, with depleted Sr‐Nd‐Hf isotopes, (87Sr/86Sr)I = 0.7032–0.7042, εNd(t) = +4.0 to +6.6 and zircon εHf(t) = +11.14 to +14.99. This suggests that the bojite was derived from lithospheric mantle metasomatized by subducted slab melt, while the syenogranite originated from very juvenile arc‐related lower crust. Usng data from coeval magmatic rocks from Linxi–Ar‐Horqin, the Ar‐Horqin intra‐oceanic arc was reconstructed, i.e., initial transition in 290–280 Ma and mature after 278 Ma. Combined with regional geological and geophysical materials in southeastern Inner Mongolia, an early Permian tectonic framework as ‘one narrow ocean basin of the PAO’, ‘two continental marginal arcs on its northern and southern’ and ‘one intra‐oceanic arc in its southern’ is proposed.

Subducted Front of the Indian Continental Crust Beneath the Tibetan Plateau in the Early Eocene

AbstractThe immense Tibetan Plateau is a masterpiece of the ongoing India–Asia collision. The timing of the collision is a critical parameter to reconstruct the plateau evolution, but has been not well understood yet. Here, we report a newly discovered Eocene (53.8 Ma) shoshonitic intrusion with the input of Indian continental material in the Yangbajing area of the Lhasa Terrane, south Tibet. The reverse 207Pb/206Pb zoning exhibited by feldspars, the linear isotopic arrays between whole‐rock 187Os/188Os and 1/188Os, the in‐situ feldspar 208Pb/204Pb and 206Pb/204Pb values, and the in‐situ zircon εHf(t) values and δ18O values strongly demonstrate a binary interaction process for the generation of the Yangbajing shoshonitic intrusion. Our Os isotopes further illustrate that the interaction process was dominated by recycled crustal melt assimilating minor mantle melt. In addition, different isotopic systems consistently point to an end‐member represented by the underthrust crust slice of Indian continent, which indicates that the Indian lithosphere must have already subducted beneath the Lhasa Terrane at 53.8 Ma. This is also supported by the abrupt isotopic shift toward the enriched values and the composition variation toward the high potassium contents in the subsequent Tibetan magmatism, corresponding to an increasing involvement of the Indian continental crust into the upper plate magmatism. Therefore, the Yangbajing shoshonitic intrusion is one of the earliest known magmatic evidence for the onset of the India–Asia collision.

Crust–mantle interactions in Zijinshan ore field identified by zircon SIMS U–Pb age and zircon Hf–O isotopes

AbstractThis study presents zircon U–Pb geochronology and Hf and O isotope data for granitic rocks in the Zijinshan ore field, southwestern Fujian Province, China. The intrusive rocks comprise monzogranite, granite and granodiorite. The magmatic zircon U–Pb ages from these granitic rocks can be divided into four episodes: episodes 1 (157.9–159.9 Ma) and 2 (141 Ma) in the Late Jurassic and episodes 3 (108.1–103.2 Ma) and 4 (97.5–99.7 Ma) in the Middle and Late Cretaceous, respectively. Patterns of rare-earth elements (REE) show enrichment in light REE and obvious negative Eu anomalies. These rocks are also enriched in Rb, Th, U, La, Ce, Nd and Hf, and depleted in Ba, Nb, Sr, P and Ti. The increasing La/Yb ratio and decreasing heavy REE content with decreasing age may imply an increasing contribution of mantle-derived materials from the Late Jurassic to Cretaceous. The zircon ϵHf(t) and δ18O values, ranging from −37.7 to −2.8 and 12.0 ‰ to 6.3 ‰, respectively, indicate that the lower crust is an important source of granitic rocks. There was a significant increase in ϵHf(t) values and a decrease in δ18O values in the younger magmatic episodes (3 and 4), which ranged from −11.4 to −0.6 and 10.7 to 6.3 ‰, respectively. This suggests an increasing contribution of mantle-derived magma to the crustal melts from the Late Jurassic to late Early Cretaceous in response to the changing regional tectonic setting from compression to extension and an increasing interaction between the crust and mantle.

Tectonic switch of the north Yangtze Craton at ca. 2.0 Ga: Implications for its position in Columbia supercontinent

Two episodes of magmatism with zircon U-Pb ages of 2.46 Ga and 2.0 Ga were studied in the Jinpan Complex in the north Yangtze Craton of South China. The ca. 2.46 Ga gneissic granites with various chemical compositions were formed by remelting of different crustal materials in a collisional event. The occurrence of both negative and positive whole-rock εNd(t) and εHf(t) values in these rocks indicates the growth of juvenile crust and reworking of Archean crust during early Paleoproterozoic. The ca. 2.0 Ga trondhjemites have high (La/Yb)N and Sr/Y ratios as well as negative whole-rock εNd(t), εHf(t) and zircon εHf(t) values, suggesting that they were formed by remelting of thickened lower crust in a collisional orogen. The ca. 2.0 Ga A-type granites have high Zr, Nb, Y contents and Ga/Al, Y/Nb ratios, belonging to A2 type granite. Their negative whole-rock εNd(t), εHf(t) and zircon εHf(t) values are similar to those of the ca. 2.0 Ga trondhjemites. These evidences suggest that they were produced by remelting of the residue after extraction of earlier granitic magma in an extensional tectonic setting. The 2.0 Ga mafic dykes show significant enrichment in LILEs but weak negative Nb, Ta anomalies and various Nb/U ratios. This is consistent with a parent magma similar to continental flood basalts and experienced different degrees of crust contamination. The co-occurrence of 2.0 Ga trondhjemites, A-type granites and mafic dykes implies a tectonic switch from convergence to extension at ca. 2.0 Ga in the north Yangtze Craton. Based on the similarities of the ca. 2.0 Ga magmatic rock association and metamorphic records in the north Yangtze Craton and south Siberia, the position of the Yangtze Craton in Columbia supercontinent is proposed to be close to south Siberia.

Late Permian-Triassic ridge subduction beneath the northeastern margin of the North China Craton: Evidence from the Kaiyuan appinitic to high-Mg intermediate intrusions in northern Liaoning, North China

Recognizing terminal ridge subduction is of first-order importance in chronicling the tectonic timeline of any accretionary orogens, but remains elusive in the final suturing zone of the Paleo-Asian Ocean along the Solonker−Xar Moron−Changchun−Yanji swath. Here we report two generations of ultramafic-mafic to intermediate intrusions from northern Liaoning, North China, linking eastern Central Asian Orogenic Belt and northern North China Craton. The ca. 259 Ma appinites show variable enrichment in large-ion lithophile elements (LILEs) but depletion in high-field strength elements (HFSEs), and variably enriched isotopic compositions with εNd(t) of −11.8 to −2.4 and zircon εHf(t) of −15.7 to +5.0. These petro-geochemical traits argue for their derivation from partial melting of subduction-modified lithospheric mantle. By contrast, the high-Mg diorites of 226−223 Ma display decoupling features between LILEs and HFSEs and juvenile isotopic signatures with εNd(t) of −0.3 to +2.6 and zircon εHf(t) of +5.4 to +11.4. These characters are consistent with a magmatic origin from partial fusion of sediment-fertilized asthenospheric mantle. Synthesizing the two mantle-melting events with regional coeval igneous activities leads to the identification of Late Permian (265−250 Ma) and Middle-Late Triassic (241−218 Ma) magmatic flare-ups with a 10−15 m.y. lull along the northern North China Craton. This magmatic tempo tends to record a salient mantle replacement from hydrous metasomatized lithosphere to anhydrous asthenosphere. In combination with ensuing progressive crustal growth, simultaneous metamorphism, and structural activities, these diverse manifestations make a compelling case of ridge subduction and concomitant slab window formation during the eventual closure of the Paleo-Asian Ocean along the Solonker−Xar Moron−Changchun−Yanji swath.

Early Eocene A-type (ferroan) rhyolites in southwestern Tibet: A far-field tectonic effect of the India–Eurasia collision

ABSTRACT Eocene igneous rocks along the Gangdese belt in southern Tibetan Plateau are important for understanding the India–Eurasia collision and Tibetan Plateau uplift. These magmatic rocks are widely considered to be related to roll-back or break-off of the Neotethyan slab during northward subduction. However, Eocene rhyolites in the northwestern Gangdese belt (SW Qiangtang margin) do not fit either the rollback or breakoff models. This paper investigates these Early Eocene lavas and compares them with contemporaneous igneous rocks along the Gangdese belt via detailed field observations, petrology, zircon geochronology, zircon Lu–Hf isotopes and whole-rock geochemistry. These felsic lavas form large outcrops in western Tibet and have two zircon U–Pb ages of 54.71 ± 0.14 Ma and 54.74 ± 0.27 Ma. They have high SiO2 and alkali contents, FeO*/MgO, and Ga/Al ratios as well as strongly negative Eu anomalies and slightly positive zircon εHf(t) values (+2.5 to +4.4). Both Ti-in-zircon and Zr saturation thermometers confirm high magmatic temperatures (~900°C). They are ferroan, A-type rhyolites. Furthermore, the distinctive low εHf(t) values imply that these rhyolites are likely partial melting products of the southwestern Qiangtang Terrane. The lithosphere in this region undergone long-term shortening and thickening since 80–95 Ma. Pre-thickened lithosphere may be a prerequisite for the Early Eocene delamination, and the simultaneous inducement is a far-field tectonic effect from the India–Eurasia collision. We suggest that: (1) India collided with Eurasia before 55 Ma and triggered delamination to form the Shiquanhe A-type rhyolites on the southwestern Qiangtang margin thereafter; and (2) tectonic stresses related to India–Eurasia collision during the Eocene were transmitted efficiently over large distances.

U-Pb zircon LA-ICP-MS and Hf composition in granitogneiss of Chu Lai body and its implication of the Kontum massif, central Vietnam

The Chu Lai granitogneiss is widespread throught the Northern Kontum massif. The Chu Lai body is located in the W-SW of the Nui Thanh Townlet (Nui Thanh Dists., Quang Nam Prov.). On an areas of ~ 300 km2. The Chu Lai intrusion mainly consists two mica gneiss, it is light grey and have porphyritic textures. Its major minerals include plagioclase (25÷40%), K-feldpar (20÷40%), quartz (25÷35%), biotite (5÷13%) and mustcovite (0÷6%). Accessory minerals are apatite, zircon, orthit. Garnet and tourmaline are occiasionally found. Zircons separated from a granitogneiss sample colleted in Chu Lai body are generally euhedral to subhedral, dark gray and prissmatic in shape with 100÷300 µm, with length/witdth ratios from 1:1÷1:3. There are many Neoproterozoic - Cambrian ages among the zircon cores in the Chu Lai samples, and these are regarded as inherited zircons. The LA-ICP-MS zircon age is 431 Ma, corresponding to the Silurian. The Chu Lai granitogneiss strongly negative zircon εHf (-4.2÷-11.4) and complex inherited zircon components, characteristics of typical S-type granite. Hf model ages TDM2 1.5÷1.9 Ga, suggests that the Chu Lai granitogneiss was derived from partial melting of old crustal basement rocks, probaly Paleoproterozoic in age.

Tectonic affinity of the Zhusileng–Hangwula Belt in the northern Alxa area: Evidence from the zircon U–Pb ages and Hf isotopic compositions of the Mesoproterozoic (~1.4 Ga) igneous rocks

Precambrian rocks are necessary to understand the tectonic and crustal evolution of the Central Asian Orogenic Belt, especially the tectonic affinities of embedded microcontinents. We conducted a combined analysis of whole‐rock geochemistry, zircon U–Pb geochronology, and Hf isotope on the Mesoproterozoic igneous rocks from the Zhusileng–Hangwula Belt of the northern Alxa area to investigate its tectonic affinity. The zircon ages show that the gneissic granites, metagabbro, and amphibolite formed at 1,433–1,424 Ma, 1,383, and 1,373 Ma, respectively. Furthermore, zircon xenocrysts from the rhyolite in the Zhusileng area exhibit a206Pb/238U ages cluster at about 1.4 Ga. Geochemically, the gneissic granites are high‐potassium calc‐alkaline granitoids and exhibit light rare earth element‐enriched pattern, pronounced significant negative Eu anomalies, negative Nb–Ta anomalies, positiveεHf(t) values (3.2–11.3), and young two‐stage model ages (2.21–1.46 Ga), indicating that they were derived from a magma source of rapid reworking of juvenile mantle‐derived materials with a limited ancient crustal contamination. The FeOT, CaOm and MgO contents of mategabbros and amphibolite are high, but their total rare earth elements are relatively low (TREE = 31.45–32.74). They are characterized by relatively positive zirconεHf(t) values (5.3–11.0), and very young two‐stage model ages (1.98–1.49 Ga), indicating that they were generated from the depleted mantle. Our geochemical data suggest that these Mesoproterozoic rocks in the Zhusileng–Hangwula Belt are consistent with the formation period and tectonic environment of juvenile basement rocks from the Central Tianshan Arc and southern Beishan Orogenic Belt, whereas a Mesoproterozoic correlation with the Tarim Craton is highly unlikely. Thus, we believe that the Zhusileng–Hangwula Belt has an analogous tectonic evolution and a close affinity with the Central Tianshan Arc and southern Beishan Orogenic Belt during the Mesoproterozoic.