Zircon eHf Research Articles

Eocene (∼ 53 Ma) alkaline complex in the southern Lhasa subterrane, Tibet: Implications for Neo-Tethyan slab breakoff

The Eocene alkaline magmatism in the southern Lhasa subterrane provides insights into the timing and dynamic mechanism of the Neo-Tethyan oceanic slab breakoff. Here, we present a combined study of whole-rock geochemistry, zircon U–Pb ages and Sr–Nd–Hf isotopes for the Mayum alkaline complex in the southern Lhasa subterrane. The complex is composed of amphibole syenites, quartz syenite, alkali feldspar granites and mafic microgranular enclaves (MMEs) in the host quartz syenites. Their crystallization ages are 52.2 ± 0.8 Ma, 52.2 ± 1.0 Ma, 49.6 ± 0.5 Ma and 53.1 ± 1.6 Ma, respectively, indicating that these rocks were simultaneously generated in the early Eocene. The hosted alkaline rocks are shoshonic with high SiO2 (64.32–70.49 wt.%), Na2O+K2O (6.63–9.43 wt.%) and low MgO (0.57–2.47 wt.%) contents. They are enriched in large-ion lithophile elements (LILEs: e.g., Rb, K), light rare earth elements (LREEs), Th and U, and are depleted in high field-strength elements (HFSEs) (such as Nb, Ta, and Ti) with strongly negative Eu anomalies (Eu/Eu* = 0.33–0.75). They have homogeneous whole-rock (87Sr/86Sr)i ratios (0.7051–0.7056), low εNd(t) values (–1.7 to –0.9), and positive zircon εHf(t) values (+1.69 to +7.72). Thus, the host alkaline rocks were generated from partial melting of the juvenile lower crust under the southern Lhasa subterrane, and went through a fractional crystallization process during magma ascending emplacement. Compared with the host alkaline complex, the MMEs have lower SiO2 contents (55.16–63.67 wt.%), very higher Fe2O3T (4.08–6.58 wt.%) contents with variable Cr (3.45–226.00 ppm), V (46–107 ppm) and Ni (2.66–6.16 ppm) contents. Meanwhile, the MMEs have similar patterns in trace and rare earth elements (such as obviously Eu anomalies, Eu/Eu* = 0.24–0.38) and similar whole-rock Sr-Nd isotopes ((87Sr/86Sr)i = 0.7051–0.7056, εNd(t) = –2.1 to –1.4) with the host alkaline rocks. Thus, the MMEs might be derived from a mantle source, and magma mixing occurred between the MMEs and the host alkaline rocks. The Mayum alkaline rocks and associated MMEs were generated under an extensional tectonic setting related to the Neo-Tethyan oceanic slab breakoff at ca. 53 Ma.

Petrogenesis of two Cretaceous granitoid episodes in the Luk Ulo region, Central Java, Indonesia, and its implication for the tectonic evolution of the easternmost Neo-Tethys

The central part of Java, Indonesia, is located on the southern margin of Sundaland, and records the tectonic-magmatic history of the easternmost Neo-Tethys. Elucidating the petrogenesis and its tectonic setting of the Cretaceous Luk Ulo granites in Central Java is key to reconstructing the late subduction-accretion history of the easternmost Neo-Tethys. This study reports for the first time the zircon U-Pb geochronology, Hf-O isotope, whole-rock major and trace elements, and Sr-Nd isotope geochemistry of two granitoid episodes from Central Java. Zircon U-Pb dating results show that the Luk Ulo granites formed in two Cretaceous episodes at ca. 115 Ma and ca. 70 Ma. These two Cretaceous granitoid episodes contain both calc-alkaline with enriched large-ion lithophile elements and light rare earth elements and depleted high field strength elements, exhibiting arc geochemical signatures. The older (ca. 115 Ma) granites show slightly higher (87Sr/86Sr)i values of 0.70772 to 0.70784 and weakly negative εNd(t) values of −2.37 to −1.67, indicating the contribution of ancient crust. However, the scattered zircon εHf(t) values of +0.23 to +11.39 suggest a probable mixture of ancient crustal components and juvenile crustal additions in the magma source. The high zircon δ18O values (+8.86‰ to +14.24‰) show the possible incorporation of supracrustal components (sediments and fluids) in the magma formation. In contrast, the younger (ca. 70 Ma) granites show low (87Sr/86Sr)i values of 0.70427−0.70442, strong positive εNd(t) values of +3.89 to +4.03, and zircon εHf(t) values of +14.04 to +17.38 and slightly higher zircon δ18O values of +5.01‰ to +6.49‰ than the depleted mantle, indicating that the magma was predominantly derived from the juvenile crust with negligible supracrustal involvement. In general, zircon εHf(t) values and whole-rock εNd(t) values of the Late Cretaceous (after ca. 90 Ma) granitic rocks in the southwest margin of Sundaland were higher than those of the Early Cretaceous granitoids, suggesting a change in the source region from ancient to the juvenile in response to the rollback of the Neo-Tethys ocean. Our findings from the two Cretaceous granitoid episodes in Central Java provide new insights into the tectono-magmatic evolution along the southwestern margin of Sundaland and the two different episodes of crustal growth in the easternmost Tethys during the Cretaceous.

Tectonic transition during the Jurassic-Cretaceous in the Jiaodong Peninsula, North China: insights from asynchronous adakitic and A-type granitic plutons

ABSTRACT Jurassic-Cretaceous magmatic rocks are widely distributed in the Jiaodong area, North China. These magmatic rocks are closely associated with gold deposits, but their petrogenesis and geodynamic background are still controversial. The Late Jurassic-Early Cretaceous granitic rocks exposed in the Guocheng area, Jiaodong Peninsula are the focus of this paper. Zircon U-Pb dating, Hf-O isotope and whole rock geochemical analysis are used to determine the petrogenesis of these rocks. Combined with previous data, the geodynamic processes of granite formation in different time intervals are investigated which provide new petrological evidence for understanding the magmatic-mineralization and tectonic background of the Jiaodong area. Samples were collected from the Queshan and Shazibu plutons. The Queshan pluton is a mylonite granite, one sample of which yields a 206U-238Pb zircon age of 156 Ma, while the Shazibu pluton is a quartz monzonite, one sample of which records a 206U-238Pb zircon age of 117 Ma. The two plutons have variable zircon Hf-O isotopic compositions: zircon εHf(t) values of the Queshan pluton are −29.2 to −22.8, and δ18O values are 7.30–7.84 ‰, while the Shazibu pluton has relatively high zircon εHf(t) values (−21.6 to −21.0) and δ18O values of 7.48–8.43 ‰. Whole-rock geochemical data shows that the Queshan pluton has high Sr/Y (60.7–169) and (La/Yb)N (34.6–65.9) values and low Y (3.11–10.3 ppm) and Yb (0.29–0.85 ppm) contents, akin to adakites, whereas granites of the Shazibu pluton are A-type with high Zr+Nb+Ce+Y contents (354–420 ppm) and zircon saturation temperatures (752–795°C). Based on the geochemical and isotopic data, the Late Jurassic Queshan pluton is the product of partial melting of thickened lower crust of the North China Block, while the Early Cretaceous Shazibu pluton formed via fractional crystallization of mafic rocks derived from partial melting of the lower crust of the North China Block. Although both plutons were derived from the lower crust of the North China Block, the nature of the lower crust was modified by involvement of more depleted mantle-derived materials during the Early Cretaceous. From the Late Jurassic to the Early Cretaceous, the rock types (from the adakite to A-type granite) and the nature of the magma source suggest a shift in geodynamic processes. Combined with previous research, the Late Jurassic Queshan pluton is proposed to have formed under low-angle subduction of the ancient Pacific Plate, while the Early Cretaceous Shazibu pluton formed subsequently during Pacific Plate rollback and extension. The Early Cretaceous transformation of tectonomagmatic environments provided favourable conditions for the formation of large-scale gold deposits in the Jiaodong region.

Late Neoarchean charnockite in Daqingshan terrane, North China Craton: petrogenesis and implications for continental crustal evolution

ABSTRACT Modern analogues of Archaean charnockite are important because they facilitate investigations into processes of early crustal formation and tectonic transition. Herein, we present the results of the petrography, geochemistry, and isotope geochronology of Late Neoarchean charnockites in the Daqingshan terrane at the northern margin of the North China Craton. The sources, petrogenesis, and tectonic implications of the samples obtained are determined based on their geochemical characteristics. Charnockites mainly exhibit magnesian and calc–alkaline characteristics; furthermore, they contain high amounts of light rare-earth elements, with slightly positive Eu anomalies. Analysis of zircon U–Pb dating using a sensitive high-resolution ion microprobe reveals that Hademengou–Xiwulanbulang (HDMG–XWLBL) charnockites were emplaced during the (i) Late Neoarchean (ca. 2500 Ma), with zircon εHf(t) values ranging from 1.57 to 7.81; (ii) single-stage model ages (TDM1) from 2529 to 2637 Ma; and (iii) two-stage model ages (TDM2) from 2710 to 2820 Ma. A comparative study has performed on the petrography, geochemistry, and geochronology of charnockite and granulite shown that the parent magma of the charnockites is the product of the partial melting of granulite. Combining our results with geological data pertaining to the Archaean structural evolution of the Daqingshan terrane, we speculate that the Late Neoarchean HDMG–XWLBL charnockite was formed during a subduction-related thermo-tectonic event in the northern margin of the North China Craton.

Development of a back-arc basin from initial rifting to seafloor spreading: Constraints from Paleozoic basic rocks in the North Qinling accretionary orogen, central China

The progression from initial back-arc rifting to back-arc opening in ancient orogenic collages is important for reconstructing subduction histories, constraining tectonic switching, and understanding crustal growth and evolution. However, it is difficult to constrain this transition in ancient arcs. The Qinling-Dabie orogenic belt is one of the most important orogenic belts in eastern Asia, yet the history of Paleozoic accretionary processes in this belt remains equivocal, owing to a poor understanding of back-arc opening processes in the Erlangping unit. In this study, we present whole-rock geochemical analyses of mafic dikes in the Erlangping unit, along with U-Pb ages and Hf-O isotope compositions of zircon from these dikes. Zircon secondary ion mass spectrometry (SIMS) dating of these mafic dikes yielded U-Pb ages of 453 ± 3 Ma. The mafic dikes are calc-alkaline and are characterized by high K2O contents (1.16−3.16 wt%). They have enriched ([La/Yb]N = 4.3−14.9) light rare earth elements (REEs) and relatively flat heavy REE ([Dy/Yb]N = 0.9−1.5) patterns, and they exhibit enrichment in large ion lithophile elements (LILEs) but depletion in high field strength elements (HFSEs), resembling arc-like magmatism. These mafic dikes are characterized by relatively enriched initial 87Sr/86Sr (0.7049−0.7059), chondritic to slightly radiogenic εNd(t) (−0.36 to 1.33), and radiogenic whole-rock and zircon εHf(t) (+7.2−7.6 and +7.5−7.8, respectively). The zircons have δ18O values (5.0‰ ± 0.1‰) similar to those of normal mantle zircon. Accordingly, we interpret that the mafic dikes were derived from an enriched lithospheric mantle source metasomatized by subducted Proto-Tethys (Shangdan) ocean material. In contrast, previously reported ca. 440 Ma gabbros from the Erlangping unit are tholeiitic and have lower incompatible trace-element concentrations with less enrichment in LILEs and less depletion in HFSEs than the mafic dikes presented here. Whole-rock Nd and zircon Hf isotopic compositions suggest that these Silurian gabbros were derived from partial melting of a more depleted mantle with the involvement of asthenosphere, and they have a close geochemical affinity with back-arc basin basalts. In addition, trace-element ratios and geochemical modeling suggest higher melting pressures for the mafic dikes than the gabbros. The geochemical differences show systematic variations from island-arc basalt into back-arc basin basalt types, which is consistent with the magma source evolution of the Mariana Trough. Thus, we interpret that the ca. 454 Ma mafic dikes were emplaced when the infant arc split, and they record initial back-arc rifting in the Erlangping unit, whereas the Silurian gabbros subsequently formed during the opening of the back-arc basin. Our study provides a paradigm for deciphering the evolution of back-arc basins through the study of spatiotemporal geological and geochemical variations of mafic intrusions in ancient accretionary orogens.

Early Cretaceous magmatism in Yunnan traces the tectonic transition from the Tengchong-Baoshan continental collision to Neo-Tethyan slab rollback

Early Cretaceous magmatic rocks of the Tengchong and Baoshan blocks provide insight into the late Mesozoic evolution of southeastern Tibet—Yunnan. We present LA-ICP-MS U-Pb zircon age, zircon εHf(t) isotope, and whole-rock geochemical and Sr-Nd isotopic data for dioritic porphyrite and rhyolite, outcropping in the Eastern Tengchong Belt and the Gaoligong Belt, respectively. The dioritic porphyrite has a 123.0 ± 1.3 Ma (2σ) age, negative whole-rock ℇNd(t) of −1.99 to −2.16, initial 87Sr/86Sr of 0.70690–0.70734, zircon ℇHf(t) of −1.42 to 4.11, and adakitic geochemical features, suggesting an origin from mixing of mantle- and crust-derived magmas; the rhyolite has a 122.2 ± 1.0 Ma age, low whole-rock ℇNd(t) of −9.69 to −8.83, initial 87Sr/86Sr of 0.71104–0.71246, and zircon ℇHf(t) of −8.55 to −2.59, suggesting crustal derivation. Our data—along with the published data—suggest that the Early Cretaceous rocks (140–109 Ma) comprise two magmatic phases with a geochemical and isotopic transition at ∼123 Ma. The 140–123 Ma phase—mainly outcropping in the Gaoligong Belt—is mainly peraluminous, highly silicic, and has negative zircon εHf(t) values, suggesting derivation from remelting of ancient crust in a postcollisional setting; the 123–109 Ma phase is mainly metaluminous, restricted to the Eastern Tengchong Belt, and formed in a continental-arc setting with mantle melt involved. We propose that the ∼123 Ma geochemical and isotopic change marks the transition from contraction due to the Tengchong-Baoshan collision to extension resulting from slab rollback of the Neo-Tethyan lithospheric slab.

Early Jurassic lithospheric delamination in the Amdo microcontinent, central Tibet: Inferred from coeval OIB- and MORB-like gabbros

The Bangong–Nujiang suture zone (BNSZ) is the remnants of the Meso-Tethyan main oceanic basin in the Tibetan plateau. It is noted that several microcontinents, e.g., Amdo and Jiayuqiao, occur within the Meso-Tethyan ocean basin. These microcontinents were strongly reworked associated with the subduction and closure of this ancient ocean, thus they play a key role in understanding the evolution of this ocean. In this contribution, we report newly documented Early Jurassic gabbros (ca. 182–175 Ma) from the Amdo microcontinent in the middle segment of the BNSZ. The gabbros can be subdivided into two groups, i.e., OIB (ocean island basalt) and MORB (mid-ocean ridge basalt) groups. The OIB-group gabbros are characterized by highly enriched NdHf isotopic characteristics (zircon εHf(t) = −11.7 to −8.9; whole-rock εNd(t) = −11.0 to −10.1). They are geochemically similar to OIB and are interpreted to be products of the partial melting of a relatively deep mantle source (> 85 km) and subsequent continental crustal inputting. The MORB-group gabbros belong to the tholeiitic series and have similar compositions to those of MORB. They were most likely derived from a depleted mantle source (zircon εHf(t) = +3.7 to +16.5; whole-rock εNd(t) = +4.9 to +8.1) in a relatively shallow depth (< 85 km). Integrating previous studies with the data presented in this contribution, we suggest that the generation of coeval OIB- and MORB-like gabbros are related to lithospheric delamination after the Qiangtang-Amdo collision and the closure of the Bangong-Nujiang ocean basin. This result will give new constraint on the evolution of the Meso-Tethyan Ocean.

Characteristics of early Paleozoic granite-pegmatite and associated lithium-beryllium mineralization in the Tugeman area, Altun orogenic system, northwestern China

The Altun Orogenic Belt (AOB) is located on the northern margin of the Tibetan Plateau. We report the petrography, zircon U-Pb ages, Hf isotopic compositions, and whole-rock geochemistry of the Tugeman pegmatitic and granitic rocks from the AOB to constrain their petrogenesis and tectonic setting. Zircon U-Pb dating of the pegmatitic and granitic rocks yielded ages of 500–440 Ma, which we interpret as the emplacement ages of the granites and formation age of pegmatite. The granites are weakly peraluminous to peraluminous (A/CNK = 1.01–1.26), and they have high SiO2 (63.9–74.2 wt%) and Al2O3 (13.7–17.6 wt%) and low CaO (0.72–3.80 wt%) and P2O5 (0.06–0.44 wt%) contents. They show marked depletion in HREEs, enrichment in LREEs, and pronounced negative Eu anomalies, and they are enriched in Th, U, K, Pb, Nd, and Sm and depleted in Ba, Nb, Ce, Sr, P, and Ti. Zircon εHf(t) values vary from − 12.0 to + 3.3, with two-stage Hf model ages of 2.2–1.2 Ga, implying that the granites were derived mainly from ancient crust with a minor contribution from juvenile crust. Weakly peraluminous pegmatitic rocks have geochemistry characters of SiO2 (74.4–79.9 wt%) and Al2O3 (12.3–14.9 wt%) and low CaO (0.08–0.69 wt%) and P2O5 (0.05–0.33 wt%), depletion in HREEs, enrichment in LREEs, depletion in Ba, La, Ce and Ti, enriched in U, K, Pb and P. Granitic pegmatite can be formed at different stages of crystallization differentiation of granitic magma, but the pegmatite associated with highly differentiated granites is favorable to the Li and/or Be mineralization, while the pegmatite associated with low differentiated granites (such as biotite granites) is unfavorable to the Li and/or Be mineralization. Based on our findings, we propose that the Tugeman granitic magmas originated from partial melting of crustal metagreywacke and metabasalt. Furthermore, we suggest that the early Paleozoic magmatism in the Central Altun Block (CAB) can be categorized into three groups, which correspond to different tectonic events. These events include the northward subduction of the Central Altun Ocean (CAO) beneath the CAB around 520 Ma, the closure of CAO at 490–480 Ma, and post-collisional extension at 480–440 Ma induced by slab breakoff and delamination of the subducted CAO.

Geochronological and geochemical study of the Late Carboniferous volcanic drilling cores from the Piedmont of the Hala'alate Mountain in West Junggar: Implications for stratigraphic division and tectonic evolution

The West Junggar tectono-magmatic processes are critical for reconstructing the amalgamation history of the Central Asian Orogenic Belt (CAOB). However, the lack of consensus regarding the geochronology, petrogenesis, and tectonic setting of the complex igneous rocks poses a challenge to comprehending the Late Paleozoic tectonic evolution of West Junggar. This study focuses on systematic geochronological and geochemical research of well-preserved drill cores from the Piedmont of the Hala'alate Mountain, including rhyolite, felsic tuff, basalt, and andesite. The ages of these rocks in Late Carboniferous (310–301 Ma) are constrained by zircon UPb dating, excluding them from the Jiamuhe Formation of the Early Permian. The rhyolites and felsic tuffs exhibit apparent affinity to the A-type granite series, characterized by high total alkali and FeOT/MgO values. Plagioclase controls the main residual facies and depleted isotopic compositions (εHf(t) = +10.2 to +13.4; εNd(t) = +7.6 to +8.1), indicating that the magma source originated from the partial melting of juvenile continental materials in an extensional background. The basalts and andesites display high LILEs/LREEs, LILEs/HFSEs ratios, along with low HFSEs, which correspond to arc-affinity geochemical compositions. The high zircon εHf(t) (+7.5 to +14.3) and whole-rock εNd(t) (+7.8 to +7.9) values indicate a depleted pyroxene-rich mantle source modified by metasomatic slab-derived fluids. This implies a large-scale upwelling of mantle materials driven by the overlying lithospheric crustal thinning. Combining the temporal variations of crustal thickness recorded by the Sr/Y and (La/Yb)N ratios in igneous rocks, the tectonic processes of West Junggar during the Carboniferous to Early Permian can be divided into three stages. The first stage involves sustained subduction processes from 350 Ma to 320 Ma, followed by the closure of the oceanic crust and collision orogenesis from 320 Ma to 310 Ma. Finally, and a post-collision extension setting occurred after 310 Ma.

Petrogenesis of Middle Triassic andesitic rocks in the Weixi area, Southwest China: Implications for the tectonic evolution of the Paleo-Tethys

The Paleo-Tethyan tectonic evolution of the central Sanjiang orogenic belt remains unclear, particularly regarding the types and tectonic setting of volcanic rocks in the Cuiyibi Formation in the Weixi area, southwest China. These volcanic rocks were previously thought to be bimodal, but our detailed geological mapping revealed that the Cuiyibi Formation volcanic rocks include basalt, andesite, and rhyolite. In this paper, we present new geological, geochronological, and geochemical data for the andesitic rocks in the Cuiyibi Formation. Zircon UPb ages of the andesitic rocks indicate they formed at 245–242 Ma. The andesitic rocks are part of the high-K calc-alkaline/shoshonite series, and they exhibit light rare earth and large-ion lithophile element (e.g., K, Rb, Th, and U) enrichment and heavy rare earth and high-field-strength element (e.g., Nb, Ta, and Ti) depletion. High Mg# values and Nb contents, low Sm/Yb and Lu/Yb ratios, and negative zircon εHf(t) and whole-rock εNd(t) values suggest these rocks were derived from an enriched mantle source. The Cuiyibi Formation volcanic rocks are geochemically similar to those formed in a continental arc. These rocks formed along a vast continental arc in the North Qiangtang–Lanping–Simao Block related to the subduction of the Paleo-Tethyan oceanic slab.

Early Triassic roll-back of subducted Paleo-Tethys oceanic lithosphere: Insights from A2-type silicic igneous rocks in the Pingxiang area, southwest China

Abstract A suite of subduction-related early Triassic igneous rocks crops out in the Pingxiang area of the Dian-Qiong suture (DQS) in southwest China; this suite represents an important geological record of subduction and closure of the Paleo-Tethys Ocean. In this study, we report geochronological, geochemical, and Nd-Hf isotope data for newly discovered rhyolites and biotite granites in the Pingxiang area. We use these data to constrain their emplacement ages, origins, and geodynamic implications. Zircon U-Pb dating indicates that the rhyolites and biotite granites were emplaced at 251–250 Ma and 249 Ma (early Triassic), respectively. The rhyolites and biotite granites have elevated FeOT/(FeOT + MgO) (0.78–0.89) and 10,000 × Ga/Al (2.83–4.11) ratios, with geochemical affinities to A2-type granites. These rocks are enriched in some large-ion lithophile elements (e.g., Rb, Th, and Ba) and depleted in high-field-strength elements (e.g., Nb, Ta, and Ti), indicating their formation in a subduction-related arc. The rhyolites and biotite granites have negative whole-rock εNd(t) (−11.5 to −9.7) and zircon εHf(t) (−14.5 to −6.2) values, suggesting that these magmas were derived from an ancient crust-dominated source. Geochemical and Nd isotope data reveal that the peraluminous A2-type rhyolites and biotite granites were derived by partial melting of felsic crustal rocks under low-pressure and high-temperature conditions. By integrating all the available data with the regional tectonic evolution of the southwestern Youjiang Basin and adjacent regions, we attribute the generation of the peraluminous A2-type rhyolites and biotite granites to the extensional setting that existed during oceanic subduction, which was induced by roll-back of thePaleo-Tethys oceanic lithosphere at 251–249 Ma. This study indicates that subduction-related magmatism related to Paleo-Tethys oceanic lithosphere was still active in the early Triassic.

Petrogenesis of early Cretaceous granites in Mufushan complex, northeastern Hunan Province: Insights on middle-late Mesozoic tectonic evolution of eastern South China

We present new field observations, whole-rock major and trace elements, Sr-Nd-Pb-Hf isotopes and zircon UPb ages for the Mesozoic granites in the Mufushan complex, eastern South China. The age determinations by LA-ICP-MS UPb dating of zircons indicate that the porphyritic biotite granites and two-mica monzogranites have ages of ∼136 Ma and ∼ 130 Ma, respectively. These granites display highly evolved S-type granite geochemical characteristics, with high SiO2 (70–74 wt%) contents, high 10000*Ga/Al ratios (2.3–3.2, average of 2.8) and weakly peraluminous (A/CNK > 1.1). Both types of granites are enriched in large ion lithophile elements (LILEs, e.g., Rb, K, Ba, Sr) and depleted in high field strength elements (HFSEs, e.g., Nb, Ta, Ti), with negative anomalies of Eu and positive anomalies of Pb, which are akin to continental arc rocks. The two-mica monzogranites have high 87Sr/86Sr(i) (0.71355–0.71535), 206Pb/204Pb(i) (18.105–18.157), low εNd(t) (−9.1 to −9.6) and εHf(t) (−4.1 to −10.4), similar to those of the porphyritic biotite granites which are characterized by high 87Sr/86Sr(i) (0.717337–0.71692), 206Pb/204Pb(i) (18.134–18.580), low εNd(t) (−9.1 to −9.7) and zircon εHf(t) (−6.8 to −3.3). The similar emplacement ages and mineral assemblages as well as Sr-Nd-Hf isotopic signatures indicate their derivations were likely derived from a common magma source. These early Cretaceous granites yield two-stage Nd model ages of 1.6–1.7 Ga, similar to the two-stage Hf model ages of 1.3–1.8 Ga. The presence of Neoproterozoic and subordinate Mesoproterozoic zircons within the granitic rocks suggest a significant contribution of ancient crustal materials involved in the genesis of the magmas. In combination with comprehensive studies on the magmatic rocks, the early Cretaceous Mufushan granitic rocks may have experienced an extensive enrichment process, contemporaneously with partial melting of the Neoproterozoic volcanic-sedimentary sequences that produced the arc-like rocks. Almost simultaneously, an extensional event caused by the subduction and slab roll-back of the Paleo-Pacific plate (Izanagi plate) dominates the middle-late Mesozoic tectonics in eastern South China. This extensional regime was accompanied by the underplating of mantle-derived magma and crustal melting, producing the widespread early Cretaceous granites in adjacent regions. The development of coeval basin-and-range structures with the production of contemporaneous magmatic rocks and related polymetallic deposits in eastern South China are all related to slab roll-back tectonics.

Timescale of magma recharge for a crystal-rich mush: Perspectives from the compositional zoned quartz in Xiangshan caldera, SE China

Crystal-rich (>30 vol%) volcanic rocks, which are generally thought to be formed by the eruption of crystal-rich mush after its reactivation, have provided an important lens through which to view the connection of volcanic and plutonic rocks in the calderas worldwide. The crystal-rich rhyolitic porphyritic lava is widely exposed in Cretaceous calderas in the southeast China. However, the petrogenesis of crystal-rich porphyritic lava still remains controversial. Xiangshan caldera is a uranium mineralization related volcanic-plutonic complex, which is composed of first subcycle rhyodacite and second subcycle tuff, crystal-rich rhyolitic porphyritic lava, granite porphyry and quartz monzonitite porphyry. All the volcanic and plutonic rocks have consistent zircon U-Pb ages (135 to 133 Ma). Sr-Nd-Hf-O isotopic characteristics show that they all mainly originated from crust derived intermediate-silicic magma. Zircon εHf(t) values for inherited zircons from rhyolitic porphyritic lava and rhyodacite range from −6.9 to +9.5. Correspondingly, zircon Hf two-stage model ages of inherited zircons are 2.12 to 1.10 Ga, suggesting their derivation from the Neoproterozoic juvenile crust and the Archean to Paleoproterozoic ancient crust. The rhyolitic porphyritic lavas show higher SiO2 contents and Rb/Sr ratios, and more obvious negative anomalies of Eu/Eu*, Ba, Sr, P and Ti; The granite porphyry show lower SiO2 contents and Rb/Sr ratios, with weak negative anomalies of Eu/Eu*, Ba, Sr, P and Ti. Combined with similar Sr-Nd-Hf-O isotopic composition, they may be derived from the same magma reservoir. Lower εNd(t), εHf(t), δ18O values and older model ages of tuff indicate more contribution of older crustal material. The cathodoluminescence (CL) brightness is strongly correlated with Ti concentration in quartz. The CL of selected quartz grains from crystal-rich rhyolitic porphyritic lava and granite porphyry show brightness zoned mantles (Ti = 19 to 77 ppm) and bright rims (high-Ti; >70 ppm). Some grains have dark cores (low-Ti; <9 ppm). However, the Ti contents of the quartz in the tuff of the second subcycle are homogeneous. Resemble the crystal-rich rhyolitic porphyritic lavas, the rims of quartz phenocrysts in the granite porphyry have consistent CL-brightness with the quartz in groundmass and have small embayments caused by growth impediments in them, which is due to the pressure release. It indicates that the granite porphyry also migrated upward rather than in situ cumulate. The repeated rise of CL brightness and Ti contents in the mantle of quartz phenocrysts recorded the rise of temperature and/or the injection of more primitive magma, indicating several times of magma recharge in the magma reservoir. The timescale of Ti diffusion in the compositional zoned mantle of quartz documented an ephemeral reactivation and remobilization of the crystal-rich mush within several to 16 thousand years with at least 7 times of magma recharge which lasted for 17 years to >11 thousand years each time.

Tracking a magmatic arc within a confined orogen: New evidence from the Araçuaí orogen (SE Brazil)

By comparison with igneous rock assemblages of well-exposed modern magmatic arcs and their typical calc-alkaline, magnesian, I-type signatures, many deeply eroded magmatic arcs have been characterized worldwide, unraveling ancient plate margins. Since the 1980's, different assemblages of Ediacaran to Cambrian magmatic rocks have been systematically mapped and characterized according to their distinctive petrographic, structural, lithochemical, geochronologic, and isotopic features, allowing to establish the pre-collisional, collisional, and post-collisional stages of the Araçuaí orogen (SE Brazil). Among them, the tonalitic-granodioritic batholiths and stocks with calc-alkaline, magnesian, I-type signatures, rich in dioritic to mafic enclaves, and related metavolcano-sedimentary successions compose a magmatic arc formed in the early Ediacaran, the Rio Doce magmatic arc. Extending for more than 1000 km along the Araçuaí-Ribeira Orogenic System (AROS), the Rio Doce arc shows a hybrid isotopic signature and crustal inheritance, compatible with modern magmatic arcs built on continental active margins. We present new field, petrographic, and lithochemical studies, coupled with U–Pb (LA-ICPMS) geochronology and isotopic (in-zircon Lu–Hf and whole-rock Sm–Nd) analysis, unraveling the least evolved isotopic signatures ever found for tonalitic-granodioritic plutons of the Rio Doce magmatic arc, and a comprehensive data comparison with modern magmatic arcs. The studied Santa Tereza and Jequitibá suites comprise tonalitic-granodioritic and Opx-bearing charnockitic rocks, with calcic-to-alkali-calcic-magnesian I-type signature, associated with gabbroic rocks. Zircon U–Pb data yielded Concordia ages of 612 ± 3 Ma (Santa Tereza) and 594 ± 3 Ma (Jequitibá) for magmatic crystallization, and 580 ± 5 Ma to 571 ± 3 Ma for metamorphic recrystallization, with associated εNd(612Ma) values from −0.06 to −7.05 (TDM model ages: 1.4–2.04 Ga), and εNd(594Ma) values from −6.67 to −8.8 (TDM model ages: 1.64–1.87 Ga). The zircon εHf(t) (+2.3 to −4.8) and Hf TDM model ages (1.33–1.65 Ga) assigned a moderately juvenile to evolved signature for the Santa Tereza suite, while the Jequitibá suite (εHf(t): −1.7 to −36.4; TDM model ages: 1.33–3.21 Ga) shows a more evolved signature. Altogether, data from the Rio Doce arc are similar to typical continental-margin magmatic arcs with the involvement of mantle melts and/or melting of juvenile crust, suggesting a westward slab retreat during ocean-floor subduction within the Araçuaí confined orogen.

The isotope geochemistry of host rocks of the late Archean Guandi and Banshigou banded iron formations, southern Jilin Province: temporal and tectonic significance

The Guandi and Banshigou iron deposits of southern Jilin Province, China, are Algoma-type banded iron formations (BIFs) located in the Eastern Block of the North China Craton (NCC). LA–ICP–MS U–Pb dating shows the magmatic zircons in plagioclase amphibolite from the Guandi BIF (PA–GD) and plagioclase hornblende gneiss from the Banshigou BIF (PHG–BSG) were crystallised at 2556 ± 17 Ma and 2545 ± 27 Ma, respectively, representing the formation age of the BIFs. Metamorphic overgrowth zircons from both samples gave two U–Pb ages of 2452 ± 23 Ma and 2446 ± 70 Ma, indicating the age of metamorphism. The zircon εHf(t) values of PA–GD (–1.3 to +2.8) and PHG–BSG (–1.5 to +2.7) indicate that the magma source was derived from depleted mantle with contamination of crustal material. According to our study, the PA–GD and PHG–BSG were formed in an island arc setting and support previously proposed subduction zone tectonic models for the northeastern NCC during the Neoarchean.

Paleoproterozoic U Mineralization in Huayangchuan Deposit, Xiaoqinling Area: Evidence from the U–Rich Granitic Pegmatite

The Huayangchuan uranium deposit, located in the west of the Xiaoqinling belt on the southern margin of the North China Craton, is a large U–Nb–Pb deposit accompanied with rare–earth elements. The Huayangchuan uranium deposit, discovered in the 1950s, has long been known as a carbonatite–type uranium deposit. Recently, new geological work has found uranium mineralization in many granitic pegmatite veins in the Huayangchuan deposit and adjacent areas. Here, we report a systematic investigation of the petrography, whole–rock geochemistry, zircon U–Pb ages, and in situ Lu–Hf isotopic characteristics of newly discovered U–rich granitic pegmatite veins in the west of Huayangchuan deposit. The petrological results showed that the lithology of the samples is granite pegmatite. The U–Pb ages of zircon were 1826.3 ± 7.9 and 1829 ± 11 Ma. Microscopically, the paragenetic characteristics of zircon, betafite, and uraninite exist in the intergranular fissures of K–feldspar and quartz, reflecting metallogenic phenomena in the rock formation process. Almost all whole–rock samples were rich in SiO2 (64.37−70.69 wt.%), total alkalis (K2O + Na2O = 8.50–10.30 wt.%), and Al2O3 (12.20–14.41 wt.%) but poor in TiO2 (0.23–0.73 wt.%), MgO (0.38–0.90 wt.%), CaO (1.23–2.22 wt.%), P2O5 (0.14–0.83 wt.%), and MnO (0.04–0.57 wt.%). Additionally, they showed enrichment of LILEs (such as Rb, Ba, Th, U, and K), depletion of HFSEs (such as Ta, P, Ti, and Hf), and no alkaline dark minerals, and the characteristics are intraplate A1–type granite. The A1–type granite displayed low zircon εHf(t) values (−19.42–−15.02) with zircon two–stage Hf model aged 3.10–2.76 Ga, indicating that the U–rich granitic pegmatite was derived predominantly from partial melting of the ancient continental crust (such as the early Taihua group formed in Archean–Neoarchean). Combined with the above results and regional geological data, the U–rich granitic pegmatite discovered in the Huayangchuan deposit was formed in a post–collisional regime after the Luliang movement in the late Paleoproterozoic. This study suggests that future uranium prospecting work in this area should focus on late Paleoproterozoic U–rich granitic pegmatites.

Geochronology, petrogenesis, and mineralization potential of the syenogranites in the Yama fluorite deposit, Tataleng granitic batholith, Qilian Orogen, NW China

The Yama fluorite deposit in the Qilian Orogen in NW China is characterized by predominant granitic magmatism and fluorite mineralization. The wall rocks hosting the fluorite–quartz veins in the Yama area consist of the Yama porphyritic syenogranite and the Wulandawu syenogranite. In this study, the major and trace element compositions, zircon U–Pb ages, and zircon Hf isotopes and trace element compositions were investigated. Two samples for the Yama porphyritic syenogranite yielded weighted mean 206Pb/238U zircon ages of 440.7 ± 4.8 and 447.9 ± 6.0 Ma, and one sample for the Wulandawu syenogranite yielded a weighted mean 206Pb/238U zircon age of 441.2 ± 5.0 Ma, all of which indicate a Late Ordovician to Early Silurian crystallization age. Geochemically, both syenogranites are peraluminous, with high alkali contents, low Zr + Nb + Ce + Y contents, relatively low (K2O + Na2O)/CaO ratios, and high Rb/Sr and Rb/Ba ratios, suggesting that they are fractionated S-type granites. They have zircon εHf( t) values of −14.9 to −4.4 and −12.2 to −4.5, respectively, suggesting that they were derived from the partial melting of pelitic-rich sources within the relatively shallow Paleoproterozoic reworked crust. The detailed geochronological and geochemical data suggest that the studied syenogranites were emplaced in a post-collisional setting related to the closure of the South Qilian Ocean. Finally, they have relatively low quantitative oxygen fugacity values, indicating relatively reduced redox states, but their very low zircon Ce4+/Ce3+ ratios, low whole-rock K/Rb ratios, relatively high Nb/Ta ratios, and low Zr/Hf ratios suggest that they are not likely to form important W–Sn deposits and related fluorite deposits.

Geochemistry, zircon U–Pb geochronology and Hf isotope of the early Permian gabbro and high-Mg diorites from the Zhusileng–Hangwula Belt in the northern Alxa area: Petrogenesis and tectonic implications

AbstractAs the southernmost part of the central segment of the Central Asian Orogenic Belt, the northern Alxa area is characterized by abundant Permian magmatism and records key information on the geological evolution of the Palaeo-Asian Ocean. This study reports new zircon U–Pb and Lu–Hf isotopic and whole-rock geochemical data of the early Permian (285–286 Ma) Huisentala gabbro and Huodonghaer diorites from the Zhusileng–Hangwula Belt in the northern Alxa area. The gabbro is characterized by high Al, Ca, Mg# and light rare-earth elements, and low K, P and high field strength elements (e.g., Ti, Nb and Ta). Furthermore, the gabbro shows heterogeneous zircon ϵHf(t) value (−2.5 to +2.6). The Huodonghaer diorites show high MgO (3.46–6.32 wt%), Mg# (49–58), Sr (408–617 ppm) and Ba (223–419 ppm), and low FeOT/MgO (1.27–1.83) and TiO2 (0.48–0.90 wt%), with geochemical features similar to the high-Mg andesite/diorite. They show radiogenic zircon ϵHf(t) values of +1.2 to +4.9 and high Th/Nb ratios. These features suggest that the Huisentala gabbro and the Huodonghaer diorites were derived from the partial melting of mantle peridotite that was metasomatized by subduction-related fluids and by subducted sediment-derived melts, respectively.

Multiple ridge subduction processes in the southern Altaids: Implications from clinopyroxene chemistry and Sr–Nd–Hf isotopes of late carboniferous Nb-enriched, magnesian diorite-andesites in West Junggar, NW China

Magnesian (Mg# > 45) and/or Nb-rich (Nb > 6 ppm) dioritic-andesitic rocks have been identified in the Mayile area of southern West Junggar, Northwest China. A systematic petrological, geochronological, whole-rock geochemical, Sr–Nd–Hf isotope, and clinopyroxene chemistry study was conducted to constrain the petrogenesis, mantle source, and P–T conditions of magmas as well as the tectonomagmatic processes in the southern Paleo-Asian Ocean subduction zone. Mayile dioritic-andesitic rocks generated in the Late Carboniferous (306–312 Ma) have a high SiO2 content (52.3–63.2 wt%) and high Mg# (46–66) as well as sanukitic-like low LaN/YbN and Sr/Y ratios. They have high Nb contents (6.27–11.6 ppm) and Nb/U (9–18) ratios and are Nb-enriched sanukitic high-Mg andesites (HMAs). Clinopyroxene thermobarometry indicates that the parental magma of the Mayile HMAs experienced a high-temperature (1137–1199 °C) and shallow-level (0.8–0.17 GPa) partial melting in a mantle wedge. They have εNd(t) (+5.14 to +6.42), εHf(t) (+8.8 to +14.4), and zircon εHf(t) (+9.4 to +15.8) values and a slightly high (87Sr/86Sr)t ratio ranging from 0.703214 to 0.704140 relative to normal mid-ocean ridge basalt (N-MORB). The results suggest that West Junggar was dominated by continuous records of sanukitic rocks hinting at multiple ridge subduction processes in the southern Altaids. We reconstructed the subduction history of the Junggar Ocean in the Carboniferous-Permian from these particular observations in West Junggar, and gained insight into the gradual evolution of the tectonic setting, which transitioned from normal intraoceanic subduction to hot subduction of the young oceanic lithosphere from the Early to Late Carboniferous, with subsequent ridge subduction occurring mainly in the Late Carboniferous.

Lithospheric dripping triggered by slab break-off: A possible mechanism for Late Carboniferous magmatism in the eastern Central Asian Orogenic Belt

In this paper, we present zircon UPb dating, elemental geochemistry, and Sr–Nd–Hf isotopic compositions for Late Carboniferous intrusive rocks in the northern Great Xing'an Range, northeast China. We decipher the mechanisms which triggered lithospheric thinning under microblock-microblock collision and provide a new perspective on the Late Paleozoic evolution of the eastern Central Asian Orogenic Belt. Zircon UPb dating indicates that Jifeng gabbroic diorites and Xinlin granites were formed during a short time interval at 322–321 Ma, whereas the Xinlin gabbros were crystallized at 300 ± 2 Ma. The Jifeng gabbroic diorites exhibit typical arc characteristics, depleted in HFSEs and enriched in Pb and have positive εNd(t) (+1.88 to +2.00) and εHf(t) (+6.6 to +10.7) values, suggesting they originated from the partial melting of depleted lithospheric mantle modified by slab fluids. The Xinlin gabbros belong to alkaline series and are characterized by the enrichment in HFSEs with positive Nb and Ta anomalies and depleted NdHf isotopic compositions (zircon εHf(t) = +12.5 to +18.9, whole rock εNd(t) = +8.0 to +8.1). High Nb concentrations and low La/Nb (0.81–0.83) and La/Ta (12.50–14.61) ratios of the Xinlin gabbros indicate an origin from a depleted asthenospheric mantle. The Xinlin granites have high-K calc-alkaline compositions, belonging to I-type granites. These granites have positive εHf(t) values (+0.2 to +15.1) and juvenile two-stage model ages (1314–506 Ma) with low Sr and high Yb contents, indicating they were formed by the partial melting of a juvenile lower crust under low-pressure conditions. These data, together with the temporal and spatial distribution and the geochemistry characteristics of the Carboniferous igneous rocks in the Great Xing'an Range, suggest that the amalgamation between the Erguna–Xing'an and Songnen blocks occurred before the Late Carboniferous. The occurrence of asthenospheric mantle-derived mafic rocks indicates localized thinning process of lithosphere. Late Carboniferous magmatism on the Erguna–Xing'an Block attributed to dripping or piece removal of the lithosphere due to asthenospheric fluctuation triggered by slab break-off.