Zero-temperature Limit Research Articles

Can room-temperature data for tunneling molecular junctions be analyzed within a theoretical framework assuming zero temperature?

Routinely, experiments on tunneling molecular junctions report values of conductances (GRT) and currents (IRT) measured at room temperature. On the other hand, theoretical approaches based on simplified models provide analytic formulas for the conductance (G0K) and current (I0K) valid at zero temperature. Therefore, interrogating the applicability of the theoretical results deduced in the zero-temperature limit to real experimental situations at room temperature (i.e., GRT ≈ G0K and IRT ≈ I0K) is a relevant aspect. Quantifying the pertaining temperature impact on the transport properties computed within the ubiquitous single-level model with Lorentzian transmission is the specific aim of the present work. Comprehensive results are presented for broad ranges of the relevant parameters (level's energy offset ε0 and width Γa, and applied bias V) that safely cover values characterizing currently fabricated junctions. They demonstrate that the strongest thermal effects occur at biases below resonance (2|ε0| - δε0 - 0.3 ≲ |eV| - 0.3 ≲ 2|ε0|). At fixed V, they affect an ε0-range whose largest width δε0 is about nine times larger than the thermal energy (δε0 ≈ 3πkBT) at Γa → 0. The numerous figures included aim to convey a quick overview on the applicability of the zero-temperature limit to a specific real junction. In quantitative terms, the conditions of applicability are expressed as mathematical inequalities involving elementary functions. They constitute the basis of a proposed interactive data-fitting procedure, which aims to guide experimentalists interested in data processing in a specific case.

Precision measurements of the zero-temperature dielectric constant and density of liquid He4

The resonant frequencies of three-dimensional (3D) microwave cavities are explicitly dependent on the dielectric constant of the material filling the cavity, making them an ideal system for probing material properties. In particular, dielectric constant measurements allow one to extract the helium density through the Clausius-Mossotti relation. By filling a cylindrical aluminum cavity with superfluid helium, we make precision measurements of the dielectric constant of liquid $^{4}\mathrm{He}$ at saturated vapor pressure for range of temperatures 30 to 300 mK and at pressures of 0 to 25.0 bar at 30 mK, essentially the zero temperature limit for the properties of $^{4}\mathrm{He}$. After reviewing previous measurements, we find systematic discrepancy between the low and high frequency determination of the dielectric constant in the zero-temperature limit and moderate discrepancy with previously reported values of pressure-dependent density. Our precision measurements suggest 3D microwave cavities are a promising choice for refining previously measured values in helium, with potential applications in metrology.

Augmenting the residue theorem with boundary terms in finite-density calculations

At zero temperature and finite chemical potential, $d$-dimensional loop integrals with complex-valued integrands in the imaginary-time formalism yield results dependent on the integration order. We observe this even with the simplest one-loop dimensionally regularized integrals. Computing such integrals by evaluating the spatial $\mathrm{d}^{d} p$ integral before the temporal $\mathrm{d} p_0$ integral yields results consistent with those obtained at small but nonvanishing temperatures. Computing the temporal integral first by applying the residue theorem to the integrand yields a different answer. The same holds for general complexified propagators. In this work we aim to understand the theoretical background behind this difference, in order to fully enable the powerful techniques of residue calculus in applications. We cast the difference into the form of a derivative term related to Dirac deltas, and further demonstrate how the difference originates from the zero-temperature limit of the Fermi-Dirac occupation functions treated as complex-valued functions. We also discuss a generalization to propagators raised to non-integer powers.

Frozen Deconfined Quantum Criticality

There is a number of contradictory findings with regard to whether the theory describing easy-plane quantum antiferromagnets undergoes a second-order phase transition. The traditional Landau-Ginzburg-Wilson approach suggests a first-order phase transition, as there are two different competing order parameters. On the other hand, it is known that the theory has the property of self-duality which has been connected to the existence of a deconfined quantum critical point (DQCP). The latter regime suggests that order parameters are not the elementary building blocks of the theory, but rather consist of fractionalized particles that are confined in both phases of the transition and only appear-deconfine-at the critical point. Nevertheless, many numerical MonteCarlo simulations disagree with the claim of a DQCP in the system, indicating instead a first-order phase transition. Here we establish from exact lattice duality transformations and renormalization group analysis that the easy-plane CP^{1} antiferromagnet does feature a DQCP. We uncover the criticality starting from a regime analogous to the zero temperature limit of a certain classical statistical mechanics system which we therefore dub frozen. At criticality our bosonic theory is dual to a fermionic one with two massless Dirac fermions, which thus undergoes a second-order phase transition as well.

Closest-vector problem and the zero-temperature p-spin landscape for lossy compression.

We consider a high-dimensional random constrained optimization problem in which a set of binary variables is subjected to a linear system of equations. The cost function is a simple linear cost, measuring the Hamming distance with respect to a reference configuration. Despite its apparent simplicity, this problem exhibits a rich phenomenology. We show that different situations arise depending on the random ensemble of linear systems. When each variable is involved in at most two linear constraints, we show that the problem can be partially solved analytically, in particular we show that upon convergence, the zero-temperature limit of the cavity equationsreturns the optimal solution. We then study the geometrical properties of more general random ensembles. In particular we observe a range in the density of constraints at which the system enters a glassy phase where the cost function has many minima. Interestingly, the algorithmic performances are only sensitive to another phase transition affecting the structure of configurations allowed by the linear constraints. We also extend our results to variables belonging to GF(q), the Galois field of order q. We show that increasing the value of q allows to achieve a better optimum, which is confirmed by the replica-symmetric cavity method predictions.

Schrödinger cat state formation in small bosonic Josephson junctions at finite temperatures and dissipation

In this work, we consider the feasibility of Schrödinger cat (SC) and states formation by a convenient bosonic Josephson junction system in two-mode approximation. Starting with purely quantum description of two-mode Bose–Einstein condensate we investigate the effective potential approach that provides an accurate analytical description for the system with a large number of particles. We show that in the zero temperature limit SC states result from a quantum phase transition that occurs when the nonlinear strength becomes comparable with the Josephson coupling parameter. The Wigner function approach demonstrates the growth of the SC state halves separation and formation of -like states (a Fock state superposition) with the particle number increase. We examine the possibility to attain the SC state at finite temperatures and a weak dissipation leading to appearing of some critical temperature; it defines the second-order phase transition from classical activation process to the SC state formation through the quantum tunneling phenomenon. Numerical estimations demonstrate that the critical temperature is sufficiently below the temperature of atomic condensation. The results obtained may be useful for experimental observation of SC states with small condensate Josephson junctions.

Existence of the zero-temperature limit of equilibrium states on topologically transitive countable Markov shifts

AbstractConsider a topologically transitive countable Markov shift $\Sigma $ and a summable locally constant potential $\phi $ with finite Gurevich pressure and $\mathrm {Var}_1(\phi ) < \infty $ . We prove the existence of the limit $\lim _{t \to \infty } \mu _t$ in the weak $^\star $ topology, where $\mu _t$ is the unique equilibrium state associated to the potential $t\phi $ . In addition, we present examples where the limit at zero temperature exists for potentials satisfying more general conditions.

Crystal Prediction via Genetic Algorithms in a Model Chiral System.

Chiral crystals and their constituent molecules play a prominent role in theories about the origin of biological homochirality and in drug discovery, design, and stability. Although the prediction and identification of stable chiral crystal structures is crucial for numerous technologies, including separation processes and polymorph selection and control, predictive ability is often complicated by a combination of many-body interactions and molecular complexity and handedness. In this work, we address these challenges by applying genetic algorithms to predict the ground-state crystal lattices formed by a chiral tetramer molecular model, which we have previously shown to exhibit complex fluid-phase behavior. Using this approach, we explore the relative stability and structures of the model's conglomerate and racemic crystals, and present a structural phase diagram for the stable Bravais crystal types in the zero-temperature limit.

Multi-channel Luttinger Liquids at the Edge of Quantum Hall Systems

We consider the edge transport properties of a generic class of interacting quantum Hall systems on a cylinder, in the infinite volume and zero temperature limit. We prove that the large-scale behavior of the edge correlation functions is effectively described by the multi-channel Luttinger model. In particular, we prove that the edge conductance is universal, and equal to the sum of the chiralities of the non-interacting edge modes. The proof is based on rigorous renormalization group methods, that allow to fully take into account the effect of backscattering at the edge. Universality arises as a consequence of the integrability of the emergent multi-channel Luttinger liquid combined with lattice Ward identities for the microscopic 2d theory.

Nondivergent chiral charge pumping in Weyl semimetals

Recent studies suggest that the nonlinear transport properties in Weyl semimetal may be a measurable consequence of its chiral anomaly. Nonlinear responses in transport are estimated to be substantial, because in real materials such as TaAs or ${\mathrm{Bi}}_{1\ensuremath{-}x}{\mathrm{Sb}}_{x}$, the Fermi level resides near the Weyl nodes where the chiral charge pumping is said to diverge. However, this work presents semiclassical Boltzmann analysis that indicates that the chiral charge pumping is nondivergent even at the zero-temperature limit. We demonstrate that the divergence in a common semiclassical calculation scheme is not a problem of the scheme itself, but occurs because a commonly used approximation of the change in particle number breaks down near the Weyl nodes. Our result suggests the possibility that the nonlinear properties in Weyl semimetals can be overestimated, and it provides the validity condition for the conventional approximation. We also show the distinct Fermi level dependencies of the chiral magnetic effect and the negative longitudinal magnetoresistance, as a consequence of nondiverging chiral charge pumping.

Field theory for zero temperature soft anharmonic spin glasses in a field

We introduce a finite dimensional anharmonic soft spin glass in a field and show how it allows the construction a field theory at zero temperature and the corresponding loop expansion. The mean field level of the model coincides with a recently introduced fully connected model, the KHGPS model, and it has a spin glass transition in a field at zero temperature driven by the appearance of pseudogapped non-linear excitations. We analyze the zero temperature limit of the theory and the behavior of the bare masses and couplings on approaching the mean field zero temperature critical point. Focusing on the so called replicon sector of the field theory, we show that the bare mass corresponding to fluctuations in this sector is strictly positive at the transition in a certain region of control parameter space. At the same time the two relevant cubic coupling constants g 1 and g 2 show a non-analytic behavior in their bare values: approaching the critical point at zero temperature, g 1 → ∞ while g 2 ∝ T with a prefactor diverging at the transition. Along the same lines we also develop the field theory to study the density of states of the model in finite dimension. We show that in the mean field limit the density of states converges to the one of the KHGPS model. However the construction allows a treatment of finite dimensional effects in perturbation theory.

Electronegativity Equilibration.

Controlling the distribution of electrons in materials is the holy grail of chemistry and material science. Practical attempts at this feat are common but are often reliant on simplistic arguments based on electronegativity. One challenge is knowing when such arguments work, and which other factors may play a role. Ultimately, electrons move to equalize chemical potentials. In this work, we outline a theory in which chemical potentials of atoms and molecules are expressed in terms of reinterpretations of common chemical concepts and some physical quantities: electronegativity, chemical hardness, and the sensitivity of electronic repulsion and core levels with respect to changes in the electron density. At the zero-temperature limit, an expression of the Fermi level emerges that helps to connect several of these quantities to a plethora of material properties, theories and phenomena predominantly explored in condensed matter physics. Our theory runs counter to Sanderson’s postulate of electronegativity equalization and allows a perspective in which electronegativities of bonded atoms need not be equal. As chemical potentials equalize in this framework, electronegativities equilibrate.

Comparing four hard-sphere approximations for the low-temperature WCA melting line.

By combining interface-pinning simulations with numerical integration of the Clausius-Clapeyron equation, we accurately determine the melting-line coexistence pressure and fluid/crystal densities of the Weeks-Chandler-Andersen system, covering four decades of temperature. The data are used for comparing the melting-line predictions of the Boltzmann, Andersen-Weeks-Chandler, Barker-Henderson, and Stillinger hard-sphere approximations. The Andersen-Weeks-Chandler and Barker-Henderson theories give the most accurate predictions, and they both work excellently in the zero-temperature limit for which analytical expressions are derived here.

Vibrational response functions for multidimensional electronic spectroscopy in the adiabatic regime: A coherent-state approach.

Multi-dimensional spectroscopy represents a particularly insightful tool for investigating the interplay of nuclear and electronic dynamics, which plays an important role in a number of photophysical processes and photochemical reactions. Here, we present a coherent state representation of the vibronic dynamics and of the resulting response functions for the widely used linearly displaced harmonic oscillator model. Analytical expressions are initially derived for the case of third-order response functions in an N-level system, with ground state initialization of the oscillator (zero-temperature limit). The results are then generalized to the case of Mth order response functions, with arbitrary M. The formal derivation is translated into a simple recipe, whereby the explicit analytical expressions of the response functions can be derived directly from the Feynman diagrams. We further generalize to the whole set of initial coherent states, which form an overcomplete basis. This allows one, in principle, to derive the dependence of the response functions on arbitrary initial states of the vibrational modes and is here applied to the case of thermal states. Finally, a non-Hermitian Hamiltonian approach is used to include in the above expressions the effect of vibrational relaxation.

Anomalous metals: From “failed superconductor” to “failed insulator”

Resistivity saturation is found on both superconducting and insulating sides of an "avoided" magnetic-field-tuned superconductor-to-insulator transition (H-SIT) in a two-dimensional In/InOx composite, where the anomalous metallic behavior cuts off conductivity or resistivity divergence in the zero-temperature limit. The granular morphology of the material implies a system of Josephson junctions (JJs) with a broad distribution of Josephson coupling EJ and charging energy EC, with an H-SIT determined by the competition between EJ and EC. By virtue of self-duality across the true H-SIT, we invoke macroscopic quantum tunneling effects to explain the temperature-independent resistance where the "failed superconductor" side is a consequence of phase fluctuations and the "failed insulator" side results from charge fluctuations. While true self-duality is lost in the avoided transition, its vestiges are argued to persist, owing to the incipient duality of the percolative nature of the dissipative path in the underlying random JJ system.

Fluctuational electrodynamics in and out of equilibrium

Dispersion forces between neutral material bodies are due to fluctuations of the polarization of the bodies. For bodies in equilibrium these forces are often referred to as Casimir–Lifshitz forces. For bodies in relative motion, in addition to the Casimir–Lifshitz force, a lateral frictional force (“quantum friction”, in the zero temperature limit) comes into play. The widely accepted theory of the fluctuation-induced forces is based on the “fluctuational electrodynamics”, when the Maxwell equations are supplemented by random current sources responsible for the fluctuations of the medium polarization. The first part of our paper touches on some conceptual issues of the theory, such as the dissipation-less limit and the link between Rytov’s approach and quantum electrodynamics. We point out the problems with the dissipation-less plasma model (with its unphysical double pole at zero frequency) which still appears in the literature. The second part of the paper is devoted to “quantum friction”, in a broad sense, and it contains some novel material. In particular, it is pointed out that in weakly dissipative systems the friction force may not be a stationary process. It is shown, using an “exact” (nonperturbative) quantum treatment, that under appropriate conditions, an instability can occur when the kinetic energy (due to the relative motion between the bodies) is transformed into coherent radiation, exponentially growing in intensity (the instability gets eventually limited by nonlinear effects). We also discuss a setup when the two bodies are at rest but a constant electric current is flowing in one of the bodies. One may say that only the electron component of one body is dragged with respect to the other body, unlike the usual setup when the two bodies are in relative motion. Clearly, there are differences in the frictional forces between the two setups.

Tensor network renormalization study on the crossover in classical Heisenberg and RP^{2} models in two dimensions.

We study the classical two-dimensional RP^{2} and Heisenberg models, using the tensor-network renormalization (TNR) method. The determination of the phase diagram of these models has been challenging and controversial due to the very large correlation lengths at low temperatures. The finite-size spectrum of the transfer matrix obtained by TNR is useful in identifying the conformal field theory describing a possible critical point. Our results indicate that the ultraviolet fixed point for the Heisenberg model and the ferromagnetic RP^{2} model in the zero-temperature limit corresponds to a conformal field theory with central charge c=2, in agreement with two independent would-be Nambu-Goldstone modes. On the other hand, the ultraviolet fixed point in the zero-temperature limit for the antiferromagnetic Lebwohl-Lasher model, which is a variant of the RP^{2} model, seems to have a larger central charge. This is consistent with c=4 expected from the effective SO(5) symmetry. At T>0, the convergence of the spectrum is not good in both the Heisenberg and ferromagnetic RP^{2} models. Moreover, there seems to be no appropriate candidate of conformal field theory matching the spectrum, which shows the effective central charge c∼1.9. These suggest that both models have a single disordered phase at finite temperatures, although the ferromagnetic RP^{2} model exhibits a strong crossover at the temperature where the dissociation of Z_{2} vortices has been reported.

BROTOCs and Quantum Information Scrambling at Finite Temperature

Out-of-time-ordered correlators (OTOCs) have been extensively studied in recent years as a diagnostic of quantum information scrambling. In this paper, we study quantum information-theoretic aspects of the regularized finite-temperature OTOC. We introduce analytical results for the bipartite regularized OTOC (BROTOC): the regularized OTOC averaged over random unitaries supported over a bipartition. We show that the BROTOC has several interesting properties, for example, it quantifies the purity of the associated thermofield double state and the operator purity of the analytically continued time-evolution operator. At infinite-temperature, it reduces to one minus the operator entanglement of the time-evolution operator. In the zero-temperature limit and for nondegenerate Hamiltonians, the BROTOC probes the groundstate entanglement. By computing long-time averages, we show that the equilibration value of the BROTOC is intimately related to eigenstate entanglement. Finally, we numerically study the equilibration value of the BROTOC for various physically relevant Hamiltonian models and comment on its ability to distinguish integrable and chaotic dynamics.

Peak in the critical current density in (CaxSr1−x)3Rh4Sn13 tuned towards the structural quantum critical point

(Ca$_{x}$Sr$_{1-x}$)$_3$Rh$_4$Sn$_{13}$ is a rare system that has been shown to display an interesting interplay between structural quantum criticality and superconductivity. A putative structural quantum critical point, which is hidden beneath a broad superconducting dome, is believed to give rise to optimized superconducting properties in (Ca$_{x}$Sr$_{1-x}$)$_3$Rh$_4$Sn$_{13}$. However, the presence of the superconducting dome itself hinders the examination of the quantum critical point through electrical transport, as the transport coefficients vanish in the superconducting state. Here, we use critical current density to explore within the superconducting dome. Our measurements reveal a large enhancement of the critical current density at the zero-temperature limit when the system is tuned towards the structural quantum critical point.

On the Stationary Solutions of Random Polymer Models and Their Zero-Temperature Limits

We derive stationary measures for certain zero-temperature random polymer models, which we believe are new in the case of the zero-temperature limit of the beta random polymer (that has been called the river delta model). To do this, we apply techniques developed for understanding the stationary measures of the corresponding positive-temperature random polymer models (and some deterministic integrable systems). More specifically, the article starts with a survey of results for the four basic beta-gamma models (i.e. the inverse-gamma, gamma, inverse-beta and beta random polymers), highlighting how the maps underlying the systems in question can each be reduced to one of two basic bijections, and that through an `independence preservation' property, these bijections characterise the associated stationary measures. We then derive similar descriptions for the corresponding zero-temperature maps, whereby each is written in terms of one of two bijections. One issue with this picture is that, unlike in the positive-temperature case, the change of variables required is degenerate in general, and so whilst the argument yields stationary solutions, it does not provide a complete characterisation of them. On the other hand, this degeneracy does allow us to explain the appearance of atoms in the stationary measures of certain zero-temperature models. We also derive from our viewpoint various links between random polymer models, some of which recover known results, some of which are novel, and some of which lead to further questions.