X80 Pipeline Steel Research Articles

Hydrogen Embrittlement Behavior of X42 Pipeline Steel in Gaseous Hydrogen with Different Pressures

Hydrogen Embrittlement Behavior of X42 Pipeline Steel in Gaseous Hydrogen with Different Pressures

Microstructural Evolution and Mechanical Properties of Reeled X65 Pipeline Steel during Cyclic Plastic Deformation and Natural Aging

The reel laying is recognized as a cost‐effective installation process for offshore pipelines. However, the mechanical properties are modified due to plastic deformation during the reel laying and lowering process of reeled pipelines and the subsequent natural aging in service. Cyclic plastic deformation (CPD) is conducted on X65 pipeline steel to simulate the strain experienced in the reel‐laying and lowering process, and then, the CPD specimen is aged at 250 °C to simulate natural aging in service. The dislocation configurations gradually evolve from dislocation lines and tangles into dislocation walls and cells due to the increase in strain level. After CPD and aging, the tensile strength increases by about 25 MPa, which is not significantly affected by the last introduced load direction and strain level. At the end of compressive loading, the yield strength and yield ratio decrease, but the uniform elongation increases significantly. In contrast, at the end of tensile loading, the yield strength and yield ratio increase, but the uniform elongation decreases slightly. The yield strength further increases as the strain level increases from 2 to 3%. Therefore, CPD and aging modify the mechanical properties of X65, considerably depending on the last introduced load direction and strain level.

An enhanced Hosford–Coulomb fracture model for predicting ductile fracture under a wide range of stress states

In this study, an Enhanced Hosford–Coulomb (EHC) fracture model is proposed, which suits a wide range of stress states. The model is validated by quantitatively investigating the ductile fracture behaviors of Ti-6Al-3Nb-2Zr-1Mo titanium alloy through experiments and numerical simulations, and the fracture morphologies are characterized using scanning electron microscopy. The results show that the EHC model has higher accuracy in predicting ductile fracture strain for Ti-6Al-3Nb-2Zr-1Mo alloy compared to the original Hosford–Coulomb (HC) model. Finally, the accuracy and material applicability of the EHC model are further verified with X80 pipeline steel and AA2024-T351 aluminum alloy, demonstrating its advantages.

Variations of the residual magnetic fields of X70 pipeline steels with double defects

The aim of this research is to correlate residual magnetic fields (RMFs) with double defects in ferromagnetic steels. Specimens of X70 pipeline steels were machined into smooth plates with two types of defect (single and double defects) for comparison. Tensile tests were carried out to detect the RMF signals on the surface of the defective specimens. The variation of the tangential component of the RMF signals was presented and magnetic parameters were defined to investigate the abnormal magnetic changes of the two types of defect. It was found that the peak value of the tangential component was not influenced by defect types and the valley value was capable of evaluating the interaction effect between defects. Correlation between the RMF signals and the location of double defects was also investigated. This research will promote the investigation of defect clusters in ferromagnetic steels based on the metal magnetic memory (MMM) technique.

Effects of hydrogen blending ratios and CO2 on hydrogen embrittlement of X65 steel in high-pressure offshore hydrogen-blended natural gas pipelines

In this study, the effects of hydrogen blending ratios and high CO2 content on hydrogen embrittlement (HE) of offshore natural gas X65 pipeline steel were investigated. In high-pressure hydrogen gas, the impact of hydrogen content on yield strength and tensile strength was minimal. However, the effect on elongation was more significant, with the area decreasing and the HE index increasing until the hydrogen-blended ratio approached 30%, at which point the HE index reached 8.94%. Introducing CO2 into high-pressure hydrogen-rich gas further increased the HE index with high CO2 content. At 40% CO2, the HE index was 2.42 times higher than in high-pressure hydrogen-blended mixtures (30% H2). Additionally, the local fracture morphology transitions from ductile to quasi-cleavage fracture with the addition of CO2 and H2.

Effect of Filler Wire Composition on Weld Metal Microstructure and Mechanical Properties in X80 Steel Laser Welds.

Laser welding was performed using different filler wires, ER70S steel, commercially pure iron, and pure nickel filler, in the context of welding X80 pipeline steel to assess the microstructure and mechanical properties of the weld metal. Introducing an ER70S wire promoted acicular ferrite formation in the fusion zone, compared to a bainitic microstructure in an autogenous laser weld. The use of pure iron wire was considered as a potential strategy for reducing hardenability, as it led to the dilution of alloying elements in the fusion zone, increasing ferrite content and reducing weld metal hardness to a level compliant with API pipeline standards. The addition of pure nickel wire was used to reveal the degree of weld metal mixing imposed by the laser (thus providing an unambiguous tracer element) when it is combined with filler material dilution in the fusion zone, revealing that the upper region contained 38% wire material and the lower region only 12%. This accounts for the differences observed between the upper versus lower portions of the weld metal when other wires are used, and the use of hardness mapping and micro-indentation demonstrates the correlation between the variations in mechanical properties and microstructural differences introduced by incomplete mixing of the filler wire elements.

Experimental Study on Hydrogen Embrittlement Behavior of X80 and X70 Pipeline Steels Evaluated by Hydrogen Permeation and Slow Strain Rate Tensile Tests

Experimental Study on Hydrogen Embrittlement Behavior of X80 and X70 Pipeline Steels Evaluated by Hydrogen Permeation and Slow Strain Rate Tensile Tests

Multi-objective prediction and optimization of X70 pipeline steel welding morphology in overhead laser-MAG hybrid welding based on RSM-NSGA-II

Multi-objective prediction and optimization of X70 pipeline steel welding morphology in overhead laser-MAG hybrid welding based on RSM-NSGA-II

Anions exacerbate microbial corrosion of X80 pipeline steel induced by sulfate-reducing bacteria in the sea mud environment

Sulfate-reducing bacteria (SRB) present in sea mud pose a challenge to the safe operation of subsea pipelines. Chlorides and sulfates in sea mud promote the microbial corrosion of subsea pipelines by SRB. This study investigates the effects of sulfate and chloride on the microbial corrosion of X80 pipeline steel in the sea mud environment. The results indicate that sulfate serves as an electron acceptor, promoting the growth of SRB, while chloride regulates the osmotic pressure of SRB cells, affecting their bioactivity. SRB exhibit more aggressive corrosion behavior in sea mud with high concentrations of both chloride and sulfate.

Hydrogen Embrittlement Behavior of API X70 Linepipe Steel under Ex Situ and In Situ Hydrogen Charging.

This study investigates the hydrogen embrittlement behavior of API X70 linepipe steel. The microstructure was primarily composed of a dislocation-rich bainitic microstructure and polygonal ferrite. Slow strain-rate tests (SSRTs) were performed under both ex situ and in situ electrochemical hydrogen charging conditions to examine the difference between hydrogen diffusion and trapping behaviors. The ex situ SSRTs showed almost the same tensile properties as air and a limited brittle fracture confined to near the surface. In contrast, the in situ SSRTs showed an abrupt failure after the maximum tensile load, leading to a brittle fracture across the entire fracture surface with stress-oriented hydrogen-induced cracking (SOHIC). The crack trace analysis results indicated that SOHIC propagation paths were influenced by localized hydrogen accumulation due to high-stress fields. As a result, the dominant hydrogen embrittlement mechanisms, such as hydrogen-enhanced localized plasticity (HELP) and hydrogen-enhanced decohesion (HEDE), changed. These findings provide critical insights into the microstructural factors affecting hydrogen embrittlement, which are essential for the design of hydrogen-resistant steels in hydrogen infrastructure applications.

Evaluating the Effect of Blended and Pure Hydrogen in X60 Pipeline Steel for Low-Pressure Transmission Using Hollow-Specimen Slow-Strain-Rate Tensile Testing

Evaluating the Effect of Blended and Pure Hydrogen in X60 Pipeline Steel for Low-Pressure Transmission Using Hollow-Specimen Slow-Strain-Rate Tensile Testing

Microstructure and wear resistance of laser cladding AlCoCrFeNiSiB high-entropy alloy with high boron content

In this study, a wear-resistant coating of high boron content Al1.5CoCr2Fe1.5NiSi0.5B2 high-entropy alloy (HEA) was prepared on X65 pipeline steel by laser cladding. The coating underwent microhardness testing, wear performance testing, and analyses including scanning electron microscope (SEM), transmission electron microscope (TEM), and X-ray diffraction (XRD). The results revealed a dual-phase structure of body-centered cube (BCC) and face-entered cube (FCC) in the coating, with the presence of Fe1.1Cr0.9B0.9 phase distributed within the BCC. Utilizing high-resolution transmission electron microscopy (HRTEM) characterization, irregular atomic arrangement regions within the BCC structure were observed. Through the calculation of the α2 and ε parameters of the coating, the degree of lattice distortion in the BCC and FCC phases was quantitatively described. The results suggested that the addition of a substantial amount of boron could strengthen the lattice distortion effect, leading to improved hardness and wear resistance of the coating. The average microhardness of the coating was 912 HV, about 5 times higher than X65 substrate, improved by more than 10 % compared with other AlCoCrFeNi-based high-entropy alloys and B-containing high-entropy alloys. The wear rate was 4.78 × 10−6 mm/N·m, wear performance is nearly 10 times higher than other AlCoCrFeNi HEA without boron, 2 times higher than HEA with born. The wear mechanism of the coating was identified as abrasive and oxidative wear.

Coupled effect of microstructure heterogeneity and hydrogen on local embrittlement of CGHAZ and IC-CGHAZ in X65 pipeline steel

The local embrittlement of the coarse-grained heat-affected zone (CGHAZ) and intercritically reheated CGHAZ (IC-CGHAZ) in X65 pipeline steel was investigated using an in situ crack-tip opening displacement test in air and H2S, combined with microstructure-based simulation. The IC-CGHAZ exhibited significantly lower cracking resistance, with the fracture toughness reduced by 50% compared to CGHAZ in both environments (0.160 mm in air and 0.017 mm in H₂S for IC-CGHAZ, compared to 0.307 mm in air and 0.034 mm in H₂S for CGHAZ). The martensite/austenite (M/A) constituents showed exceptionally higher intrinsic hardness than the ferrite matrix. The continuous distribution of M/As along the prior austenite grain boundaries resulted in local hardening and the formation of heterogeneous hard zones in IC-CGHAZ. Such microstructure heterogeneity resulted in the unique partitioning of plastic strain localization and stress triaxiality that promotes premature fracture, particularly with the coupled effect of hydrogen. This study provides a novel perspective on the fracture mechanisms and the typical fracture morphology of IC-CGHAZs in pipeline steel under the coupled effect of microstructure heterogeneity and hydrogen.

Manipulating nano-WS2 aggregates in electroplated Ni coating to mitigate hydrogen embrittlement in X70 pipeline steel

WS2 is a two-dimensional nanomaterial with significant potential for hydrogen barrier applications. Herein, WS2/Ni composite coatings were fabricated on X70 pipeline steel substrates via electrodeposition. The properties of the composite coatings were systematically examined by electrochemical hydrogen permeation tests, hydrogen evolution kinetics tests, SSRT, SKPFM, and FEM. The results indicate that varying the deposition time leads to changes in coating microstructure, which correspondingly influence hydrogen permeation performance. Furthermore, the hydrogen barrier mechanism of the WS2/Ni composite coatings involves two key processes: the inhibition of hydrogen evolution reactions on the coating surface and hydrogen adsorption by WS2 within the coating interior.

Hydrogen permeation behavior of X80 pipeline steel under alternating wet-dry environment in the South China Sea

The riser sections of offshore pipelines are subject to cathodic potentials, alternating wet-dry (AWD) cycles and stresses in the service environment. The hydrogen permeation of X80 offshore pipeline with different cathodic potentials, dry/wet ratios, and constant tensile stress in AWD environment were investigated by the self made experimental equipment, which includes the three modules, i.e., the constant stress loading, the two-component cell hydrogen permeation, and AWD environment. Results showed that hydrogen permeation current fluctuates with the AWD, which is different from that in the bulk solution. In one AWD cycle, the permeation increases in the wetting stage and decreases in the dry stage. The smaller the dry/wet ratio, the longer the hydrogen permeation current keeps high level which is caused by the dense corrosion product layer. The hydrogen permeation currents in the elastic stress are greater than those in the plastic deformation, and unstressed conditions is the smallest.

Study on the Mechanical Response Behavior of X80 Pipeline Steel Welding Structure under Tensile Stress

Abstract The weld joint is composed of the weld area and the heat-affected area. The heterogeneity of the organizational structure will lead to local strain mismatch and affect its mechanical properties. This paper studies the strain distribution characteristics of the weld area and the heat-affected area under tensile stress, and reveals the respective strain response mechanism of the two regions. It is found that the weld area has lower yield strength and hardness, greater uniform elongation and strain hardening index. The plastic strain of the weld joint under tensile stress is highly heterogeneous, and the strain response mechanism is mainly based on the processing hardening effect. The strain response of the heat-affected area is weak and is affected by grain-oriented hardening. The research results provide a theoretical basis and experimental basis for the design of pipeline steel welding process and the safety evaluation under plastic deformation conditions.

Numerical Investigation on Cathodic Protection of X80 Pipeline Steel in Marine Environment

Abstract Submarine pipelines are usually buried in sea mud, but part of the pipes will be exposed to seawater directly because of the change of seabed, the differences between sea mud and seawater result in different corrosion states. Generally, due to its large geometric size, complex medium, difficult to detect and other reasons, corrosion defects will cause greater harm to pipeline materials. A numerical analysis model of the outer surface corrosion of submarine pipelines was developed to simulate status of cathodic protection, furthermore, potential distribution and local density of current inside the defects was also analyzed and evaluated. The results indicates that: (1)The CP potential distributes more evenly in sea mud when the same sacrificial anode is used, and the cathodic protection current density needed to meet the anti-corrosion requirements is much larger in seawater than in sea mud.(2)Compared with sea mud, the polarization potential of the sacrificial anode in seawater is more negative, and the CP potential at the edge of anodes is the most positive in both sea mud and seawater. Furthermore, in seawater, the dissolution rate of sacrificial anodes closer to the seabed is lower, and anodes dissolve much faster at the inner surface, while it is just the opposite in sea mud.(3)Cathodic protection cannot ensure complete and effective protection at defect points. At defect bottom, the cathodic protection current is partially shielded, reducing the effectiveness of CP system on corrosion protection of pipelines. Moreover, the shielding effect of defect point on cathodic protection current has a great deal with the geometric shape of defect points, with decreasing width and increasing depth, the shielding phenomenon becomes more obvious.(4) Numerical simulation technique based on the finite element model provides a new method to solve this problem and plays a positive role in assessing anti-corrosion status and the service life of anodes.

Underlying mechanisms for the effect of Nb micro-alloying on the elemental distribution and precipitation behavior in the X70 weld metal

Niobium (Nb) is a widely recognized micro-alloying element due to its low cost and substantial impact on steel properties. While the effect of Nb in processed steels has been well investigated, studies on its elemental distribution and precipitation behavior in weld metal remain scarce. This study focuses on the weld metal of specially designed Nb-rich X70 pipeline steel by scanning transmission electron microscopy (STEM) and energy-dispersive X-ray spectroscopy (EDS) characterization, complemented with thermodynamic and kinetics modeling analysis. In the majority of the weld, Nb was essentially uniformly distributed. This suggests that Nb primarily exists in the solid solution form in the weld metal, which is also supported by precipitation kinetics modeling results. This is primarily due to the short thermal history associated with the welding process, which leads to insufficient time for the uniform precipitation of Nb. Two instances of Nb precipitates were observed at the weld centerline and reinforcement region. The low partition coefficient of Nb results in an elevated local concentration along the weld centerline. However, precipitation kinetics calculations suggest that this enhancement alone is not adequate to induce precipitate formation. The occurrence of MnS and the prior formation of Ti precipitates may provide heterogeneous nucleation sites for Nb, facilitating the nucleation of Nb precipitates in the weld centerline and reinforcement region.

Constitutive Modeling, Processing Map Optimization, and Recrystallization Kinetics of high-grade X80 pipeline steel

Hot compression tests were used to examine the hot deformation behavior and of high-grade pipeline X80 steel at strain rates of 0.001-1 s-1 and temperatures of 950-1100 ºC. Two approaches were used to model material flow curves. The first used the Zener-Hollomon parameter, Z, to show the impact of deformation temperature and strain rate on flow stress, using the Arrhenius constitutive equation. The second used a rule of mixture to represent the material's flow curve, considering work hardening and dynamic recrystallization flow stresses. The first method was accurate at low Z and low strains, while the second method accurately displayed peak stress, was suitable for large strains, and predicting flow curves at industrial strain rates. The microstructure of X80 steel exhibits strain rate dependence under hot deformation conditions, with finer and more equiaxed microstructures observed at higher strain rates. These findings align with processing map predictions for stable deformation behavior, suggesting potential for optimized hot working processes. The static recrystallization kinetics showed that the Avarmi exponent, n, ranges from 1 to 2 for strains of 0.2 and 0.35 at 950°C, but higher values were observed under hot deformation conditions.

Investigation of the Fitness for Service (FFS) of Cracks in API 5L X70 Pipeline Steel using Failure Assessment Diagram (FAD)

In this study, the fitness for service of crack propagation in API 5L X-70 stee1 was investigated using a model called Failure Assessment Diagram (FAD) to determine how fit a crack can be under certain operational pressure. It is a known fact that during the production of pipes, there are tendencies for flaws such as inclusions and cracks to occur in the pipes. When these flaws are subjected to stresses, there are tendencies for failures to occur starting from where the cracks or flaws are located. The failure due to the propagation of the cracks leads to oil spillage causing pollution to the environment which had negatively impacted livelihood of the host communities and aquatic lives. This had resulted in Government spending huge amount of money maintaining the pipelines and remediation. The purpose of this paper is to investigate the fitness for service of crack lengths 12 mm, 17 mm, 22 mm and 27 mm using the Failure Assessment Diagram (FAD) mode1. The material used in this paper is API 5L X 70 steel in the form of a Compact Tension (CT) specimen machined according to ASTM E1820 – 13. API 5L X-70 stee1 is a low-carbon stee1 with a carbon content of as low as 0.04 %. It is used in the production of pipelines for conveying crude oil and natural gas from the place of production to the place of refining or export. In the investigation of the fitness for service of the cracks, a charpy V-notch impact test was carried out to determine the energy required to fracture the steel, which was later inputted numerically into a critical stress intensity factor formula in accordance with BS 7910 – 13 standards to obtain the critical stress intensity factor (KIC or KQ). The stress intensity factor (KI) was obtained from formula also according to BS 7910 – 13 standards. The ratio of KI to KQ was used in the FAD analysis. Subsequently, a monotonic tensile test was conducted to obtain the yield stress ( ys) and the reference stress ( ref) was obtained numerically according to BS 7910 – 13. The ratio of ref) to ys) was also used in the FAD analysis. The FAD analysis was used to determine the fitness for services and fracture behaviour of each crack. Scanning electron microscopy (SEM) was used to confirm the fracture behaviour obtained from the FAD. The results obtained show that the energy from the charpy V-notch impact test was 302.9 J and the critical stress intensity factor (KQ) correlated numerically according to BS 7910 – 13 was determine as 246.73 MPa . The yield stresses obtained from the monotonic test for crack lengths of 12 mm, 17 mm, 22 mm and 27 mm were 132.51 MPa, 109.10 MPa, 114.36 MPa and 118.21 MPa, respectively. In the FAD analysis, it was observed that the safe operational stress to ensure fitness for service decreases with an increase in crack length. The fracture behaviour shows a ductile fracture behaviour since the FAD lies within the plastic collapse region. This fracture behaviour was confirmed by the image obtained from the scanning electron microscopy (SEM), which showed a cup and cone image suggesting ductile fracture behaviour. This FAD method will ensure that safe operational stresses are maintained for various crack length to prolong the life span of the pipeline. It is a novel method that can also be used to properly schedule the rate of inspection in pipelines alongside Ultrasonic sound, Liquid penetrant, Magnetic particle and radiographic methods of inspection.