X-ray Phase Analysis Research Articles

Structural and electromagnetic properties of 3D printed and electron beam sintered lithium ferrite ceramic

In this work, the structures and electromagnetic properties of lithium ferrite ceramics manufactured by the additive method, based on the extrusion deposition of ferrite samples with a binder and their subsequent heating with high-energy electron beam, were studied. Preliminary synthesis of ferrite powder was carried out by a solid-phase method using iron oxide and lithium carbonate. To prepare ferrite paste, a binder based on ethylcellulose and terpineol was used. The printed samples were sintered by heating with 1.4 MeV electron beam using an ELV-6 accelerator. Using X-ray phase analysis, it was established that the sintered ceramic consists mainly of an ordered α−Li0.5Fe2.5O4 phase and a certain amount of disordered β−Li0.5Fe2.5O4 phase. Ferrite ceramics are characterized by a relative density of 72.6–92.1 %, specific saturation magnetization of 63–65 emu/g, Curie temperature of 628–630 °C, electrical resistivity of 108–106 Ω cm, depending on the thickness of the printed sample (200 and 400 μm) and sintering temperature (1100 and 1200°С).

Study of the structural and phase state of ceramics synthesized from 6YSZ - Al2O3 – HfO2 by semi–dry pressing followed by sintering in vacuum

The study investigates the properties of 6YSZ – Al2O3 – HfO2 powder mixture and the resulting ceramics obtained by semi-dry pressing followed by sintering in vacuum. X-ray fluorescence spectrometry revealed the primary constituents as zirconium (81%), aluminum (8.7%), yttrium (5.7%), and hafnium (3.5%). The average particle diameter was 0.5 μm, with specific surface area and bulk weight recorded at 18,535 cm2/g and 0.84 g/cm3, respectively. X-ray phase analysis indicated a predominance of monoclinic zirconium dioxide. Sintering at 1400-1600°C transformed the phase composition, enhancing density and microhardness, with values peaking at 5.8 g/cm3 and 12.1 GPa at 1600°C. This process also increased the tetragonal phase content to 63%. The ceramics exhibited the highest crack resistance at 1600°C, attributed to the stabilized tetragonal zirconium dioxide. Microstructural analysis confirmed the homogenous distribution of the elements and the presence of fine fractions influencing microstructural properties. 1600°C was found to be the optimal temperature for sintering the 6YSZ – Al2O3 – HfO2 ceramics.

Raw Materials in the Paste of Ceramics of the Kulaika Culture Surgut Variant (Based on Samples from Barsova Gora)

A multidisciplinary analysis of ceramics from six sites of the Surgut variant of the Kulaika culture at Barsova Gora was made. Technology was assessed using traceological, petrographic, and X-ray phase analyses. At all the sites, the potters used ferruginous clays tempered with grus, grog, sand, and organic material. Fragments in the clay were either rounded, as in sand, or coarse, as in grus. The sand was mainly represented by feldspar and quartz, suggesting that this type of raw material was extracted from nearby non-metallic mineral deposits. The grus consisted of fragments of basaltoids, amphiboles, and pyroxenes, evidencing that it came from igneous common rocks associated with the Surgut volcanic fi eld and spread over a large area. Rocks were probably mined near settlements, perhaps on the floodplain of the Ob. Grog in all the samples was similar to the basic clay in terms of its composition. Three groups of sites were identified, differing in the composition of the clay of which the ceramics were made. This may indicate the presence of several groups within the Iron Age Kulaika population, utilizing various sources of clay.

In the LiCl-KCl melt at 500<sup>о</sup>С depending on the content of Li<sub>2</sub>О и LiOH

Molten alkali metal chlorides used in pyrotechnologies are aggressive corrosive agents. The high operating temperature of the process, the heterogeneity of the environment, and the significant corrosion activity of the molten salt necessitate both the search for stable structural materials and the development of methods for protecting the structural elements of high-temperature technological devices. Corrosion loss reduction techniques traditionally used in low temperature environments are not applicable at high temperatures. The article examines the influence of oxygen-containing impurities (lithium oxide and hydroxide) on the corrosion behavior of metallic nickel (grade NP1) – the main component of candidate structural alloys, a thermodynamically and structurally stable material in the melt for the process of electrolytic refining of spent nuclear fuel. A method for preparing the LiCl–KCl salt electrolyte and obtaining lithium oxide by thermal decomposition of anhydrous lithium hydroxide under vacuum is described, and the concentrations of impurities in the electrolyte and the synthesized lithium oxide are determined. An installation for conducting corrosion tests in an inert atmosphere of a glove box is presented. To assess the corrosion resistance of the material, the following were used: gravimetric analysis, X-ray diffraction analysis of the surface and cross-sectional sections, and X-ray diffraction analysis of the surface of the samples. The dependences of the corrosion rate of the material on the concentration of oxygen-containing additives Li2O and LiOH were obtained. Based on a combination of gravimetric, X-ray microspectral and X-ray phase analysis data, it was established that metallic nickel samples demonstrate high corrosion resistance in the studied melts with the introduction of Li2O and LiOH additives.

SYNTHESIS AND PHYSICO-CHEMICAL PROPERTIES OF A NEW COMPLEX FERRITE

The article discusses the synthesis of new complex ferrite, radiographic and electron microscopic studies. The phase of complex ferrites was synthesized by the method of high-temperature sol-gel synthesis. For the first time, the structure of CrKFe2O5 Composite ferrite was studied by X-ray phase analysis and scanning electron microscope methods, the syngony type, elementary cell parameters, radiographic and pycnometric densities, and elemental analysis were determined. A comparative analysis of the relationship between the parameters of the Crystal cell of primary substances and the parameters of the obtained complex ferrite Crystal cell was carried out. Micro-samples were taken from different parts of the crystallite obtained through a scanning electron microscope, the elemental composition of the crystals was analyzed, and the general type of layer of the complex ferrite surface was demonstrated. As a result, the fact that the compound consists of two phases, the clarity of its construction was determined by the topography and chemical composition of the compound. As a result, it was found that the newly synthesized complex ferrite corresponds to the Formula CrKFe2O5. The particle size of the compounds formed is large (between 200 μm, 20.0 μm, 5.00 μm and 2.00 μm).

RESEARCH OF THE POSSIBILITY OF USING CHP ASH IN THE PRODUCTION OF FIRED ASH GRAVEL

The article presents a comparative analysis of the characteristics of the dump ash of the Kyzylorda CHP hydraulic removal. A huge amount of ash, slag waste is collected in the dumps of the CHP, their accumulation in the dumps leads to a violation of the ecology of the environment. The issue of ash, slag waste disposal is an urgent problem. The use of ash and slag not only solves the issue of availability of raw materials, but also allows to improve the quality of products while reducing their cost. One of the valuable components of ash and slag waste is hydraulic removal ash. Hydraulic removal ash as a raw material can be used for the manufacture of artificial concrete aggregates (ash, agglomerate gravel, etc.). Studies were conducted to study the physico-chemical composition, determine the specific effective activity of natural radionuclides, loss during calcination of two types of hydraulic removal ash samples from Kyzylorda CHP (black and gray), which differ in sampling sites from ash dump. When studying the properties of the ash, X-Ray phase analysis was carried out, with the help of which the phase composition of the ash was determined. Work was carried out on the X-Ray phase analysis of ash, determination of the specific effective activity of natural radionuclides, calcination losses, which showed the possibility of using ash for the production of building materials. The conducted studies have confirmed the expediency of using the ash of the Kyzylorda thermal power plant in the production of fired ash gravel.

Possibility of processing phosphogypsum to obtain an alkalizing reagent

Relevance. The need to develop a technology for the disposal of solid and liquid industrial waste to obtain organic-inorganic fertilizer. The growth of industrial production is accompanied by an increase in waste. In modern society, considerable attention is paid to the problem of processing man-made waste to obtain demanded products. Phosphogypsum is the main by-product of the production of fertilizers and phosphoric acid, it is a multi-tonnage waste, its storage leads to the withdrawal of vast territories from circulation. Liquid waste from pig farms also needs to be processed into organic fertilizers. Aim. To study the process of heat treatment of phosphogypsum in the presence of a reducing agent to obtain an alkalizing reagent. This will make it possible to further organize processing liquid and solid agricultural and industrial waste and produce domestic organic fertilizers Methods. Heat treatment of phosphogypsum in the presence of a reducing agent, followed by the preparation of an aqueous suspension to obtain an agent that reduces the acidity of livestock effluents. The samples of heat-treated phosphogypsum obtained during the study were characterized by X-ray phase analysis, electron microscopy. Suspensions with different pH values were obtained on their basis. Results and conclusions. The authors have studied heat treatment of large-tonnage inorganic waste of the chemical industry – phosphogypsum. It was found that the suspension of phosphogypsum heat-treated in the presence of a reducing agent has increased values of the hydrogen index, which can be used to obtain an alkalizing reagent for treating agricultural waste. The authors revealed the optimal technological modes of obtaining a reagent having the maximum pH value of the suspension: the amount of the introduced reducing agent is 0.16 mol/mol CaSO4, the heat treatment temperature is 1000 °C.

Binding properties of synthesized CS glasses activated by alkaline components

The paper presents the synthesis and evaluation of hydration and binding properties of individual minerals with glass-like structures in silicate systems, most often found in technogenic materials based on phosphorus and blast furnace slags. This work aims to determine the optimum composition of CS glasses to obtain binders with given properties, the hydration of glasses of different silicate and aluminosilicate compositions in the presence of solutions of soda, sodium hydroxide, and sodium metasilicate was investigated. The results of X-ray phase and differential-thermal analysis, and infrared spectrum are given, and the hydration structure of the calcium oxide-silicon oxide-alkali component system has been studied. The analysis of hydrate neoplasms of the studied binding systems shows that the most optimal conditions for the synthesis of stone strength with stable physical and mechanical properties are created in the presence of gel-like phase reinforced by hydrosilicates and hydroaluminosilicates of alkaline and alkaline-alkaline-earth composition, characterized by fiber-like structure and possessing the ability to epitaxial fusion with each other, as well as gel-like phase, which they reinforce.

OBTAINING AN ACTIVE INGREDIENT FOR COTTON SEED TREATMENT BASED ON METHYLENDIUREA AND PARAAMINOBENZOIC ACID AND STUDYING ITS PHYSICOCHEMICAL CHARACTERISTICS

Seed treatment is the main method of protecting plants from infectious diseases. The article presents data on the production of a double compound based on methylene diurea and paraaminobenzoic acid and the study of its physicochemical characteristics. The chemical interaction in the three-component water-salt system methylenediurea (MDU) – para-aminobenzoic acid (PABA) – water was studied using the isothermal method of physicochemical analysis. The crystallization region of the new binary compound, the active substance, was established at a molar ratio MDU: PABA = 1:2. The formation of the double compound is confirmed by X-ray phase and IR spectroscopic methods of analysis. From the obtained X-ray phase analysis data, it follows that the reference lines of the double compound and their intensity differ from the X-ray patterns of the initial components. The IR spectra of MDM and PABA are characterized by intense absorption in the region of 3500-3390 cm-1 , 2000-500 cm-1 and 3500-3345 cm-1 , 1800-500 cm-1 , respectively. In the IR spectra of the new double compound MDM•2PABA, the absorption intensity in the region of 1800-500 cm-1 increases. A decrease in the absorption region of the stretching vibration of CO groups from 1626, 1626.3 cm-1 to 1612 cm-1 is observed in the case of the double compound MDM•2PABA. The results of the studies indicate the formation of a new compound. It is shown that the double compound has low hygroscopicity under summer, autumn, spring and winter storage conditions, high swelling and moisture capacity, and low solubility.

ОРТА КӨМІРТЕКТІ ФЕРРОМАРГАНЕЦ ТЕХНОЛОГИЯСЫН ЗЕРТТЕУ ЖӘНЕ ӘЗІРЛЕУ

This article presents the results of medium-carbon ferromanganese smelting from domestic manganese ores under large-scale laboratory conditions. Data on the production and demand for refined ferromanganese produced during the last successful year are provided. Since 2020, refined ferromanganese production has decreased by approximately 1,2 million tons, which is 18% lower than in 2019. This decline was caused by the outbreak of the coronavirus (COVID-19), which began in China in 2019, and the subsequent worldwide pandemic, as well as geopolitical conflicts (Russia — Ukraine), which started in 2021. Kazakhstan has significant reserves of manganese ores, which are in ferrous-manganese and carbonate states. X-ray phase analysis showed that manganese in the ores is represented by hydroxide, pyrolusite, and iron oxide. Medium-carbon ferromanganese was smelted in an electric furnace with a transformer power of 0.1 MVA. The chemical composition of the resulting alloy is as follows, %: Mn – 80-85; Si – 0,05-0,25; Fe – 1,8-3,0; P – 0,05-0,09; C – 1,5-2,0; MnO – 20-25; SiO₂ – 13,94-14,5; CaO – 23,35-24,85; MgO – 12,5-14,0. Thus, an optimal technological scheme for the production of a wide range of manganese ferroalloys was developed.

Qualities of Regenerated Mixtures of Adsorbents

A proposal has been presented for the regeneration of a spent sorbent mixture, comprising activated carbon (BAU-A brand) and kieselguhr (Bekogur 200 brand), in a mass ratio of 1:3. The effectiveness of the regeneration process and the potential applications of the spent sorbents were determined through X-ray phase analysis methods. The study included an investigation into the adsorption of the primary dye (methylene blue) by activated carbon and various sorbent mixtures. The observed efficiency of regeneration supports the recommendation of using a combination of kieselguhr and activated carbon sorbents for treating wastewater in food industry enterprises.

Твердофазное восстановление оксидов FexOy и MnxOy углеродом в условиях низкотемпературного обжига шихты на основе марганцевых отходов

Based on complex analytical studies, including methods of atomic emission spectrometry with inductively coupled plasma and X-ray phase analysis of intermediate and final products, the material and mineralogical compositions of manganese wastes of the Dzhezdinsky GOK have been studied. It is shown that the low content of iron and manganese in waste determines the need for a preliminary operation for their enrichment. The mechanism of be havior of iron and manganese oxides under conditions of low-temperature firing of a charge composed on the basis of manganese waste has been studied. Based on thermodynamic calculations of reactions of reduction of iron and manganese oxides by carbon, the possibility of complete reduction of iron to metal from its higher and lower oxides is shown. Higher man ganese oxides are subjected to solid-phase reduction by carbon. Stable manganese oxide at the temperatures of firing to metal is practically not restored due to the positive values of the Gibbs free energy. To increase the iron content in the charge, it is necessary to provide for the addition of iron-containing waste with a high iron content to the charge, for example, rolling scale, etc. When arranging the final charge, it is necessary to take into account the optimal carbon consumption: carbon consumption should not exceed the stoichiometrically necessary amount for the reduction of iron and manganese oxides. The excess carbon not used for the reduction of MnO will remain in the charge, and will be fully used as a reducing reagent during the reduction melting. The metallized product obtained after firing must be subjected to gran ulation in order to obtain durable granular pellets, which will represent the final monoshift for the production of high-quality ferromanganese.

Effect of HVOF method spraying parameters on phase composition and mechanical and tribological properties of 86WC-10Co-4Cr coating

Valve components used in the petroleum industry are subjected to intense wear during operation, which leads to a sharp decrease in their durability. Usually, the often subjected to the wear process surface of the valves is treated by tungsten carbide cladding to improve its durability. Because of the difficulty in applying tungsten carbide using conventional surfacing techniques, high velocity oxyfuel (HVOF) spraying technology is rec- ommended. In this work, the mechanical, tribological properties and phase composition of 86WC-10Co-4Cr composition coatings obtained by HVOF Termika-3 high-velocity gas-fuel spraying were investigated. Vary- ing the technological parameters of spraying was carried out by changing the spraying distance, which led to differences in the thickness of the coatings. The phase composition, microstructure and distribution of ele- ments were analyzed using X-ray diffraction (XRD), scanning electron microscopy (SEM) methods. The hardness of the samples was measured on a microhardness tester using the Vickers method, the friction coef- ficient and the wear rate were investigated using a friction and wear tester. It was determined that the surface of the coatings had developed character and high roughness. The results of X-ray phase analysis showed the predominance of hexagonal WC as the major phase, with a small amount of hexagonal tungsten carbide W2C as the minor phase, and the minor presence of cobalt oxide CoO. It was found that the increased wear re- sistance and low friction coefficient of 86WC-10Co-4Cr coatings are explained by the high volume fraction of hard and stable WC grains with high resistance to wear.

METHOD FOR OBTAINING NANOPARTICLES OF IRON-CONTAINING OXIDES AND STUDYING THEIR PROPERTIES

The synthesis of iron-containing oxide nanoparticles is of interest in medicine, electronics and ecology due to their unique physical and chemical properties, such as magnetic, catalytic and adsorption properties, which allow their use in various technological processes. In this regard, this article presents the results of obtaining nanoparticles of iron-containing oxides and studying their physical and chemical properties. It is known that stabilization with natural polymers is of great importance in the production of metal nanoparticles. Therefore, in this work, the synthesis is carried out at high temperature by stabilization with potassium humate. To study the properties of the resulting iron-containing nanoparticles, methods of X-ray phase analysis, transmission electron microscopy and infrared spectroscopy were used. As a result of physicochemical studies, the heterogeneity and monodispersity of the synthesized metal nanoparticles was established. The average particle size of the synthesized samples was 8.3 nm, the crystal lattice parameter was 0.8426 nm. The result of the study using IR spectroscopy confirms the assumption of oxidation of the samples. In addition, it was found that the prepared samples have a high degree of crystallization. Transmission electron microscopy revealed no differences in the sizes of nanoparticles. Pure iron oxide is not formed during the synthesis of iron nanoparticles using the method used in the research work. The unique properties of iron-containing oxide nanoparticles obtained as a result of research are promising for the creation of innovative technologies and solutions aimed at improving the quality of life and sustainable development of society.

Structural and morphological features of magnetron nanofilms of TaN with different thicknesses

Purpose of research. Study of morphological and phase changes in the structure of tantalum nitride nanofilms formed by magnetron reactive sputtering on a silicon substrate.Methods. Magnetron sputtering on a silicon substrate was performed using the MVU TM-Magna T setup with the sputtering time parameter changing from 300 to 900 sec, and also with constant power parameters of 500 W and working gas pressure of Ar 0,5 Pa. The morphological and phase changes in the structure of tantalum nitride nanofilms were studied using atomic force microscopy and X-ray phase analysis. The fractal dimension was determined using the cube counting method. X-ray diffractometric analysis in the in situ measurement mode with discrete heating (in 100 °C increments) in air up to 1000 °C using the PAAR HTK-16 high-temperature attachment.Results. Using atomic force microscopy methods, it was found that the granulometric distribution of nanoclusters in the studied TaN nanofilms was Gaussian and an increase in the lateral size of particles was observed with an increase in the deposition time. The nanofilm with a deposition time of 300 s had minimal roughness. The statistical fractal dimension was calculated, the value of which corresponded to their three-dimensionality. According to the X-ray phase analysis data, the sizes of the coherence region, texturing, microdeformations and interplanar deformation distortions were determined, and a mixed Stranski-Krastanov mechanism of nanofilm formation was established.Conclusion. The surface roughness of nitride nanofilms formed at a constant power (500 W) depends significantly on the magnetron sputtering time and N2 concentration. In all studied nanofilm structures, the dominant growth mechanism was the mixed Stranski–Krastanov mechanism.

Новый катодный материал La2/3Cu3Ti4−xFex O12−δ для твердооксидного топливного элемента: синтез и электропроводность

Copper lanthanum titanate La2/3Cu3Ti4−xFexO12−δ x = 0–1 was doped with Fe3+ cations. The diagram of the dependence of the tolerance factor on the relative electronegativity of cations for all studied compositions was represented. It was shown that all the compositions exist in the region of existence of distorted perovskite. X-ray diffraction and X-ray phase analysis methods established the region of existence of solid solutions of La2/3Cu3Ti4−xFexO12−δ obtained by ceramic technology, which was 0 ⩽ x ⩽ 0.4. The temperature dependences of electrical conductivity for the compositions from the region of existence of solid solutions La2/3Cu3Ti4−xFexO12−δ were obtained. The ionic-electronic nature of conductivity was suggested. It was shown that the decrease of electronic conductivity under the increase of iron content was due to the compensation of electronic carriers formed during acceptor doping.

Modification of Sulfur Cake—Waste from Sulfuric Acid Production

In the production of sulfuric acid, sulfur cake—a waste product of the sulfur purification process—is formed in large quantities, which requires its disposal and use. For its use in composite materials, modification is necessary to convert sulfur into a polymer form. The aim of the study was to develop a method for modifying sulfur cake—a waste product of sulfuric acid production—for its disposal. Available reagents—styrene, glycerol, and oleic acid—were tested as modifiers in the work. The sample compositions consisted of 100% sulfur cake (no. 1) and its mixtures: 97% sulfur cake + 3% styrene (no. 2), 97% sulfur cake + 3% glycerol (no. 3), 97% sulfur cake + 3% oleic acid (no. 4), 95% sulfur cake + 3% styrene, 1% glycerol, and 1% oleic acid (no. 5). Modification of sulfur cake was carried out at a temperature of 140 °C for 30 min. The composition, crystal structure, and thermal properties of the samples of the original and modified sulfur cake were studied using X-ray phase and X-ray structural analyses, IR spectroscopy, differential scanning calorimetry, differential thermal and thermogravimetric analysis. The optimal modifier for sulfur cake was a mixture of styrene, glycerol, and oleic acid, which led to the formation of acetal (polyoxymethylene) and an improvement in the structure due to a decrease in the content of impurities. Modification of sulfur cake with styrene resulted in the appearance of a CAr–S bond band at 571 cm−1, and modification with oleic acid a C–S band in the region of 694 cm−1 in the IR spectra. The results of differential scanning calorimetric analysis showed an increase in the heat of fusion of sulfur by 12.45 J/g in the samples of sulfur cake modified with glycerol and styrene. Modification of sulfur cake with oleic acid and a mixture of reagents resulted in the appearance of a third peak with maxima at 244.2 and 264.0 °C, which demonstrated a significant effect of the indicated additives on the thermal behavior of the sulfur cake. Proposed schemes for modifying sulfur cake with styrene and oleic acid are presented.

Study of phase composition, microstructure and hardness of multicomponent zirconia-based ceramics

The manufacture of products from refractory ceramics requires high temperatures due to the high activation energies of the sintering process of refractory oxides. Processing temperatures for ceramics made of ZrO2, Al2O3, MgO can be reduced if a flux or glass-forming component is selected. Furthermore, in multicomponent ceramics it is possible to create more favorable thermoresistive properties. This study examines the synthesis, structural, phase and mechanical properties of multicomponent porous ZrO2-WO3-Al2O3-MgO ceramics with varying weight concentrations of components. Experimental samples were obtained by standard solid state reaction method. The analysis of fabricated samples was carried out using X-ray phase analysis, scanning electron microscopy and the Vickers microhardness test. In this work, a new approach to increasing the microhardness of porous refractory ceramics is presented, in which WO3-based flux forms a matrix composed of glass-like formations that “attach” particles of ZrO2 and MgAl2O4 phases. The obtained ceramics demonstrates high microhardness values HV0.05 for porous materials ranging from 500 to 600. Studies have shown that the selected composition of multicomponent ceramics (x = 0.10–0.25) can be used as a refractory material up to temperatures of ∼1300 °C. The fabricated refractory ceramics potentially possess chemical stability and optimal microhardness properties, which makes these materials promising as a heat insulating lining in the metals, ceramics and glass manufacturing, as well as for components in the chemical industry.

CRYOCHEMICAL SYNTHESIS OF HYBRID NANOFORMS BASED ON SILVER AND THE ANTIBACTERIAL DRUG SUBSTANCE DIOXIDINE

Hybrid nanoforms based on silver and antibacterial drug dioxidine (2,3-bis-(hydroxymethyl)quinoxaline 1,4-di-N-oxide) were prepared by the method of joint co-condensation of metal and ligand vapors on a liquid nitrogen cooled surface. The samples obtained by low temperature co-condensation were characterized by FTIR-, UV-Vis and XPS-spectroscopy, ТЕМ, SEM and powder X-ray phase analysis (ХРА). It was shown that cryomodified nanoforms preferably consist of anhydrous triclinic (T-phase) crystal phase of dioxidine, the dimensions of dioxidine particles ranges from 50 to 300 nm, the average size of included silver nanoparticles is (15±3) nm. Broadening of the diffraction patterns belonging to silver shows the transition of metallic silver to the nanoscale state. The FTIR results indicate for hybrid nanoforms stabilized by donor-acceptor interactions of surface silver atoms with hydroxyl groups and with donor N-atoms of quinoxaline cycles of dioxidine molecules.

Preparation of uranium-plutonium oxide solid solution powder from ammonium uranyl-plutonyl carbonate in a laboratory microwave unit

The method of obtaining a solid solution powder of uranium-plutonium oxides (with 38% plutonium content) from the AUPuC pulp of the process (ammonium uranyl-plutonyl carbonate) using microwave radiation in reducing and atmospheric environments was proposed and tested at the laboratory level. For research purposes, the pulp obtained by coprecipitation of uranium and plutonium from nitrate solution (stripping product simulator) was prepared in advance. The process consists of three main stages: oxidation of Pu(IV) to Pu(VI), precipitation, and conversion in a laboratory microwave unit. According to the X-ray phase analysis, the powder obtained in a reducing atmosphere is a solid cubic solution (UxPu1–x)O2. The powder obtained in an atmospheric environment is a mixture of two oxides, PuO2 and U3O8. Scanning electron microscopy and electron probe microanalysis of the powder obtained in an atmospheric environment showed a fairly uniform distribution of U, Pu, and O in the solid phase.